scholarly journals ЕФЕКТИВНІСТЬ ЕНЕРГОТЕХНОЛОГІЧНОЇ УСТАНОВКИ ЩОДО ВИДОБУВАННЯ СІРКОВОДНЮ З ГЛИБИН ЧОРНОГО МОРЯ

2019 ◽  
pp. 50-57
Author(s):  
Михайло Романович Ткач ◽  
Борис Георгійович Тимошевський ◽  
Аркадій Юрійович Проскурін ◽  
Юрій Миколайович Галинкін
Keyword(s):  
Mathematical Model ◽  
Hydrogen Sulfide ◽  
Black Sea ◽  
Control Valve ◽  
Operational Reliability ◽  
Gas Content ◽  
The Black Sea ◽  
Depth Range ◽  
Gaseous State ◽  
Pressure Hydrogen

The article discusses a promising energy-technology unit for the extraction of hydrogen sulfide from the deep waters of the Black Sea, which provides for raising the gas-liquid mixture from the depths by the gas-lift method using wave pulses to separate hydrogen sulfide in the gaseous state. The installation includes a supply line, which is lowered to the required depth, a supply pump, a coalescing separator, a seawater discharge line with a reduced concentration of hydrogen sulfide, a control valve, a hydrodynamic generator of mechanical vibrations, a lifting pipeline, a high pressure hydrogen sulfide separator, a hydraulic turbine, a low pressure hydrogen sulfide separator, seawater discharge pipe and hydrogen sulfide expander. This unit will improve the energy efficiency and operational reliability of the process of hydrogen sulfide production, as well as reduce the burden on the Black Sea environment. A mathematical model of this setup has been developed. The results obtained by the mathematical model adequately coincide with the known experimental ones. This suggests that it is possible to use the model to determine the parameters of the process for the extraction of hydrogen sulfide from the Black Sea. The parameters of the process for the extraction of hydrogen sulfide from the Black Sea in the depth range of the pipeline 0...1000 m at a temperature of 280...285 K. It has been established that increasing the gas content of seawater from 0 to 2.5 m3/m3 leads to a decrease in the pressure value by 2.2 MPa. A further increase in seawater gas content from 2.5 to 5.0 m3/m3 is accompanied by a decrease in pressure of another 1.6 MPa. Such a significant decrease in pressure at the inlet to the riser piping allows hydrogen sulfide and seawater to be obtained at a pressure that is substantially greater than atmospheric. The excess pressure at the outlet of the lifting pipeline is determined based on data obtained by the method of "equivalent length". When the seawater gas content is 2.5 m3/m3, the pipeline’s immersion depth is 250...1000 m, the value of the overpressure of substances at the exit of the lifting pipeline will be 0.2...0.45 MPa, and at 5 m3/m3 – 0.67...1.07 MPa, at 7.5 m3/m3 – 0.83...1.4 MPa and at 10 m3/m3 – 0.97...1.68 MPa.

scholarly journals ПІДВИЩЕННЯ ЕФЕКТИВНОСТІ ТЕХНОЛОГІЇ ОТРИМАННЯ ВОДНЮ ШЛЯХОМ ВИКОРИСТАННЯ РЕГЕНЕРАЦІЙНОГО КОНТУРУ З РОТОРНО-ПОРШНЕВОЮ РОЗШИРЮВАЛЬНОЮ МАШИНОЮ

2020 ◽  
pp. 12-18
Author(s):  
Михайло Романович Ткач ◽  
Аркадій Юрійович Проскурін ◽  
Олександр Сергійович Митрофанов ◽  
Юрій Миколайович Галинкін
Keyword(s):  
Hydrogen Sulfide ◽  
Hydrogen Production ◽  
Black Sea ◽  
Thermal Power ◽  
Hydraulic Turbine ◽  
Gas Content ◽  
Effective Capacity ◽  
The Black Sea ◽  
Operating Modes ◽  
Production Of Hydrogen

