scholarly journals Nutrients Recovery From Aquaculture Wastewater Using Thermally Treated Gastropod Shells

2018 ◽  
pp. 60-68
Author(s):  
Adelagun Ruth Olubukola Ajoke

Various technological options are currently being assessed towards phosphorus recovery from waste streams. Premised on the development of sustainable appropriate technology, gastropod shell was thermally modified in this study to enhance its sorption capacity as a substrate material for P recovery from aquaculture used water. It was revealed that the thermal treatment impacted enhanced defects in the surficial morphologies of the gastropod shell leading to an increased P recovery efficiency; this was contrary to the general view that high P recovery efficiency of calcined calcium – rich materials was as a result of conversion of CaCO3 to CaO. Furthermore, about 60% P recovery was obtained and a substantial recovery of the total Nitrogen was also achieved. There was a significant improvement in the overall characteristics of the treated used water for safe disposal or reuse.

Author(s):  
Changyu Li ◽  
Yanqing Sheng

Abstract Vivianite crystallization is a promising route for phosphorus (P) recovery from P-rich wastewater. However, organic matter (OM) in wastewater may influence vivianite formation. In this study, the effects of four representative OMs, glucose, bovine serum albumin (BSA), humic acid (HA) and sodium alginate (SA), on P recovery by vivianite were investigated. The results showed that P recovery efficiency was inhibited by HA and SA, declining by 3.7% and 12.1% under HA (100 mg/L) and SA (800 mg/L), respectively. BSA, HA and SA affected the aggregated form of vivianite crystals. Vivianite particle size decreased in the presence of HA and SA. Subsequent mechanistic exploration indicated that the complexation between the OM and Fe2+ was the main cause of P recovery efficiency reduction. The coprecipitation of HA and SA with vivianite could reduce the zeta potential on the crystal surface, resulting in a smaller particle size. The nucleation sites provided by BSA and SA could transfer vivianite from single plate-like agglomerate to multilayer plate-like agglomerate. This study provided a better understanding of P recovery by vivianite from OM-rich wastewater.


2019 ◽  
Vol 79 (7) ◽  
pp. 1376-1386 ◽  
Author(s):  
Pidchaya Wongphudphad ◽  
Patiya Kemacheevakul

Abstract Struvite crystallization is an interesting method for the recovery of phosphorus (P) from wastewater. However, the struvite crystals obtained are small, which makes them difficult to separate from wastewater. A continuous reactor for enlarging struvite crystals was developed. Batch-scale experiments were conducted to investigate the optimum factors for the enlargement of struvite crystals. The results of pH experiments showed that P recovery efficiency increased with an increase of pH values (7.6 to 10), while the size of struvite crystals decreased. The results of the Mg:P ratios found that the maximum P recovery efficiency occurred at the maximum ratio of Mg:P. The sizes of struvite crystals were not significantly different. For the variation of temperature values, the results showed that P recovery efficiency and crystal sizes decreased when temperature values increased. Therefore, the optimized conditions for P recovery efficiency and enlargement of struvite crystals for the continuous reactor were pH 8.5 and an Mg:P ratio of 1.2:1 at 30 °C (room temperature). The treated swine wastewater and seawater were continuously fed in at the bottom of the reactor. After 30 days, the size of struvite crystals had increased from 125 μm to 0.83 mm (seven times).


2011 ◽  
Vol 63 (2) ◽  
pp. 339-344 ◽  
Author(s):  
A. Ehbrecht ◽  
S. Schönauer ◽  
T. Fuderer ◽  
R. Schuhmann

P-Recovery from actual sewage by P-RoC-technology (Phosphorus Recovery by Crystallisation of phosphate mineral phases from waste- and processwater) was studied in a pilot scale. Therewith the practicability of the pilot plant was tested and the quality of the so generated products was investigated.


1999 ◽  
Vol 39 (4) ◽  
pp. 495 ◽  
Author(s):  
M. A. Hegney ◽  
I. R. McPharlin

The relative effectiveness of broadcasting compared with band-placement of phosphorus (P) fertilisers (0–480 kg P/ha) was compared using potatoes grown on P-deficient sandy soils over 2 seasons in Western Australia (Karrakatta sand in 1993, experiment 1; and Spearwood sand in 1996, experiment 2). The maximum yield of potatoes when P fertiliser was broadcast and incorporated to 20–25 cm before planting (broadcast) was 17 t/ha higher than when P was placed in 2 bands 5 cm to the side of and below seed piece level (banded) in experiment 1, and 13 t/ha higher in experiment 2. However, higher rates of applied P were required to reach 99% of maximum yield on the broadcast compared with the banded plots in both years (i.e. 174 v. 134 kg/ha in experiment 1, and 279 v. 125 kg/ha in experiment 2). Despite the lower levels of applied P required to achieve maximum yield in the banding treatment, banding P fertiliser for potatoes grown on Karrakatta and Spearwood sands would result in significant economic loss. The higher yield in the broadcast treatment corresponded with significantly (P<0.001) higher P concentrations (about 2-fold) in petioles of youngest fully expanded leaves from 56 to 131 days after sowing. When tubers were 10 mm long, the petiole P concentrations corresponding with 95 and 99% of maximum yield were 1.13 and 1.28%, respectively, for the broadcast P treatments in experiment 1, and 0.95 and 1.11% in experiment 2. The reduced yield in the banded treatments was assumed to be due to P fertiliser toxicity in the soil and not P toxicity in the plant tissue. Phosphorus uptake by tubers was significantly (P<0.001) higher (about 2-fold) when P was broadcast rather than banded, especially at high levels of applied P. Phosphorus recovery efficiency by tubers (P uptake by tubers/P applied, both in kg/ha) was higher when P was broadcast rather than banded, particularly at high levels of applied P (e.g. at 480 kg applied P/ha, recovery efficiency was 0.07 in the broadcast treatment compared with 0.03 in the banded treatment). These results show that, for growers to avoid significant economic loss, broadcast applications of P fertilisers should continue to be recommended for potatoes grown on the low P-fixing, sandy soils of the Swan Coastal Plain.


