Catalytic activity of CuOn–La2O3/γ-Al2O3 for microwave assisted ClO2 catalytic oxidation of phenol wastewater

2008 ◽  
Vol 154 (1-3) ◽  
pp. 543-549 ◽  
Author(s):  
Xiaoyi Bi ◽  
Peng Wang ◽  
Hong Jiang
2011 ◽  
Vol 36 (4) ◽  
pp. 342-351 ◽  
Author(s):  
Fa-mei Feng ◽  
Fu-an Liu ◽  
Shu-lan Cai ◽  
Jia-qing Xie

A new macrocyclic (N-donor) cobalt(II) complex, denoted CoR, was synthesized and characterized, and used as a mimetic peroxidase in the catalytic oxidation of phenol by H2O2. The catalytic system displayed high catalytic activity and the catalytic character of a metalloenzyme, although it did not attain the catalytic efficiency of enzymes. The final products were maleic and oxalic acids. Intermediate products, such as catechol and hydroquinone and p-benzoquinone, were detected by high-pressure liquid chromatography (HPLC) and UV-Vis spectrophotometry. The effects of temperature and the pH of the system on the rate of the catalytic oxidation were investigated. A reaction mechanism and kinetic model for the catalytic oxidation are proposed, which are supported by the results of the experimental and calculation data.


1998 ◽  
Vol 40 (4) ◽  
pp. 343-352 ◽  
Author(s):  
Jale F Akyurtlu ◽  
Ates Akyurtlu ◽  
Suphan Kovenklioglu

1999 ◽  
Vol 33 (4) ◽  
pp. 1005-1013 ◽  
Author(s):  
C Miró ◽  
A Alejandre ◽  
A Fortuny ◽  
C Bengoa ◽  
J Font ◽  
...  

2015 ◽  
Vol 5 (6) ◽  
pp. 3159-3165 ◽  
Author(s):  
Lei Luo ◽  
Chengyi Dai ◽  
Anfeng Zhang ◽  
Junhu Wang ◽  
Min Liu ◽  
...  

The mesoporous ZSM-5 zeolite obtained from alkaline treatment was found to be a superior support of bimetallic FeCu, minimizing the nanoparticle size, enhancing the bimetallic interaction, and promoting catalytic oxidation of phenol.


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