scholarly journals Isotopically Light Cd in Sediments Underlying Oxygen Deficient Zones

2021 ◽  
Vol 9 ◽  
Author(s):  
Lena Chen ◽  
Susan H. Little ◽  
Katharina Kreissig ◽  
Silke Severmann ◽  
James McManus
Keyword(s):  
Water Column ◽  
Continental Margin ◽  
Solid Phase ◽  
Isotope Composition ◽  
Accumulation Rate ◽  
Cadmium Sulphide ◽  
Crustal Material ◽  
Deep Seawater ◽  
Complex Particle ◽  
Cd Isotopes

Cadmium is a trace metal of interest in the ocean partly because its concentration mimics that of phosphate. However, deviations from the global mean dissolved Cd/PO4 relationship are present in oxygen deficient zones, where Cd is depleted relative to phosphate. This decoupling has been suggested to result from cadmium sulphide (CdS) precipitation in reducing microenvironments within sinking organic matter. We present Cd concentrations and Cd isotope compositions in organic-rich sediments deposited at several upwelling sites along the northeast Pacific continental margin. These sediments all have enriched Cd concentrations relative to crustal material. We calculate a net accumulation rate of Cd in margin settings of between 2.6 to 12.0 × 107 mol/yr, higher than previous estimates, but at the low end of a recently published estimate for the magnitude of the marine sink due to water column CdS precipitation. Cadmium in organic-rich sediments is isotopically light (δ114/110CdNIST-3108 = +0.02 ± 0.14‰, n = 26; 2 SD) compared to deep seawater (+0.3 ± 0.1‰). However, isotope fractionation during diagenesis in continental margin settings appears to be small. Therefore, the light Cd isotope composition of organic-rich sediments is likely to reflect an isotopically light source of Cd. Non-quantitative biological uptake of light Cd by phytoplankton is one possible means of supplying light Cd to the sediment, which would imply that Cd isotopes could be used as a tracer of past ocean productivity. However, water column CdS precipitation is also predicted to preferentially sequester light Cd isotopes from the water column, which could obfuscate Cd as a tracer. We also observe notably light Cd isotope compositions associated with elevated solid phase Fe concentrations, suggesting that scavenging of Cd by Fe oxide phases may contribute to the light Cd isotope composition of sediments. These multiple possible sources of isotopically light Cd to sediments, along with evidence for complex particle cycling of Cd in the water column, bring into question the straightforward application of Cd isotopes as a paleoproductivity proxy.

Dissolution and recrystallization in modern shelf carbonates: evidence from pore water and solid phase chemistry

1993 ◽  
Vol 344 (1670) ◽  
pp. 27-36 ◽  
Keyword(s):  
Organic Matter ◽  
Pore Water ◽  
Solid Phase ◽  
Chemical Exchange ◽  
Isotope Composition ◽  
Geochemical Data ◽  
Carbonate Sediments ◽  
Pore Waters ◽  
Carbonate Minerals ◽  
Carbonate Production

We present an overview of geochemical data from pore waters and solid phases that clarify earliest diagenetic processes affecting modern, shallow marine carbonate sediments. Acids produced by organic matter decomposition react rapidly with metastable carbonate minerals in pore waters to produce extensive syndepositional dissolution and recrystallization. Stoichiometric relations among pore water solutes suggest that dissolution is related to oxidation of H 2 S which can accumulate in these low-Fe sediments. Sulphide oxidation likely occurs by enhanced diffusion of O 2 mediated by sulphide-oxidizing bacteria which colonize oxic/anoxic interfaces invaginating these intensely bioturbated sediments. Buffering of pore water stable isotopic compositions towards values of bulk sediment and rapid 45 Ca exchange rates during sediment incubations demonstrate that carbonate recrystallization is a significant process. Comparison of average biogenic carbonate production rates with estimated rates of dissolution and recrystallization suggests that over half the gross production is dissolved and/or recrystallized. Thus isotopic and elemental composition of carbonate minerals can experience significant alteration during earliest burial driven by chemical exchange among carbonate minerals and decomposing organic matter. Temporal shifts in palaeo-ocean carbon isotope composition inferred from bulk-rocks may be seriously compromised by facies-dependent differences in dissolution and recrystallization rates.

