scholarly journals Photoalignment and photopatterning: New liquid crystal technology for displays and photonics

Author(s):  
V. G. Chigrinov

Objectives. Since the end of the 20th century, liquid crystals have taken a leading position as a working material for the display industry. In particular, this is due to the advances in the control of surface orientation in thin layers of liquid crystals, which is necessary for setting the initial orientation of the layer structure in the absence of an electric field. The operation of most liquid crystal displays is based on electro-optical effects, arising from the changes in the initial orientation of the layers when the electric field is turned on, and the relaxation of the orientation structure under the action of surfaces after the electric field is turned off. In this regard, the high quality of surface orientation directly affects the technical characteristics of liquid crystal displays. The traditional technology of rubbing substrates, currently used in the display industry, has several disadvantages associated with the formation of a static charge on the substrates and surface contamination with microparticles. This review discusses an alternative photoalignment technology for liquid crystals on the surface, using materials sensitive to polarization of electromagnetic irradiation. Also, this review describes various applications of photosensitive azo dyes as photo-oriented materials. Results. The alternative photoalignment technology, which employs materials sensitive to electromagnetic polarization, allows to create the orientation of liquid crystals on the surface without mechanical impact and to control the surface anchoring force of a liquid crystal. This provides the benefits of using the photoalignment technology in the display industry and photonics—where the use of the rubbing technology is extremely difficult. The optical image rewriting mechanism is discussed, using electronic paper with photo-inert and photoaligned surfaces as an example. Further, different ways of using the photoalignment technology in liquid crystal photonics devices that control light beams are described. In particular, we consider switches, controllers and polarization rotators, optical attenuators, switchable diffraction gratings, polarization image analyzers, liquid crystal lenses, and ferroelectric liquid crystal displays with increased operation speed. Conclusions. The liquid crystal photoalignment and photopatterning technology is a promising tool for new display and photonics applications. It can be used for light polarization rotation; voltage controllable diffraction; fast switching of the liquid crystal refractive index; alignment of liquid crystals in super-thin photonic holes, curved and 3D surfaces; and many more applications.

MRS Bulletin ◽  
1991 ◽  
Vol 16 (1) ◽  
pp. 46-56 ◽  
Author(s):  
Walter Zimmermann

One hundred years after their discovery, we meet liquid crystals everywhere in our daily life. Their most widely known application is the liquid crystal displays (LCDs) in watches, pocket calculators, or gasoline pumps. Applications aside, liquid crystals show many exciting properties, making them highly interesting for fundamental research. For example, electrohydrodynamic convection (EHC) in nematic liquid crystals, which is studied in cells of a configuration similar to liquid crystal displays, serves with its characteristic properties as a model System for investigating central questions of pattern formation and chaos.Today's liquid crystal displays work on the principle described in 1971 by Martin Schadt and Wolfgang Helfrich (Figure 1). In nematic liquid crystals, organic molecules orient on average along a macroscopic direction, described by the director field n(r), that has neither head nor tail (n = −n). Nematics are therefore anisotropic and for energetic reasons, n(r) orients parallel (perpendicular) to an electric field when the dielectric permittivity (ε∥) along n is larger (smaller) than the perpendicular (ε⊦ one. For positive εa = ε∥ − ε⊦, when an electric field is applied perpendicular to the direction of n, a reorientation of n takes place together with a corresponding change in the optical property of the cell. The controlled change by an electric field in the optic axis (orientation) in well-defined areas of the display then allows the representation of numbers, etc.


2020 ◽  
Vol 10 (6) ◽  
pp. 780-787
Author(s):  
Hongyue Gao ◽  
Suna Li ◽  
Jicheng Liu ◽  
Wen Zhou ◽  
Fan Xu ◽  
...  

