scholarly journals Experimental Study on the Elemental Sulfur Solubility in Sour Gas Mixtures

2021 ◽  
Vol 9 ◽  
Author(s):  
Rui Zhang ◽  
Shaohua Gu ◽  
Liang Huang ◽  
Daqian Zeng ◽  
Tong Li ◽  
...  

The investigation of elemental sulfur solubility plays critical roles on sour gas reservoir development. In this paper, the solubility of elemental sulfur was directly measured by static method with gas samples from well M1 of a sour gas reservoir in Sichuan Basin. The results show that the solubility of elemental sulfur ranges from 0.001 g/cm3 to 0.968 g/cm3 at 40–98.9 MPa and 15–49.8 MPa. The elemental sulfur solubility increases with increasing temperature and pressure, especially when the pressure is greater than 30 MPa. Moreover, the H2S content in sour gas mixtures is also an important factor affecting elemental sulfur solubility. The elemental sulfur solubility increases with increasing H2S content of the sour gas mixtures. The experimental data in this paper display a consistent trend with the reported experimental data. Based on the experimental results, the chrastil-type model, Robert’s model and Hu’s model were investigated and compared. The results show that the chrastil-type model by fitting experimental data in this paper has less error and higher accuracy in calculating elemental sulfur solubility in M gas reservoir. The chrastil-type models proposed in the literature, meanwhile, are only based on the regression of specific gas components and experimental conditions, which lead to a large error in the calculation of elemental sulfur solubility of sour gas samples in this research. The research results provide important basic data and technical support for the development of M gas reservoir.

2019 ◽  
Vol 33 (08) ◽  
pp. 1950052 ◽  
Author(s):  
Huasheng Chen ◽  
Chao Liu ◽  
Xiaoxiao Xu

The elemental sulfur solubility in sour gas plays an important role in H2S-rich gas reservoir development and transportation. While the solubility of elemental sulfur in sour gas can be measured in macroscopical respect, the interaction of solid deposition is not clear at microscale. In this work, molecular dynamic simulation (MD) was adopted to predict the solubility of elemental sulfur in hydrogen sulfide at nanoscale. It is found that the results of new nanoscale solubility model are close to the reported experimental data. The average relative error of the solubility of elemental sulfur in hydrogen sulfide by using the new model is 11.05% compared with the experimental data. Therefore, the new model can be used to predict the solubility of elemental sulfur in hydrogen sulfide.


2014 ◽  
Vol 18 ◽  
pp. 31-38 ◽  
Author(s):  
Jing-Hong Hu ◽  
Jin-Zhou Zhao ◽  
Lei Wang ◽  
Ling-Ye Meng ◽  
Yong-Ming Li

2012 ◽  
Vol 268-270 ◽  
pp. 1207-1211
Author(s):  
Jing Hong Hu ◽  
Zhi Ping Li ◽  
Lei Wang ◽  
Ling Ye Meng ◽  
Ju Hong Lu

With the development of sour gas reservoir, the utilization of horizontal well technology has a great significance. The accurate prediction of the productivity of horizontal well in developing sour gas reservoir will become more and more important. In this paper, productivity prediction formulas of the horizontal well are established with considering the effect of sulfur deposition on permeability. The effects of the length of horizontal well, the effective thickness of the reservoir, elemental sulfur deposition and reservoir heterogeneity on productivity can be analyzed by established formulas. According to the field case, the calculating results of improved Joshi’s equation approaches the real productivity, which means that it could be used to predict the productivity of horizontal well at initial stage during sour gas reservoir development. The results can be used as a reference for the development of similar sour gas reservoir.


Materials ◽  
2021 ◽  
Vol 14 (10) ◽  
pp. 2518
Author(s):  
Dorota Kołodyńska ◽  
Yongming Ju ◽  
Małgorzata Franus ◽  
Wojciech Franus

The possibility of application of chitosan-modified zeolite as sorbent for Cu(II), Zn(II), Mn(II), and Fe(III) ions and their mixtures in the presence of N-(1,2-dicarboxyethyl)-D,L-aspartic acid, IDHA) under different experimental conditions were investigated. Chitosan-modified zeolite belongs to the group of biodegradable complexing agents used in fertilizer production. NaP1CS as a carrier forms a barrier to the spontaneous release of the fertilizer into soil. The obtained materials were characterized by Fourier transform infrared spectroscopy (FTIR); surface area determination (ASAP); scanning electron microscopy (SEM-EDS); X-ray fluorescence (XRF); X-ray diffraction (XRD); and carbon, hydrogen, and nitrogen (CHN), as well as thermogravimetric (TGA) methods. The concentrations of Cu(II), Zn(II), Mn(II), and Fe(III) complexes with IDHA varied from 5–20 mg/dm3 for Cu(II), 10–40 mg/dm3 for Fe(III), 20–80 mg/dm3 for Mn(II), and 10–40 mg/dm3 for Zn(II), respectively; pH value (3–6), time (1–120 min), and temperature (293–333 K) on the sorption efficiency were tested. The Langmuir, Freundlich, Dubinin–Radushkevich, and Temkin adsorption models were applied to describe experimental data. The pH 5 proved to be appropriate for adsorption. The pseudo-second order and Langmuir models were consistent with the experimental data. The thermodynamic parameters indicate that adsorption is spontaneous and endothermic. The highest desorption percentage was achieved using the HCl solution, therefore, proving that method can be used to design slow-release fertilizers.


