Change in Electrochemical Impedance Spectrum of Al/CFRP Adhesive Lap Joint by High Temperature, High Humidity-Cold Cycle test

A novel heteropoly acid salt, Na6[Ni(Mo11ZrO39)]·20H2O, has been synthesized by the means of acidification and adding the reactants into the solution step by step. The heteropoly compound was characterized by elemental analysis, TGA/DSC, infrared spectrum, ultraviolet spectrum, X-ray diffraction, and SEM. Its protonic conduction was measured by the means of the electrochemical impedance spectrum. The results showed that it belongs to the Keggin type, and its conductivity value was 1.23 × 10–2 S/cm at 23°C when the relative humidity was 60%, and the conductivity enhanced with the elevated temperature. Its proton conduction mechanism was in accordance with vehicle mechanism, and the activation energy was 27.82 kJ/mol.

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Fe-Doped UiO-66 Combined with ZnIn2S4 for Adsorption and Degradation of RhB Under Visible Light

NANO ◽

10.1142/s1793292020500897 ◽

2020 ◽

Vol 15 (07) ◽

pp. 2050089

Author(s):

Litong Niu ◽

Shaoping Hu ◽

Yali Ma ◽

Mingming Wang ◽

Bolin Lv ◽

...

Keyword(s):

Visible Light ◽

Electrochemical Impedance ◽

Diffuse Reflectance Spectroscopy ◽

Photogenerated Electron ◽

Impedance Spectrum ◽

Solvothermal Reaction ◽

Electrochemical Impedance Spectrum ◽

X Ray Diffraction ◽

One Pot ◽

Ft Ir

Novel ZnIn2S4/FeUiO-66 (ZFeU) photocatalyst with different proportion of FeUiO-66 has been successfully prepared by a facile one-pot solvothermal reaction. The as-synthesized nanocomposites have been thoroughly characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), Fourier transform-infrared spectroscopy (FT-IR), UV-Vis diffuse reflectance spectroscopy (UV-Vis DRS), Brunauer–Emmett–Teller (BET) characterization, photoluminescence (PL) analysis and electrochemical impedance spectrum (EIS). The photocatalytic performance of ZFeU nanocomposites for the photodegradation of RhB under visible light irradiation was better than that of ZnIn2S4 and FeUiO-66 alone. The experiment results showed the 20% ZFeU nanocomposites had the best photocatalytic properties. At the same time, a probable mechanism was discussed and it was believed that introduction of FeUiO-66 on ZnIn2S4 would minimize the recombination of photogenerated electron-hole pairs, leading to the enhancement of the photocatalytic activity.

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EIS Study of Corrosion Behavior of Hot-Dip Galvanized Steel in 5% NaCl Aqueous Solution

Advanced Materials Research ◽

10.4028/www.scientific.net/amr.335-336.779 ◽

2011 ◽

Vol 335-336 ◽

pp. 779-782

Author(s):

Shi Quan He ◽

Hui Zhong

Keyword(s):

Aqueous Solution ◽

Equivalent Circuit ◽

Corrosion Behavior ◽

Immersion Time ◽

Electrochemical Impedance ◽

Corrosion Behaviour ◽

Impedance Spectrum ◽

Corrosion Products ◽

Galvanized Steel ◽

Electrochemical Impedance Spectrum

Corrosion behaviour of hot-dip galvanized steel in 5% NaCl aqueous solution was studied by electrochemical impedance spectrum (EIS) technique. The results revealed that corrosion behaviour of hot-dip galvanized steel has a great relationship with immersion time. With the increase of immersion time, corrosion products are constantly changing, and the impedance of corrosion products are different. Parameters fitted by equivalent circuit show that the impedance of corrosion products increased at first, then decreased.