The article discusses a promising technology for the production and safe accumulation of hydrogen from the Black Sea hydrogen sulfide, which includes the following processes: production of hydrogen sulfide from the depths of the Black Sea; separation of hydrogen sulfide and seawater; destruction of hydrogen sulfide to produce a hydrogen-containing gas; separation of hydrogen from a hydrogen-containing gas; safe hydrogen storage; safe transportation of hydrogen. It is proposed to use the regeneration circuit to increase the efficiency of this technology, which includes: an expansion machine for high-pressure hydrogen sulfide, a seawater hydraulic turbine, and a heat pump installation. It is proposed to evaluate the efficiency of the application of the technology for the production and safe accumulation of hydrogen from the Black Sea hydrogen sulfide by effective capacity, which includes: thermal power of hydrogen, power of the regeneration circuit; the power needed to carry out hydrogen production processes. It is proposed to use the 20RPD-4.4/1.75 rotary piston engine as a hydrogen sulfide expansion machine that will satisfy all the requirements. Rational operating modes and limiting values of the efficiency of using the technology for obtaining and safe accumulation of hydrogen from the Black Sea hydrogen sulfide for daily hydrogen production of 200 kg/day were determined depending on the degree of hydrogen sulfide conversion during destruction, the gas content of hydrogen sulfide in seawater and the depth of immersion of the lifting pipeline using the regeneration circuit. The minimum permissible degrees of conversion at which the efficiency of using the technology for obtaining and safe accumulation of hydrogen from the Black Sea hydrogen sulfide for a gas content of hydrogen sulfide of 2.5 m3/m3 at a depth of immersion of the lifting pipeline of 250...1000 m is 0.427 ... 0.413, for 5 m3/m3 – 0.375...0.363, for 7.5 m3/m3 – 0.363...0.350, for 10 m3/m3 – 0.356...0.343. The use of the regeneration circuit allowed us to reduce the minimum permissible degrees of conversion for the gas content of hydrogen sulfide of 2.5...10 m3/m3 at a depth of immersion of the lifting pipeline of 250...1000 m by 0.136 ... 0.069.

CORRELATION OF THE BLACK, MARMARA AND AEGEAN SEAS DURING THE HOLOCENE

2017 ◽  
Author(s):  
Nikolay Esin ◽  
Nikolay Esin ◽  
Vladimir Ocherednik ◽  
Vladimir Ocherednik
Keyword(s):  
Mathematical Model ◽  
Sea Level ◽  
Black Sea ◽  
Aegean Sea ◽  
The Black Sea ◽  
Sea Level Changes ◽  
The Holocene

A mathematical model describing the change in the Black Sea level depending on the Aegean Sea level changes is presented in the article. Calculations have shown that the level of the Black Sea has been repeating the course of the Aegean Sea level for the last at least 6,000 years. And the level of the Black Sea above the Aegean Sea level in the tens of centimeters for this period of time.

scholarly journals On the possible presence of oxygen in the upper sediment layer of the hydrogen sulfide zone in the Black Sea

2019 ◽  
Vol 59 (1) ◽  
pp. 166-169
Author(s):  
P. A. Stunzhas ◽  
M. B. Gulin ◽  
A. G. Zatsepin ◽  
E. A. Ivanova
Keyword(s):  
Black Sea ◽  
Benthic Fauna ◽  
Water Layer ◽  
Bottom Layer ◽  
The Black Sea ◽  
Depth Range ◽  
Sediment Layer ◽  
Bottom Water Layer ◽  
Long Time ◽  
Eukaryotic Organisms

In the northeastern Black Sea the search was performed for living eukaryotic organisms (micro- and meiobenthos) in hypoxic and anoxic conditions as well as measurement of O2 in the bottom water layer and in the upper layer of sediments. The results have shown the presence of a deep maximum abundance of zoobenthos in a depth range of 215–244 m. This aggregation of benthic fauna occupies a layer of 30 m along the vertical. In general, the proportion of active meiobenthos was no greater than 1.5% of the total number of organisms recorded from the sample.The presence of aerobic benthos near the upper boundary of the H2S zone can be explained by: sliding down of sediments from a higher depth; quasi-periodic O2 supply due to fluctuations in the position of the isopycna and/or sinking of waters downslope in the bottom Ekman layer. Also, in the case of physical entry of oxygen into the bottom layer, it can remain for a relatively long time in the upper part of the H2S zone due to the lack of deep Mn+2 flux and reaction with it.

