scholarly journals Improvement of Calcium Aluminate Cement Containing Blast Furnace Slag at 50°C and 315°C

2022 ◽  
Vol 8 ◽  
Author(s):  
Wu Zhiqiang ◽  
Liu Hengjie ◽  
Qu Xiong ◽  
Wu Guangai ◽  
Xing Xuesong ◽  
...  

During the thermal recovery of heavy oil thermal recovery wells, improving the mechanical properties and integrity of the cement ring is of great significance for the safe and efficient exploitation of heavy oil resources. This paper studies the relative properties of calcium aluminate cement and three kinds of slags under the conditions of 50°C × 1.01 MPa and 315°C × 20.7 MPa. CAC-slag composite material performance was evaluated using the cement paste compressive strength and permeability tests to study the physical properties of CAC with blast furnace slag. X-ray diffraction analysis, scanning electron microscopy (SEM), and thermal analysis (DSC/TG) were carried out to investigate the mineralogical composition of CAC with blast furnace slag. Results show that adding blast furnace slag did not affect the performance of cement slurry. Moreover, C2ASH8 curing occurred at low temperature, the microstructure of CAC paste was compact, and the permeability resistance was improved, thus improving the low-temperature properties of neat CAC. When cured at a high temperature, the CAC paste was mainly hydrated with C3ASH4 and AlO(OH), which had a well-developed crystal structure. Adding blast furnace slag can improve the CAC resistance to high temperature.

Materials ◽  
2021 ◽  
Vol 14 (23) ◽  
pp. 7333
Author(s):  
Solmoi Park ◽  
Namkon Lee ◽  
Gi-Hong An ◽  
Kyeong-Taek Koh ◽  
Gum-Sung Ryu

The use of alternative cementitious binders is necessary for producing sustainable concrete. Herein, we study the effect of using alternative cementitious binders in ultra-high-performance concrete (UPHC) by calculating the phase assemblages of UHPC in which Portland cement is replaced with calcium aluminate cement, calcium sulfoaluminate cement, metakaolin or blast furnace slag. The calculation result shows that replacing Portland cement with calcium aluminate cement or calcium sulfoaluminate cement reduces the volume of C-S-H but increases the overall solid volume due to the formation of other phases, such as strätlingite or ettringite. The modeling result predicts that using calcium aluminate cement or calcium sulfoaluminate cement may require more water than it would for plain UHPC, while a similar or lower amount of water is needed for chemical reactions when using blast furnace slag or metakaolin.


2021 ◽  
Vol 571 ◽  
pp. 121066
Author(s):  
Jian Zhang ◽  
Cui Wang ◽  
Kexin Jiao ◽  
Jianliang Zhang ◽  
Zhengjian Liu ◽  
...  

2013 ◽  
Vol 115 (2) ◽  
pp. 1245-1252 ◽  
Author(s):  
František Šoukal ◽  
Petr Ptáček ◽  
Jiří Másilko ◽  
Tomáš Opravil ◽  
Jaromír Havlica ◽  
...  

2017 ◽  
Vol 41 (19) ◽  
pp. 11299-11307 ◽  
Author(s):  
Rong Liu ◽  
Yifan Xu ◽  
Fei Ye ◽  
Feng Jia ◽  
Rui Xu

Mn–Ce based catalysts supported on Ti-bearing blast furnace slag (industrial solid waste) and the doping of transition metals were studied.


2014 ◽  
Vol 33 (4) ◽  
pp. 325-328 ◽  
Author(s):  
Zaoyuan Li ◽  
Yan Wang ◽  
Xiaowei Cheng ◽  
Xiaoyang Guo

AbstractThe sharp strength recession of silicate cement in high temperature is the crucial reason of casings damage and zonal isolation failure in heavy oil thermal recovery. Although aluminophosphate cement has a better high temperature resistance in comparison with silicate cement, its compressive strength recession in high temperature slightly recessed. The results show that adding slag into aluminophosphate cement can not only develop compressive strength of cement at low temperature, but it can also improve the high temperature resistance of the cement. After adding slag, the formation of C2ASH8 conduces to develop cement strength at low temperature, and C3AS2H2 conduces to high temperature resistance. To increase temperature resistance of aluminophosphate cement, C3ASH4 generation and Al(OH)3 decomposition should be avoided. Crystal structure of cement after high temperature is well developed with compactly and neatly arranged, allowing cement to maintain good mechanical properties to help protect the casing and improve zonal isolation performance.


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