2017 ◽  
Vol 96 (4) ◽  
pp. 886-894 ◽  
Author(s):  
Jinghong Hu ◽  
Zhengdong Lei ◽  
Zhangxin Chen ◽  
Zhanguo Ma

2012 ◽  
Vol 16 (12) ◽  
pp. 1346-1352 ◽  
Author(s):  
Renata C. dos Reis ◽  
Ivano A. Devilla ◽  
Diego P. R. Ascheri ◽  
Ana C. O. Servulo ◽  
Athina B. M. Souza

The objective of this paper was to model the drying curves of the leaves of basil (Ocimum basilicum L.) in the infrared at temperatures of 50, 60, 70 and 80 ºC and to evaluate the influence of drying temperature on the color of dried leaves. Drying was conducted in infrared dryer with temperature and greenhouse air circulation. Experimental data were fitted to eight mathematical models. The magnitude of the coefficient of determination (R²), the mean relative error (P), the estimated mean error (SE) and chisquare test (χ2) were used to verify the degree of fitness of the models. From the study it was concluded that: a) the behavior of the drying curves of basil leaves was similar to most agricultural products, the drying times in the infrared were less than the drying times in an oven with air circulation, b) the mathematical drying model proposed by Midilli et al. (2002) was the one which best adjusted to the experimental data, c) the diffusion coefficient ranged from 9.10 x 10-12 to 2.92 x 10-11 m² s-1 and d) the color of the samples was highly influenced by drying, becoming darker due to loss of chlorophyll with increasing temperature.


Author(s):  
Elisabete P. de Sousa ◽  
Rossana M. F. de Figueirêdo ◽  
Josivanda P. Gomes ◽  
Alexandre J. de M. Queiroz ◽  
Deise S. de Castro ◽  
...  

ABSTRACT The aim of this work was to study the drying kinetics of pequi pulp by convective drying at different conditions of temperature (50, 60, 70 and 80 °C) and thickness (0.5, 1.0 and 1.5 cm) at the air speed of 1.0 m s-1, with no addition of adjuvant. The experimental data of pequi pulp drying kinetics were used to plot drying curves and fitted to the models: Midilli, Page, Henderson & Pabis and Newton. Effective diffusivity was calculated using the Fick’s diffusion model for a flat plate. It was found that, with increasing thickness, the drying time increased and, with increasing temperature, the drying time was reduced. The Midilli model showed the best fit to the experimental data of pequi pulp drying at all temperatures and thicknesses, presenting higher coefficients of determination (R2), indicating that this model satisfactorily represents the pequi pulp drying phenomenon. There was a trend of increase in the effective diffusivity with the increase in pulp layer thickness and temperature.


Author(s):  
Thuy Chu ◽  
Tan C. Nguyen ◽  
Jihoon Wang ◽  
Duc Vuong

AbstractElectrical Submersible Pump (ESP) is one of the major Artificial Lift methods that is reliable and effective for pumping high volume of fluids from wellbores. However, ESP is not recommended for applications with high gas liquid ratio. The presence of free gas inside the pump causes pump performance degradation which may lead to problems or even failure during operations. Thus, it is important to investigate effect of free gas on ESP performance under downhole conditions. At present, existing models or correlations are based on/verified with experimental data. This study is one of the first attempts to develop correlations for predicting two-phase gas–liquid pump performance under downhole conditions by using field data and laboratory data. Field data from three oil producing wells provided by Strata Production Company and Perdure Petroleum LLC. as well as experimental data obtained from experimental facility at Production and Drilling Research Project—New Mexico Tech were used in this study. Actual two-phase pump differential pressure per stage is obtained from experiments or estimated from field data and was normalized using pump performance curve. The values are compared to pump performance curve to study the relationships between pump performance and free gas percentage at pump intake. Correlations to predict ESP performance in two-phase flow under downhole and experimental conditions was derived from the results using regression technique. The correlation developed from field data presented in this study can be used to predict two-phase ESP performance under downhole conditions and under high gas fraction. The results from the experimental data confirm the reliability of the developed correlation using field data to predict two-phase ESP performance under downhole conditions. The developed correlation using the laboratory data predicts quite well the two-phase pump performance at the gas fraction of less than 15% while it is no longer reliable when free gas fraction is more than 15%. The findings from this study will help operating companies as well as ESP manufacturers to operate ESPs within the recommended range under downhole conditions. However, it is recommended to use the proposed correlation on reservoirs with conditions similar to those of the three presented wells.


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