scholarly journals Isotope Climatic Record Over The Last 2.5 KA from Dome C, Antarctica, Ice cores

1982 ◽  
Vol 3 ◽  
pp. 17-22 ◽  
Author(s):  
J. P. Benoist ◽  
J. Jouzel ◽  
C. Lorius ◽  
L. Merlivat ◽  
M. Pourchet
Keyword(s):  
Isotope Composition ◽  
Accumulation Rate ◽  
Maximum Amplitude ◽  
Ice Cores ◽  
Ice Age ◽  
Pass Filter ◽  
Low Pass Filter ◽  
Temperature Changes ◽  
Low Pass ◽  
Climatic Record

Data on climatic changes over thousands of years is needed for a better understanding of the shorter term variations which are of interest to man. For this purpose we measured the isotope composition (δD‰) of two adjacent ice cores drilled in the Dome C area. The time scale was established using the remarkably constant mean annual accumulation rate (37 kg m−2) determined by various techniques. The detailed isotope records were smoothed to filter out the δ value fluctuations not directly related to local temperature changes. With respect to conditions over the last 2.5 ka, the combined smoothed δ curve indicates a cooler climate from about 1800 to 1200 AD and a slightly warmer period from about 1200 to 700 AD. These periods may well correspond to the suggested world-wide Little Ice Age and medieval warm phase. Using the present δD‰/T°C measured at the surface, the maximum amplitude for these two periods, after smoothing with a low pass filter of 512 a, is approximately -0.35 and +0.3°C, respectively.

scholarly journals Chromium isotope cycling in the water column and sediments of the Peruvian continental margin

2019 ◽  
Vol 257 ◽  
pp. 224-242 ◽  
Author(s):  
S. Bruggmann ◽  
F. Scholz ◽  
R.M. Klaebe ◽  
D.E. Canfield ◽  
R. Frei
Keyword(s):  
Water Column ◽  
Continental Margin

scholarly journals Experimental Melting of Hydrothermally Altered Rocks: Constraints for the Generation of Low-δ18O Rhyolites in the Central Snake River Plain

2019 ◽  
Vol 60 (10) ◽  
pp. 1881-1902 ◽  
Author(s):  
Juliana Troch ◽  
Ben S Ellis ◽  
Chris Harris ◽  
Peter Ulmer ◽  
Anne-Sophie Bouvier ◽  
...  
Keyword(s):  
Hydrothermal Alteration ◽  
Large Scale ◽  
Country Rock ◽  
Isotope Composition ◽  
Snake River Plain ◽  
Snake River ◽  
Crustal Material ◽  
Yellowstone Hotspot ◽  
River Plain ◽  
Source Materials

Abstract Quantifying the relative contributions of crustal versus mantle-derived melt is important for understanding how silicic magmas are generated, stored, and interact with country rock in trans-crustal magmatic systems. Low-δ18O rhyolitic ignimbrites and lavas erupted during Miocene volcanic activity in the central Snake River Plain (14–6 Ma) have been inferred to be the result of large-scale partial or bulk melting of pre-existing hydrothermally altered lithologies of the Idaho batholith and Challis volcanic field. In this study, we assess the melting behaviour of heterogeneously altered source materials via partial melting experiments over a range of run times at conditions of 750–1000°C and 1–2 kbar, and apply our observations to current models for the petrogenesis of low-δ18O rhyolites along the Yellowstone hotspot track. Partial melt produced in the experiments inherits the bulk oxygen isotope composition from hydrothermally altered peraluminous source materials independent of the melt fraction, excluding the possibility for preferential, disequilibrium melting of 18O-depleted mineral phases during incipient melting. We propose a new model to explain the generation of low-δ18O rhyolites in the central Snake River Plain, whereby mantle-derived magmas assimilate ∼30–40% of crustal material that was hydrothermally altered at high temperatures in two stages: (1) a preceding episode of hydrothermal alteration during intrusion of Eocene plutons (‘pre-existing source’); (2) syn-magmatic hydrothermal alteration within a nested caldera complex. During assimilation, dilution of peraluminous crustal lithologies with mantle-derived magma maintains the metaluminous character of rhyolites erupted along the Yellowstone hotspot track. These results link previous models favouring melting of either pre-existing or syn-magmatically altered lithologies for the generation of low-δ18O rhyolites along the Yellowstone hotspot track and provide direct experimental observation of the chemical processes occurring during assimilation processes in magmatic environments.