Resources ◽  
2018 ◽  
Vol 7 (3) ◽  
pp. 54 ◽  
Author(s):  
Saba Daneshgar ◽  
Armando Buttafava ◽  
Arianna Callegari ◽  
Andrea Capodaglio

Phosphorus is a potential environmental pollutant, which could lead to the eutrophication of water bodies. For this reason, wastewater treatment plants worldwide are often designed and operated to eliminate phosphorous from effluents, at substantial cost. At the same time, phosphorus is an essential nutrient for agriculture and, consequently, human life. Data seem to suggest that the world will run out of phosphorus by around 2300, in the best case scenario, although even shorter estimates exist. This situation evokes the need for more efficient phosphorus recovery technologies, in order to meet current water quality requirements and—at the same time—critical future phosphorous needs. Chemical precipitation is the main process for achieving a phosphorus-containing mineral suitable for reuse as a fertilizer, where Struvite is an example of such a product. In this study chemical equilibrium of struvite precipitation was simulated using US Geological Survey (USGS)’ PHREEQC model, and results were compared to laboratory precipitation tests to evaluate struvite recovery efficiency under various conditions. pH had the most significant effect on the results and P recovery of >90% was achieved at pH = 9.5. Simulations indicated that struvite precipitation is affected by the presence of Amorphous Calcium Phosphate (ACP) and calcite in the final product of the process. The model showed great potential for predicting equilibrium conditions, and could be very helpful for future optimization of the process.


2017 ◽  
Vol 52 (9) ◽  
pp. 786-793 ◽  
Author(s):  
Jerusa Maia e Sá ◽  
Cláudia Pozzi Jantalia ◽  
Paulo César Teixeira ◽  
José Carlos Polidoro ◽  
Vinícius de Melo Benites ◽  
...  

Abstract: The objective of this work was to evaluate agronomic and P recovery efficiencies of a granulated organomineral phosphate fertilizer (OMF) produced from poultry litter, compared with those of monoammonium phosphate (MAP), in soils with different textures. The experiment followed a 2x2x4+2 factorial arrangement, with two Oxisols (sandy loam and clay loam textures), two sources of P (OMF and MAP), four levels of P (50, 100, 200, and 400 mg kg-1), besides two control treatments without P application. The treatments were evaluated in 10-kg pots filled with soil, during four successive cultivations of corn without replacing the P absorbed by the plants, in order to evaluate the actual and residual effects of the fertilizers. Available P contents in the soil were higher with the MAP fertilizer in the sandy loam soil, with no significant differences between fertilizers in the clay loam soil. OMF had a greater immediate effect and promoted a higher dry matter yield in the first cultivation; however, the residual effects of the fertilizers did not differ in the other cultivations. P accumulation by plants was not affected by the fertilizer used. OMF had higher agronomic efficiency, but P recovery efficiency did not differ significantly between fertilizers. OMF performance indicates good potential use of poultry litter as fertilizer, in organomineral formulations.


Author(s):  
A.N.Z. Alshehri

In this study, two chamber microbial electrolysis cells (MECs) were used to investigate effect of applied voltage and concentration of influent COD on bio-hydrogen (H2) production and phosphorus (P) recovery. On the cathode chamber P as crystals were precipitated (the maximum was 94%), and verified as struvite, using X-ray diffraction and scanning electron microscopy analysis. Maximum of the H2 production rate was 0.31m3/m3/d. H2 production and P recovery have highly affected by applied voltage according to statistical optimization, while P recovery only had significantly affected by influent COD concentration. The range from 28 to 42%, was the total of energy recovery in the MEC. The current findings demonstrated capability of H2 production and P recovery using MECs technology.Int. J. Appl. Sci. Biotechnol. Vol 6(1): 1-11 


2014 ◽  
Vol 955-959 ◽  
pp. 1983-1986 ◽  
Author(s):  
Tao Zhang ◽  
Ci Fang ◽  
Ping Li ◽  
Rong Feng Jiang

Struvite crystallization is an efficient method for phosphorus recovery from animal manure wastewater. However, large amount of organic coexisting impurities, contained in animal manure wastewater, might influence struvite crystallization. In this study, the effect of typical organic matter contained in animal manure wastewater, such as butyric acid, fulvic acid, tetracycline, on phosphorus recovery was examined. The following conclusions were drawn: (1) with an increase in butyric acid concentration in animal manure wastewater, phosphorus recovery efficiency did not change significantly; (2) with an increase in fulvic acid concentration in animal manure wastewater, phosphorus recovery efficiency decreased obviously; (3) with an increase in tetracycline concentration in animal manure wastewater, phosphorus recovery efficiency decreased slightly.


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