In this paper, we studied the holographic properties of liquid crystal (LC) thin film doped with carbon dots (CDs) which can be used as real-time holographic display screen. The maximum value of diffraction efficiency can reach up to 30% by using a low applied electric field 0.2 V/μm. Holograms in the LC film can be dynamically formed and self-erased. The hologram build-up time and the hologram self-erasure time in the material is fast enough to realize video refresh rate. In addition, the forming process of hologram was studied. The holographic diffraction efficiency was measured depending on the intensity of recording light, applied electric field, the intensity of readout light, and readout light polarization direction. Triple enhancement of the diffraction efficiency value by the modulation of voltage under the condition of low recording energy is presented. Therefore, we develop an easy way to obtain real-time dynamic holographic red, green and blue displays with high diffraction efficiency, which allow the LC film doped with CDs to be used as a holographic 3D display screen.


1981 ◽  
Vol 36 (7) ◽  
pp. 718-726 ◽  
Author(s):  
Paul R. Gerber

Abstract o lta g e -In d u c e d C h o le s te r ic S tr u c tu r e -T r a n s f o r m a tio n in T h i n L a y e rs Measurements of various threshold voltages which occur in thin layers of cholesteric liquid crystals with positive dielectric anisotropy under homeotropic wall-alignment conditions are presented. Characteristic times are determined for some of the structure-changing processes which take place under application of electric-field changes. The measurements have been performed for various pitch-to-thickness ratios, and are expressed in empirical formulae.


1996 ◽  
Vol 457 ◽  
Author(s):  
Shiro Matsumoto ◽  
Marthe Houlbert ◽  
Takayoshi Hayashi ◽  
Ken-ichi Kubodera

ABSTRACTNano-sized fine droplets of liquid crystal (LC) were obtained by phase separation of nematic LC in UV curing polymer. The polymer composite had a high transparency in the infrared region. The fine droplets responded to an electric field causing a change in birefringence. Output power change was brought about by the generated retardation between two polarizations, parallel and perpendicular to the applied electric field. This differs from the composite containing much larger droplets, where output depends on the degree of scattering. The birefringence changed by 0.001 at the applied voltage of 7.5 V/μm.


2017 ◽  
Vol 5 (18) ◽  
pp. 4384-4387 ◽  
Author(s):  
O. Sato ◽  
N. Iwata ◽  
J. Kawamura ◽  
T. Maeda ◽  
Y. Tsujii ◽  
...  

We present the “one-side zero-anchoring in-plane switching” (OZ-IPS) mode in liquid crystal displays (LCDs) comprising an electrode substrate onto which poly(hexyl methacrylate) chains are grafted and a counter substrate coated with a rubbed polyimide film.


2019 ◽  
Vol 33 (26) ◽  
pp. 1950319
Author(s):  
Yan Li ◽  
Xiaobo Lu ◽  
Chunfeng Hou

In this paper, we study the twist of the nematic liquid crystal molecules under the applied electric field. The dynamic equation of the twisted molecules is derived. It is proved to be a kind of sine-Gordon (SG) equation. We obtain the breather solution of the equation and confirm that the deflection angles of the twisted molecules can distribute in the form of breathers. We give the relationship between the molecular deflection angle and the breather frequency, and discuss the effect of electric field on breather shape and breather frequency.


1999 ◽  
Vol 559 ◽  
Author(s):  
L. V. Natarajan ◽  
R. L. Sutherland ◽  
V. P. Tondiglia ◽  
S. Siwecki ◽  
R. Pogue ◽  
...  

ABSTRACTElectrically switchable volume reflection holograms were written by inhomogeneous illumination of a prepolymer syrup containing a nematic liquid crystal and a multifunctional acrylate monomer. Switchable holograms are diffractive optics structures and the diffraction efficiency can be controlled by the application of an electric field. Reflection gratings with grating spacing varying between 0.16-0.27 µm were made during the phase separation of liquid crystals from the fast curing prepolymer syrup. The reflection efficiency of the holograms were electrically modulated with the applied field of ∼10-15V/µm. Real time study of the grating formation revealed that the maximum efficiency is reached in ∼15 seconds. The shrinkage of the host polymer during grating formation resulted in the blue shift of the reflection notch. The response time of the grating in an electric field is ∼50 µs. Low voltage scanning electron microscope studies showed the presence of discrete nematic droplet domains of sizes 30-60 nm in liquid crystal rich region.


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