The Catalytic Oxidation of Aqueous Phenol by H2O2Using a Macrocyclic (N-Donor) Cobalt(Ii) Complex
A new macrocyclic (N-donor) cobalt(II) complex, denoted CoR, was synthesized and characterized, and used as a mimetic peroxidase in the catalytic oxidation of phenol by H2O2. The catalytic system displayed high catalytic activity and the catalytic character of a metalloenzyme, although it did not attain the catalytic efficiency of enzymes. The final products were maleic and oxalic acids. Intermediate products, such as catechol and hydroquinone and p-benzoquinone, were detected by high-pressure liquid chromatography (HPLC) and UV-Vis spectrophotometry. The effects of temperature and the pH of the system on the rate of the catalytic oxidation were investigated. A reaction mechanism and kinetic model for the catalytic oxidation are proposed, which are supported by the results of the experimental and calculation data.
Low platinum alloy catalyst PtCo3 obtaining high catalytic activity and stability with great water and CO2 resistance for catalytic oxidation of toluene
