SYNTHESIS, CHARACTERISTIC AND ACTIVITY OF NANOSIZED Cu–Me (Me–Co, Zn, Ni) OXIDE SYSTEMS IN CO OXIDATION IN THE PRESENCE OF H2

Nanooxides of Cu–Me composition (Me–Co, Zn, Ni) were synthesized by hydrothermal reduction of metal salts with subsequent calcination and the influence of their properties (size, morphology, structure) on catalytic activity of deep CO oxidation reaction in the presence of H2 was considered. The nanooxides have been characterized by XRD and SEM methods. It was revealed that particles of Cu–Co–O are nanoplates (30–35 nm), and Cu–Zn–O (12.5–20 nm) are nanorods. The SEM method revealed a higher structural organization of the Cu–Сo–O particles than Cu–Zn–O; the growth of nanocrystals is shown by varying the magnification of the scale grid of images. The highest activity of the Cu–Co–O system was found among the mentioned and corresponding individual oxides. The effect of metal (Cu/Co) ratio on the dispersibility and morphology of nanoparticles and their activity has been studied. The non-additive increase in activity is explained by the redox properties of cobalt oxides and the contribution of copper to electronic state of this element. The variation of composition, as well as high dispersibility (30–35 nm) make it possible to reduce the temperature of oxidation beginning (T50%) of CO to less than 1150C