scholarly journals Control of the geomorphology and gas hydrate extent on widespread gas emissions offshore Romania

2017 ◽  
Vol 188 (4) ◽  
pp. 26 ◽  
Author(s):  
Vincent Riboulot ◽  
Antonio Cattaneo ◽  
Carla Scalabrin ◽  
Arnaud Gaillot ◽  
Gwénaël Jouet ◽  
...  
Keyword(s):  
Water Column ◽  
Black Sea ◽  
Gas Hydrate ◽  
Accumulation Rate ◽  
Sediment Accumulation ◽  
The Black Sea ◽  
North East ◽  
Bottom Simulating Reflectors ◽  
Gas Flares ◽  
Sea Fan

The Romanian sector of the Black Sea deserves attention because the Danube deep-sea fan is one of the largest sediment depositional systems worldwide and is considered the world's most isolated sea, the largest anoxic water body on the planet and a unique energy-rich sea. Due to the high sediment accumulation rate, presence of organic matter and anoxic conditions, the Black sea sediments offshore the Danube delta is rich in gas and thus shows Bottom Simulating Reflectors (BSR). The cartography of the BSR over the last 20 years, exhibits its widespread occurrence, indicative of extensive development of hydrate accumulations and a huge gas hydrate potential. By combining old and new datasets acquired in 2015 during the GHASS expedition, we performed a geomorphological analysis of the continental slope north-east of the Danube canyon compared with the spatial distribution of gas seeps in the water column and the predicted extent of the gas hydrate stability zone. This analysis provides new evidence of the role of geomorphological setting and gas hydrate extent in controlling the location of the observed gas expulsions and gas flares in the water column. Gas flares are today considered an important source of the carbon budget of the oceans and, potentially, of the atmosphere.

scholarly journals Effects of eutrophication on sedimentary organic carbon cycling in five temperate lakes

2019 ◽  
Vol 16 (19) ◽  
pp. 3725-3746 ◽  
Author(s):  
Annika Fiskal ◽  
Longhui Deng ◽  
Anja Michel ◽  
Philip Eickenbusch ◽  
Xingguo Han ◽  
...  
Keyword(s):  
Organic Carbon ◽  
Water Column ◽  
Trophic State ◽  
Microbial Respiration ◽  
Accumulation Rate ◽  
Eutrophic Lake ◽  
Accumulation Rates ◽  
Artificial Lake ◽  
Eutrophic Lakes ◽  
Lake Ecosystems

Abstract. Even though human-induced eutrophication has severely impacted temperate lake ecosystems over the last centuries, the effects on total organic carbon (TOC) burial and mineralization are not well understood. We study these effects based on sedimentary records from the last 180 years in five Swiss lakes that differ in trophic state. We compare changes in TOC content and modeled TOC accumulation rates through time to historical data on algae blooms, water column anoxia, wastewater treatment, artificial lake ventilation, and water column phosphorus (P) concentrations. We furthermore investigate the effects of eutrophication on rates of microbial TOC mineralization and vertical distributions of microbial respiration reactions in sediments. Our results indicate that the history of eutrophication is well recorded in the sedimentary record. Overall, eutrophic lakes have higher TOC burial and accumulation rates, and subsurface peaks in TOC coincide with past periods of elevated P concentrations in lake water. Sediments of eutrophic lakes, moreover, have higher rates of total respiration and higher contributions of methanogenesis to total respiration. However, we found strong overlaps in the distributions of respiration reactions involving different electron acceptors in all lakes regardless of lake trophic state. Moreover, even though water column P concentrations have been reduced by ∼ 50 %–90 % since the period of peak eutrophication in the 1970s, TOC burial and accumulation rates have only decreased significantly, by ∼ 20 % and 25 %, in two of the five lakes. Hereby there is no clear relationship between the magnitude of the P concentration decrease and the change in TOC burial and accumulation rate. Instead, data from one eutrophic lake suggest that artificial ventilation, which has been used to prevent water column anoxia in this lake for 35 years, may help sustain high rates of TOC burial and accumulation in sediments despite water column P concentrations being strongly reduced. Our study provides novel insights into the influence of human activities in lakes and lake watersheds on lake sediments as carbon sinks and habitats for diverse microbial respiration processes.

