scholarly journals The Inhibition Action of Viscum Album Extract on theCorrosion of Carbon Steel in Hydrochloric Acid Solution

2021 ◽  
Vol 11 (6) ◽  
pp. 14344-14358

Corrosion rate of carbon steel (CS) in 1M HCl was examined in the absence and presence of Viscum album plant extract as a corrosion inhibitor using weight loss, polarization, and impedance techniques. The effect of temperature and extract dose was studied using a weight loss test. The outcome data gained displayed that Viscum album extract plays as an inhibitor for CS in HCl and reduces the corrosion rate. The higher inhibition efficacy reached 96.3% for Viscum album at greater inhibitor doses (300 ppm) and temperature. Polarization data revealed that this extract acts as a mixed kind inhibitor. The surface analysis of CS was checked by different methods, which showed the formation of extract film on the CS surface. The adsorption of Viscum album plant extract was found to obey the Temkin model, and the data of adsorption free energy was more negative than -40 kJ/mol, which means that the adsorption is chemical.

2014 ◽  
Vol 2014 ◽  
pp. 1-7 ◽  
Author(s):  
Arman Abdullah ◽  
Nordin Yahaya ◽  
Norhazilan Md Noor ◽  
Rosilawati Mohd Rasol

Various cases of accidents involving microbiology influenced corrosion (MIC) were reported by the oil and gas industry. Sulfate reducing bacteria (SRB) have always been linked to MIC mechanisms as one of the major causes of localized corrosion problems. In this study, SRB colonies were isolated from the soil in suspected areas near the natural gas transmission pipeline in Malaysia. The effects of ATCC 7757 and consortium of isolated SRB upon corrosion on API 5L X-70 carbon steel coupon were investigated using a weight loss method, an open circuit potential method (OCP), and a potentiodynamic polarization curves method in anaerobic conditions. Scanning electron microscopy (SEM) and energy dispersive X-ray spectroscopy (EDS) were then used to determine the corrosion morphology in verifying the SRB activity and corrosion products formation. Results from the study show that the corrosion rate (CR) of weight loss method for the isolated SRB is recorded as 0.2017 mm/yr compared to 0.2530 mm/yr for ATCC 7757. The Tafel plot recorded the corrosion rate of 0.3290 mm/yr for Sg. Ular SRB and 0.2500 mm/yr forDesulfovibrio vulgaris. The results showed that the consortia of isolated SRB were of comparable effects and features with the single ATCC 7757 strain.


ROTOR ◽  
2017 ◽  
Vol 10 (1) ◽  
pp. 13
Author(s):  
Naufan Arviansyah ◽  
Sumarji Sumarji ◽  
Digdo Listyadi Setyawan

This research have a purpuse to know corrosion rate in pipe X52 and A53 at oil sludge media caused BS and W. Corrosion is a damage of metal that occurs because reaction between metal with environtment and produce unwanted of corrosion product. Pipe X52 and A53 is a type of low carbon steel that use for fluid transportation system in industry. Oil sludge is a sediment of crude oil from main gathering storage and containing variouses elements. Oil sludge have a one of element is Basic Sediment and Water that is can make corrosion happen to distribution pipes. Measuring Method used in this research is weight loss method. The result of corrosion rate in Oil Sludge media containing 30,17% BS and W for pipe A53 is 1,64 x 10-2 mmpy and the result for pipa X52 is 2,47 x 10-2 mmpy. The result of corrosion rate in Oil Sludge media containing 60,67% BS and W for pipe A53 is 2,12 x 10-2 mmpy and for pipe X52 the result is 3,13 x 10-2 mmpy. The result of this research showed pipe A53 have more resistance than pipe X52. The corrosion is classified as uniform corrosion. Keywords : A53, Weight Loss, Oil Sludge, X52.