scholarly journals Consorts of gastropod Rapana venosa (Valenciennes, 1846) in the Northern Black Sea. Part I: Porifera, Cnidaria, Bryozoa, Chordata

2017 ◽  
Vol 2 (2) ◽  
pp. 20-33 ◽  
Author(s):  
I. P. Bondarev ◽  
N. K. Revkov
Keyword(s):  
Surface Area ◽  
Coastal Zone ◽  
Black Sea ◽  
The Black Sea ◽  
Bottom Fauna ◽  
Depth Range ◽  
Shell Surface ◽  
Rapana Venosa ◽  
The Core ◽  
Rapa Whelk

Gastropod mollusk-invader Rapana venosa (Valenciennes, 1846) in the 1940s took a free ecological niche terminal predator in benthic communities of the Black Sea shelf and has become an important element of the ecosystem. The ability of rapa whelk to have a devastating impact on the biocenosis filter feeders determines the necessity of constant monitoring of this species populations’ state. The study of rapa whelk showed that the ecological role of this species is not limited to predation. Fairly large shell R. venosa is a solid substrate for alga, attached and restrictedly movable (sedentary) benthic animal organisms, among which mobile free-living forms sometimes find shelter. The aim of the work is to describe specific complex of epibiotic organisms formed on rapa-whelk shells, which is regarded as a consortium, where of R. venosa is the core. To study the consort community of R. venosa a sampling was made in 7 regions of the northern part of the Black Sea: 1 – Mamaia beach, Romania, 2 – the north-western part of the Black Sea (NWBS), Crimean sector, 3 – Sevastopol, 4 – Alupka, 5 – Yalta – Alushta, 6 – Karadag, 7 – the Kerch Strait. The sampling in the coastal zone (less then 15 m depth) was carried out by SCUBA and snorkel diving, deeper (up to 40 m) was used “Ocean-50”grab corer was used. Totally of 856 specimens of R. venosa were collected and analyzed. The main bulk of the material in the amount of 750 specimens of R. venosa was sampled in the coastal zone in Sevastopol vicinity (south-western Crimea) at the depth range of 1.5–10.0 m. The collection of the rapa whelk specimens was carried out totally and each specimen was placed in a separate plastic bag indicating the collection area, depth and biotope. Along with the mollusks sampling, visual observations and photographic fixation of hydrobionts in situ were carried out. Based on the research results the taxonomic list of rapa whelk epibiotic organisms was extended and for the first time the taxonomic composition of the mobile forms permanently or temporarily present in the R. venosa consortium was given. The first part of the investigation provides a list of rapa whelk epibionts taxa relating to four (Porifera, Cnidaria, Bryozoa, Chordata) of the seven detected Phyla with indication of sampling depths and bottom type and comments on the frequency of occurrence, the quantity and of their interaction with the consortium core. Phylum Porifera is represented by 1, Bryozoa – 3 Cnidaria – 2 and Chordata – 4 species. The drilling sponge Pione vastifica was found in all the investigated areas, except region 2 (NWBS), with a frequency of 20 to 90 % and the shell surface area damage was up to 100 % (average 30–35 %). Not numerous representatives of Cnidaria were found singly in the region 3 (Actinia equina) and in the region 5 (Diadumene lineata). Bryozoans are the most common group of animal-consorts of rapa whelk present in all the areas of our research. The frequency of their occurrence ranged from 10 to 100 %, the covering area of the shell surface was from 0 to 85 %. More than 90 % of the total surface area of rapana shell cover with bryozoans and their occurrence is in Cryptosula pallasiana. The second bryozoans’ species on development indices is Conopeum seurati, which was found in areas 3, 6 and 7, where the occurrence was up to 30 % and the coverage was up to 25 %. The other 3 species of bryozoans (Schizomavella auriculata, Bowerbankia imbricata, Hippothoa sp.) were found rarely. Representatives of Chordata – 2 species of ascidians (Botryllus schlosseri, Ciona intestinalis) and 3 species of fish (Diplecogaster bimaculata, Parablennius tentacularis, Scorpaena porcus) were recorded singly in regions 2, 3, 5. For the four Phyla of animal organisms considered the consorts list of R. venosa of the sandy bottom biotopes (10 species) is twice more numerous than that of the rocky eco-form (5 species). The organisms studied are of a different degree and nature of relations with the core consortium from commensalism to parasitism. Generalized information on periphyton and total coverage of rapa whelk shells with epibiotic complex is given. The results of the work show that in the Black Sea R. venosa has become an important element of the ecosystem, increasing biological diversity of the bottom fauna due to the formation of its own consortium complexes of epibiontic organisms.