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Quantitative Rapid Analysis Method for Ofloxacin in Raw Milk Based on Molecule-Specific Recognition and Electrochemical Impedance Spectrum

Transactions of the ASABE ◽

10.13031/trans.11465 ◽

2017 ◽

Vol 60 (5) ◽

pp. 1439-1443 ◽

Cited By ~ 11

Author(s):

Guohua Hui ◽

Yibin Ying

Keyword(s):

Quantitative Analysis ◽

Electrochemical Impedance ◽

Impedance Spectrum ◽

Raw Milk ◽

Rapid Analysis ◽

Electrochemical Impedance Spectrum ◽

Analysis Method ◽

Eigen Values ◽

Sodium Tetraphenylboron ◽

Association Complex

Abstract. A quantitative rapid analysis method for ofloxacin detection in raw milk using molecule-specific recognition and an electrochemical impedance spectrum (EIS) technique was investigated in this study. An association complex (AC) formed by a combination of ofloxacin and sodium tetraphenylboron (ST) was used as the active material for electrochemical analysis. A carbon screen-printed electrode (CSE) was modified with the AC to form an electrochemical active membrane for ofloxacin detection. EIS data of pretreated raw milk samples were measured and analyzed with a non-linear bistable stochastic resonance (SR) model. Trace ofloxacin concentrations were characterized by SR output signal-to-noise ratio (SNR) eigen values. An ofloxacin quantitative analysis model was built based on SNR eigen values. Experimental results demonstrated that the proposed method presented good accuracy, repeatability, and recovery. It is a promising way for ofloxacin detection in raw milk. Keywords: Association complex, Electrochemical impedance spectrum, Ofloxacin, Quantitative analysis, Sodium tetraphenylboron.

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Composition and Performance of Nanostructured Zirconium Titanium Conversion Coating on Aluminum-Magnesium Alloys

Journal of Nanomaterials ◽

10.1155/2013/594273 ◽

2013 ◽

Vol 2013 ◽

pp. 1-8 ◽

Cited By ~ 6

Author(s):

Sheng-xue Yu ◽

Rui-jun Zhang ◽

Yong-fu Tang ◽

Yan-ling Ma ◽

Wen-chao Du

Keyword(s):

Corrosion Resistance ◽

Salt Solution ◽

Photoelectron Spectroscopy ◽

Electrochemical Impedance ◽

Impedance Spectrum ◽

Conversion Coating ◽

Mg Alloy ◽

Electrochemical Impedance Spectrum ◽

X Ray ◽

Titanium Salt

Nanostructured conversion coating of Al-Mg alloy was obtained via the surface treatment with zirconium titanium salt solution at 25°C for 10 min. The zirconium titanium salt solution is composed of tannic acid 1.00 g·L−1, K2ZrF60.75 g·L−1, NaF 1.25 g·L−1, MgSO41.0 g/L, and tetra-n-butyl titanate (TBT) 0.08 g·L−1. X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and Fourier transform infrared spectrum (FT-IR) were used to characterize the composition and structure of the obtained conversion coating. The morphology of the conversion coating was obtained by atomic force microscopy (AFM) and scanning electron microscopy (SEM). Results exhibit that the zirconium titanium salt conversion coating of Al-Mg alloy contains Ti, Zr, Al, F, O, Mg, C, Na, and so on. The conversion coating with nm level thickness is smooth, uniform, and compact. Corrosion resistance of conversion coating was evaluated in the 3.5 wt.% NaCl electrolyte through polarization curves and electrochemical impedance spectrum (EIS). Self-corrosion current density on the nanostructured conversion coating of Al-Mg alloy is9.7×10-8A·cm-2, which is only 2% of that on the untreated aluminum-magnesium alloy. This result indicates that the corrosion resistance of the conversion coating is improved markedly after chemical conversion treatment.

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PREPARATION AND ELECTROCHEMICAL PERFORMANCE OF HYBRID MATERIALS CONTAINING HETEROPOLY ACID WITH DAWSON STRUCTURE AND POLYMERS

Functional Materials Letters ◽

10.1142/s1793604712500403 ◽

2012 ◽

Vol 05 (04) ◽

pp. 1250040 ◽

Cited By ~ 4

Author(s):

XIA TONG ◽

WEN WU ◽

SHENGMING ZHOU ◽

QINGYIN WU ◽

FAHE CAO ◽

...