scholarly journals Technical Note: Silica stable isotopes and silicification in a carnivorous sponge \\textit{Asbestopluma} sp.

2014 ◽  
Vol 11 (12) ◽  
pp. 16573-16597
Author(s):  
K. R. Hendry ◽  
G. E. A. Swann ◽  
M. J. Leng ◽  
H. J. Sloane ◽  
C. Goodwin ◽  
...  
Keyword(s):  
Isotopic Composition ◽  
Oxygen Isotope ◽  
Isotope Composition ◽  
Isotopic Signature ◽  
The Body ◽  
Oxygen Isotope Composition ◽  
Silicon Isotope ◽  
Deep Seawater ◽  
Differential Distribution ◽  
Sponge Spicule

Abstract. The stable isotope composition of benthic sponge spicule silica is a potential source of palaeoceanographic information about past deep seawater chemistry. The silicon isotopic composition of spicules has been shown to relate to the silicic acid concentration of ambient water, although existing calibrations do exhibit a degree of scatter in the relationship. Less is known about how the oxygen isotope composition of sponge spicule silica relates to environmental conditions during growth. Here, we investigate the biological vital effects on silica silicon and oxygen isotope composition in a carnivorous sponge, Asbestopluma sp., from the Southern Ocean. We find significant variations in silicon and oxygen isotopic composition within the specimen that appear related to unusual spicule silicification. The largest variation in both isotope systems was associated to the differential distribution of an unconventional, hypersilicified spicule type (desma) along the sponge body. The absence of an internal canal in the desmas suggests an unconventional silicification pattern leading to an unusually heavy isotopic signature. Additional internal variability derives from a systematic offset between the peripheral skeleton of the body having systematically a higher isotopic composition than the internal skeleton. A simplified silicon isotope fractionation model, in which desmas were excluded, suggests that the lack of a system for seawater pumping in carnivorous sponges favours a low replenishment of dissolved silicon within the internal tissues, causing kinetic fractionation during silicification that impacts the isotopic signature of the internal skeleton. Analysis of multiple spicules should be carried out to "average out" any artefacts in order to produce more robust downcore measurements.

scholarly journals Carbon and nitrogen isotope evidence for widespread presence of anoxic intermediate waters before and during the Permian-Triassic mass extinction

2021 ◽  
Author(s):  
Baojin Wu ◽  
Genming Luo ◽  
Michael M. Joachimski ◽  
Paul B. Wignall ◽  
Lidan Lei ◽  
...  
Keyword(s):  
Shallow Water ◽  
Water Column ◽  
Water Depth ◽  
Mass Extinction ◽  
Isotope Composition ◽  
Nitrogen Isotope ◽  
Intermediate Water ◽  
Negative Shift ◽  
Intermediate Waters ◽  
Direct Killing

