scholarly journals Fabricating a flexible super capacitor prototype based on nano - composite electrode and polymer electrolyte

2016 ◽  
Vol 19 (4) ◽  
pp. 195-201
Author(s):  
Dao Thi Anh Luong ◽  
Quyet Huu Do

Super capacitor is an important device for energy storage and usage with high power and high efficiency. Commercial super capacitors are typically fabricated by using binder to attach electrode powder to the metal foil current collector. In this paper, we present a method to fabricate super capacitors using binder-free electrodes and carbon current collector to enhance the compact size, light weight and flexibility. To obtain high power and high energy density, nano composite electrode of CNTs-polyaniline was employed. The super capacitors with PVA electrolyte achieved the electrode capacitance of 170 F/g and charged voltage can be up to 1.2 volt, which is the maximum voltage achieved by aqueous PVA electrolyte.

2016 ◽  
Vol 4 (44) ◽  
pp. 17279-17287 ◽  
Author(s):  
Ye Tian ◽  
Li Jin ◽  
Hangfeng Zhang ◽  
Zhuo Xu ◽  
Xiaoyong Wei ◽  
...  

Solid-state dielectric energy storage is the most attractive and feasible way to store and release high power energy compared to chemical batteries and electrochemical super-capacitors.


MRS Advances ◽  
2016 ◽  
Vol 1 (6) ◽  
pp. 403-408 ◽  
Author(s):  
Qing Zhang ◽  
Kenneth J. Takeuchi ◽  
Esther S. Takeuchi ◽  
Amy C. Marschilok

ABSTRACTCarbon monofluoride (CFx) has been extensively used as a reliable cathode material in lithium primary batteries because of its high energy density and long shelf life. However, the implementation of Li/ CFx batteries in high-power applications is limited by the low power capability resulting from the insulative nature of CFx material. In this work, we incorporated multi-walled carbon nanotubes into CFx electrodes and studied the impact on the electrochemical performances when CNTs were used as a conductive additive material and current collector substrate. Our work demonstrated the promising utilization of CNTs in CFx electrodes in improving the practical capacity and power capability of Li/ CFx batteries.


Energies ◽  
2019 ◽  
Vol 12 (16) ◽  
pp. 3127 ◽  
Author(s):  
Zhang ◽  
Shewale ◽  
Yun

Electrostatic capacitors have high power density but low energy density. In contrast, batteries and fuel cells have high energy density but low power density. However, supercapacitors can simultaneously achieve both high power density and energy density. Herein, we propose a supercapacitor, in which etched nickel wire was used as a current collector due to its high conductivity. Two redox reactive materials, MnO2 nanoflakes and NiCo2O4 nanoneedles, were used in a hierarchical structure to cover the roughened surface of the Ni wire to maximize the effective surface area. Thus, a specific capacitance, energy density, and power density of 14.4 F/cm3, 2 mWh/cm3, and 0.1 W/cm3, respectively, was obtained via single-electrode experiments. A fiber-shaped supercapacitor was prepared by twisting two electrodes with solid electrolytes made of KOH and polyvinyl alcohol. Although the solid electrolyte had a low ionic conductivity, the energy density and power density were determined to be 0.97 mWh/cm3 and 49.8 mW/cm3, respectively.


2021 ◽  
Vol 13 (1) ◽  
Author(s):  
Chen Li ◽  
Xiong Zhang ◽  
Kai Wang ◽  
Xianzhong Sun ◽  
Yanan Xu ◽  
...  

AbstractLithium-ion capacitors are envisaged as promising energy-storage devices to simultaneously achieve a large energy density and high-power output at quick charge and discharge rates. However, the mismatched kinetics between capacitive cathodes and faradaic anodes still hinder their practical application for high-power purposes. To tackle this problem, the electron and ion transport of both electrodes should be substantially improved by targeted structural design and controllable chemical doping. Herein, nitrogen-enriched graphene frameworks are prepared via a large-scale and ultrafast magnesiothermic combustion synthesis using CO2 and melamine as precursors, which exhibit a crosslinked porous structure, abundant functional groups and high electrical conductivity (10524 S m−1). The material essentially delivers upgraded kinetics due to enhanced ion diffusion and electron transport. Excellent capacities of 1361 mA h g−1 and 827 mA h g−1 can be achieved at current densities of 0.1 A g−1 and 3 A g−1, respectively, demonstrating its outstanding lithium storage performance at both low and high rates. Moreover, the lithium-ion capacitor based on these nitrogen-enriched graphene frameworks displays a high energy density of 151 Wh kg−1, and still retains 86 Wh kg−1 even at an ultrahigh power output of 49 kW kg−1. This study reveals an effective pathway to achieve synergistic kinetics in carbon electrode materials for achieving high-power lithium-ion capacitors.


Materials ◽  
2021 ◽  
Vol 14 (13) ◽  
pp. 3586
Author(s):  
Qi An ◽  
Xingru Zhao ◽  
Shuangfu Suo ◽  
Yuzhu Bai

Lithium-ion capacitors (LICs) have been widely explored for energy storage. Nevertheless, achieving good energy density, satisfactory power density, and stable cycle life is still challenging. For this study, we fabricated a novel LIC with a NiO-rGO composite as a negative material and commercial activated carbon (AC) as a positive material for energy storage. The NiO-rGO//AC system utilizes NiO nanoparticles uniformly distributed in rGO to achieve a high specific capacity (with a current density of 0.5 A g−1 and a charge capacity of 945.8 mA h g−1) and uses AC to provide a large specific surface area and adjustable pore structure, thereby achieving excellent electrochemical performance. In detail, the NiO-rGO//AC system (with a mass ratio of 1:3) can achieve a high energy density (98.15 W h kg−1), a high power density (10.94 kW kg−1), and a long cycle life (with 72.1% capacity retention after 10,000 cycles). This study outlines a new option for the manufacture of LIC devices that feature both high energy and high power densities.


2018 ◽  
Vol 6 (21) ◽  
pp. 9846-9853 ◽  
Author(s):  
Ranjith Thangavel ◽  
Aravindaraj G. Kannan ◽  
Rubha Ponraj ◽  
Xueliang Sun ◽  
Dong-Won Kim ◽  
...  

Developing sodium based energy storage systems that retain high energy density at high power along with stable cycling is of paramount importance to meet the energy demands of next generation applications.


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