Keyword(s):

Hybrid Materials ◽

Heteropoly Acid ◽

Electrochemical Impedance ◽

Impedance Spectrum ◽

Xrd Analysis ◽

Proton Conduction ◽

Electrochemical Impedance Spectrum ◽

Grotthuss Mechanism ◽

Dawson Structure ◽

Higher Temperature

Highly proton-conducting hybrid materials ( P2W17V /PEG and P2W17V/PEG/SiO2 ) were prepared by heptadecatungstovanadodiphosphoric heteropoly acid with Dawson structure ( P2W17V , 90 wt.%), polyethylene glycol (PEG, 10 wt.% and 5 wt.%) and silica gel ( SiO2 , 0 wt.% and 5 wt.%). The products were characterized by the infrared (IR) spectrum, X-ray powder diffraction (XRD) analysis and electrochemical impedance spectrum (EIS). The result reveals that their conductivity values are 1.02 × 10-2 and 2.58 × 10-2S ⋅ cm-1 at room temperature (26°C) and 75% relative humidity (RH), respectively. Their conductivities increase with higher temperature and these activation energies of proton conduction are 9.51 and 14.95 kJ⋅mol-1, which are lower than that of pure heteropoly acid (32.23 kJ⋅mol-1). These mechanisms of proton conduction for these two materials are Grotthuss mechanism.

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Mathematical Aspects of Electrochemical Impedance Spectrum in Rechargeable Batteries

ECS Meeting Abstracts ◽

10.1149/ma2008-01/26/913 ◽

2008 ◽

Keyword(s):

Electrochemical Impedance ◽

Impedance Spectrum ◽

Rechargeable Batteries ◽

Electrochemical Impedance Spectrum

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Effect of Surface Pre-Treatments on the Formation and Degradation Behaviour of a Calcium Phosphate Coating on Pure Magnesium

Coatings ◽

10.3390/coatings9040259 ◽

2019 ◽

Vol 9 (4) ◽

pp. 259 ◽

Cited By ~ 5

Author(s):

Jiaping Han ◽

Carsten Blawert ◽

Shawei Tang ◽

Junjie Yang ◽

Jin Hu ◽

...

Keyword(s):

Corrosion Resistance ◽

Calcium Phosphate ◽

Electrochemical Impedance ◽

Impedance Spectrum ◽

Barrier Properties ◽

Calcium Phosphate Coating ◽

Electrochemical Impedance Spectrum ◽

Degradation Behaviour ◽

Pre Treatment ◽

Plasma Electrolytic

Calcium phosphate (CaPh) coatings are considered promising surface treatments for Mg-based implants. Normally, the phase conversion process of CaPh compounds occurs during immersion in simulated body fluid (SBF) and allows the easy penetration of a corrosive medium. To solve the issue, pre-treatment is often performed, creating an effective barrier that further improves the corrosion resistance of the underlying Mg. In the present work three pre-treatments including hydrothermal treatment, anodization, and plasma electrolytic oxidation (PEO) were performed on pure Mg prior to CaPh deposition. Results indicated that the composition, morphology, and thickness of the CaPh coatings were strongly influenced by the pre-treatments. Dicalcium phosphate dihydrate (DCPD) was formed on PEO surface, whilst DCPD and hydroxyapatite (HA) were deposited on hydrothermally prepared and anodized surfaces. HA could be deposited on the studied samples during immersion in SBF. The electrochemical impedance spectrum indicated that CaPh coating combined with PEO pre-treatment had the highest corrosion resistance at 120 h due to the superior barrier properties conferred by the PEO layer.

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Corrosion Properties of Cold Spray Zn-25Al Coating in Marine Environment

Applied Mechanics and Materials ◽

10.4028/www.scientific.net/amm.148-149.345 ◽

2011 ◽

Vol 148-149 ◽

pp. 345-348

Author(s):

Qing Jun Zhu ◽

Kai Wang

Keyword(s):

Cold Spray ◽

Corrosion Potential ◽

Electrochemical Impedance ◽

Impedance Spectrum ◽

Electrochemical Impedance Spectrum ◽

Natural Seawater ◽

Corrosion Properties ◽

Dissolution Zone ◽

Polarization Test ◽

Protection Potential

Zn-25Al coatings were prepared by cold spray on mild carbon steel Q235. The coatings were studied by potentiodynamic polarization test, corrosion potentials and electrochemical impedance spectrum in natural seawater. The results show that the Ecorr of Zn-25Al coating is -1.01V (SCE) and the Ecorr of Q235 is -0.65V (SCE) at the beginning of the immersion. Self-corrosion potential of Zn-25Al coating is lower than that of Q235. The coatings turn to activity anodic dissolution zone when the potential reaches -1.05V. The coatings changes to passivation zone after the potential reaches -1.01V and the current intensities increase slightly with the potential increasing quickly. Zn-25Al coatings can provide lower protection potential and promising current to protect Q235 from corrosion.

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