The largest mass extinction since the advent of animals occurred during the Permian-Triassic (P-Tr) transition, ca. 252 Ma, and is commonly attributed to the eruption of the Siberian Traps large igneous province. However, the direct killing mechanism is still debated. In this study, we investigated marine redox conditions of the intermediate water column that most organisms inhabit with special attention to the time interval before the onset of the mass extinction. The carbon isotope composition of carbonate and organic carbon (δ13Ccarb and δ13Corg) as well as the nitrogen isotope composition of bulk nitrogen (δ15N) were analyzed in four P-Tr boundary sequences (Zhongli, Jianshi, Ganxi, and Chaotian sections), which record a transect from a shallow water carbonate platform to a deep water, lower ramp slope in South China. δ13Ccarb shows a distinct negative shift in all sections and displays a clear, 2−4‰, decreasing gradient accompanying an increase in water depth both before and after the mass extinction. A distinct negative shift in δ15N is observed in the shallow water Zhongli section, whereas a minor negative shift is present in the three deeper water sections. Before the mass extinction, the δ15N values from shallow water sections are higher than those from deeper waters. The low δ15N values close to 0‰ in deeper water sections suggest that microbial nitrogen fixation was the predominant source of biologically available nitrogen before the onset of the mass extinction. Thus, the water depth- dependent gradient in δ13Ccarb and δ15N suggests that an oxygen-deficient intermediate water column was already present before the mass extinction. The uniform δ15N values around 0‰ accompanying the onset of the mass extinction reveal that anoxic intermediate waters expanded into shallow waters. Meanwhile, the distinct positive shift in δ13Corg observed in upper ramp slope sections, i.e., the Jianshi and Ganxi sections, suggests that a euxinic photic zone was at least episodically present in the earliest Triassic. The temporal coincidence between the expansion of intermediate water column anoxia and the onset of the P-Tr mass extinction supports the hypothesis that marine anoxia was a direct killing mechanism.

scholarly journals Controls on the Silicon Isotope Composition of Diatoms in the Peruvian Upwelling

2021 ◽  
Vol 8 ◽  
Author(s):  
Patricia Grasse ◽  
Kristin Haynert ◽  
Kristin Doering ◽  
Sonja Geilert ◽  
Janice L. Jones ◽  
...  
Keyword(s):  
Water Column ◽  
Silicic Acid ◽  
Isotope Composition ◽  
Size Fraction ◽  
Strong Relationship ◽  
Silicon Isotope ◽  
Main Driver ◽  
Subsurface Waters ◽  
Minimum Zone ◽  
Si Isotope

The upwelling area off Peru is characterized by exceptionally high rates of primary productivity, mainly dominated by diatoms, which require dissolved silicic acid (dSi) to construct their frustules. The silicon isotope compositions of dissolved silicic acid (δ30SidSi) and biogenic silica (δ30SibSi) in the ocean carry information about dSi utilization, dissolution, and water mass mixing. Diatoms are preserved in the underlying sediments and can serve as archives for past nutrient conditions. However, the factors influencing the Si isotope fractionation between diatoms and seawater are not fully understood. More δ30SibSi data in today’s ocean are required to validate and improve the understanding of paleo records. Here, we present the first δ30SibSi data (together with δ30SidSi) from the water column in the Peruvian Upwelling region. Samples were taken under strong upwelling conditions and the bSi collected from seawater consisted of more than 98% diatoms. The δ30SidSi signatures in the surface waters were higher (+1.7‰ to +3.0‰) than δ30SibSi (+1.0‰ to +2‰) with offsets between diatoms and seawater (Δ30Si) ranging from −0.4‰ to −1.0‰. In contrast, δ30SidSi and δ30SibSi signatures were similar in the subsurface waters of the oxygen minimum zone (OMZ) as a consequence of a decrease in δ30SidSi. A strong relationship between δ30SibSi and [dSi] in surface water samples supports that dSi utilization of the available pool (70 and 98%) is the main driver controlling δ30SibSi. A comparison of δ30SibSi samples from the water column and from underlying core-top sediments (δ30SibSi_sed.) in the central upwelling region off Peru (10°S and 15°S) showed good agreement (δ30SibSi_sed. = +0.9‰ to +1.7‰), although we observed small differences in δ30SibSi depending on the diatom size fraction and diatom assemblage. A detailed analysis of the diatom assemblages highlights apparent variability in fractionation among taxa that has to be taken into account when using δ30SibSi data as a paleo proxy for the reconstruction of dSi utilization in the region.

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