Author(s):  
Gina Genoveva ISTRATE ◽  
Alina Crina MUREȘAN

In this paper the corrosion behavior of different materials has been evaluated based on exposure in seawater. The laboratory immersion test technique has been applied to evaluate the effect of seawater on the corrosion behavior of different materials. In three sets of experiments, carbon steels (A681 Type O7), austenitic stainless steels (316L) and aluminium alloys (Al5083) were utilized. The specimens were fixed fully submerged in seawater. The corrosion process was evaluated using weight loss method, open-circuit potential measurements (OCP) and polarization techniques. To determine gravimetric index and the rate of penetration, samples were immersed in corrosive environment for 89 days and weighed periodically. The electrochemical experiments were conducted with a Potentiostat/Galvanostat (PGP 201) analyzer. It was connected to a PC. The Voltamaster software was used for electrochemical data analysis. A three-electrode cell composed of a specimen as a working electrode, Pt as counter electrode, and saturated calomel electrode (SCE) (Hg (l)/ Hg2Cl2 (s)) as a reference electrode were used for the tests. The weight loss tests revealed the lowest corrosion rate values for stainless steel and aluminium alloys, indicating a beneficial use for these materials in marine environments. The potentiodynamic method shows that the lowest corrosion rate in seawater (2.8 μm /year) was obtained for the Al5083 alloy, and the highest value of the corrosion rate (41.67 μm/year) for A681 carbon steel.


REAKTOR ◽  
2017 ◽  
Vol 17 (4) ◽  
pp. 177
Author(s):  
Adhi Setiawan ◽  
Nora Amelia Novitrie ◽  
Agung Nugroho ◽  
W Widiyastuti

The use of biodiesel leads to corrosion of automotive material, which can potentially shorten engine lifetime. The study aims to investigate the effect of temperature and contact time on the corrosion characteristics of carbon steel upon exposure to biodiesel synthesized from used frying oil. The corrosion rate of carbon steel was analyzed based on weight loss measurement according to the standard of ASTM G31 as affected by temperature and contact time. The immersion temperatures used in this study were 30oC, 40oC, and 70o, respectively. The contact times studied were 30 days, 40 days, and 50 days respectively. The results show that the increase of temperature and contact time of biodiesel on carbon steel surface speeds up the corrosion rate. Maximum corrosion rate (0.083 mmy) was observed on the carbon steel contacted to biodiesel at 70oC for 50 days. The SEM results showed an irregular shape of the corroded carbon steel surface. XRD / FTIR analysis of carbon steel samples show the presence of peaks, detected as Fe2O3, FeO(OH) and Fe2O2CO3, as the corrosion products. Keywords: biodiesel; carbon steel; corrosion; FAME; used frying oil


2014 ◽  
Vol 2014 ◽  
pp. 1-15 ◽  
Author(s):  
A. S. Fouda ◽  
A. A. Attia ◽  
A. A. Negm

Corrosion inhibitive performance of some thiophene derivatives during the acidic corrosion of carbon steel surface in 1 M HCl was investigated by chemical technique (weight loss) and electrochemical techniques (potentiodynamic polarization, electrochemical frequency modulation, and electrochemical impedance spectroscopy). The effect of temperature on the corrosion rate was investigated by the weight loss method, and some thermodynamic parameters for corrosion and adsorption processes were determined and discussed. The results show that the inhibition efficiency increased with the increase in inhibitor concentration and temperature. The adsorption of thiophene derivatives on the carbon steel surface obeys Langmuir adsorption isotherm. The obtained results indicated that the investigated compounds are chemically adsorbed on the steel surface. Potentiodynamic polarization studies showed that these compounds are mixed-type inhibitors and the results obtained from the techniques are in good agreement.


2020 ◽  
Vol 8 (2) ◽  
pp. 159-168
Author(s):  
Ismi Nurhayati ◽  
◽  
Pulung Karo Karo ◽  
Syafriadi Syafriadi ◽  
◽  
...  