On the Possible Presence of Oxygen in the Upper Sediment Layer of the Hydrogen Sulfide Zone in the Black Sea

Oceanology ◽  
2019 ◽  
Vol 59 (1) ◽  
pp. 155-157 ◽  
Author(s):  
P. A. Stunzhas ◽  
M. B. Gulin ◽  
A. G. Zatsepin ◽  
E. A. Ivanova
Keyword(s):  
Hydrogen Sulfide ◽  
Black Sea ◽  
The Black Sea ◽  
Sediment Layer

scholarly journals Mathematical model of the Late Pleistocene and Holocene transgressions of the Black Sea

2010 ◽  
Vol 225 (2) ◽  
pp. 180-190 ◽  
Author(s):  
N.V. Esin ◽  
V. Yanko-Hombach ◽  
O.N. Kukleva
Keyword(s):  
Mathematical Model ◽  
Late Pleistocene ◽  
Black Sea ◽  
The Black Sea

scholarly journals CURRENT VIEWS ON THE DIVERSITY AND DISTRIBUTION OF DEEP-WATER MEIOBENTHOS AT THE TURKISH SHELF (BLACK SEA)

2017 ◽  
Vol 14 ◽  
pp. 60-73
Author(s):  
Nelli G. Sergeeva ◽  
Derya Ürkmez
Keyword(s):  
Black Sea ◽  
Deep Water ◽  
Benthic Fauna ◽  
Taxonomic Diversity ◽  
The Black Sea ◽  
Depth Range ◽  
Free Living ◽  
Higher Taxa ◽  
Strong Current ◽  
High Level

Deep-water meiobenthos of Turkish shelf has been evaluated at the Black Sea exit of İstanbul Strait (Bosphorus) and off Sinop peninsula as a result of three scientific cruises. Taxonomic diversity of meiobenthos communities was studied at the Black Sea exit of Bosphorus on a transect with a depth range of 75-300 m. The bottom sediments were collected at the area during two cruises, on board RV "Arar'' (of Turkey) and ''Maria S. Merian" (of Germany) in November 2009 and April 2010, respectively. Data on meiobenthos inhabiting both normoxic and extreme conditions was collected in the studied area and meiobenthos composition included 26 high level taxa. In addition, 2-3 morphotypes of benthic fauna were recorded as incertae sedis, which require further study. The number of higher taxa decreased from 22 to 14-8 when switching from oxygenic conditions (50-125 m) to the anoxic hydrogen sulphide environment (226-300 m). The constant components of meiobenthos included protists (Ciliophora, Gromiidea and soft-shelled Foraminifera), and metazoans were constantly represented by Nematoda and Harpacticoida. In 2011, a quantitative study on meiobenthic composition of the oxic/anoxic interface at the western part off Sinop Peninsula (Southern Black Sea) has also been investigated. The material was collected by ROVs during the expedition (Black Sea Leg) of the exploration vessel (E/V) Nautilus. Results showed that the taxa composition of meiobenthos ranged from 4 to 10 major groups. Free-living marine nematodes were numerically the dominant taxon at each station. Total abundances decreased in parallel to increasing water depth, hence decreasing oxygen levels.

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