Research has been conducted on the effectiveness of maja fruit skin extract as an inhibitor of carbon steel AISI 1020 in a corrosive medium NaCl 3% with variations in immersion time. The samples carbon steel AISI 1020 were immersed in corrosive medium NaCl 3% without being given and given the inhibitor of maja skin extract with a concentration of 0.8% for 5, 15, 25, 35, and 45 days. Calculation of reduction in corrosion rate is carried out by the method of weight loss. The results showed that the addition of the maja fruit skin extract inhibitor was effective in reducing the corrosion rate of the sample with the greatest efficiency at 35 days immersion, which was equal to 72.35%. The results of XRD characterization show that the phase formed is pure Fe and Fe3O4 phase which is a corrosion product is immersed without inhibitor. The results of SEM characterization showed that the microstructure of the surface of the sample after immersion was there were cracks, holes, and lumps which indicated that the sample had been corroded. The results of EDS characterization show that in the soaked sample there were corrosion products in the form of FeO compounds whose magnitude increased every time immersion.


2018 ◽  
Vol 15 (1) ◽  
pp. 6136-6141 ◽  
Author(s):  
Mouayed yousif Kadhum ◽  
Chasib Khaiber Bkhakh ◽  
Muayad Hasan Albehadili

 The effect of increasing pH value in the corrosion of iron alloy type (C1010) was studied in the presence of different pH solutions of sodium hydroxide dissolved in industrial water at 35ËšC  and it was found that the corrosion rate of iron alloy was less at pH of 9.5 . This result was proved by measuring some thermodynamic parameters such as corrosion current and covered surface area that pertain to corrosion using weight loss electrical (Tafel plot ) methods . Also the effect of temperature on the rate of corrosion at ( 25ËšC , 35ËšC and 45ËšC ) at different pH was studied and it was found that the rate of corrosion is increased with increasing the temperature at the same pH.


2019 ◽  
Vol 3 (1) ◽  
pp. 18-23
Author(s):  
Nur Bazilah Ishak ◽  

Microbiologically Influenced Corrosion (MIC) caused by the presence of Sulfate-reducing bacteria (SRB) is a big concern in heavy industries. Pipeline infrastructure may experience severe metal loss due to corrosion induced by the species and can potentially lead to catastrophic failure. By studying SRB growth condition, important parameter can be controlled to prevent or slow down a corrosion process. This study discussed on the effect of pH value to the corrosion growth rate on API 5L X70 low carbon steel subjected to outer part of underground pipeline. In this research, the type of SRB that's been used is Postgate C of Desulfovibrio Desulfuricans. There are 80 numbers of samples prepared with various pH value and temperature, which each of the samples contains two coupon steel immersed in the medium together with SRB for 7, 14, 21 and 28 days. The process in determining weight loss is analyzed and the corrosion rate for each steel sample is identified by weight loss. The result is plotted and analyzed, the particular pH values and temperature affect the growth of SRB in the medium where the existence of SRB could accelerate the corrosion rate towards the steel surface of API X-70. The samples are exposed to SRB in days’ time. This experiment aims to determine the optimum temperature for SRB growth and demonstrate the corrosion rate simulation using One-Factor-at-A-Time method (OFAT) method. The consequences of SRB activity, it is shown that pitting corrosion produced on the surface of steel. In fact, the sulphur element is identified as one of the corrosion products due to SRB activity.


Author(s):  
Osita Obiukwu ◽  
Ignatius Opara ◽  
Chukwuemeka Asoluka

Extract of various plants; Okazi leaf (Gnetum africanum), Utazi leaf (Gongronema latifolium) and Elizabeth leaf (Chromolena odaratum) was investigated as corrosion inhibitor of stainless steel in 1M HCL and H2SO4 using conventional weight loss. Results were obtained at intervals of 24, 48, 72 and 96 hours respectively. The corrosion rate and inhibition efficiency were calculated. The results revealed that all the plant extract act as inhibitors in the acid environments while Elizabeth leaf (Chromolena odaratum) proved to be better corrosion inhibitor than Okazi plant (Gnetumafricanum) and Utazi plant (Gongronemalatifolium) extract as it recorded the highest inhibition efficiency of 90.95% in 1M HCL for 20 ml concentration.


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