Synthesis of Semicrystalline Long Chain Aliphatic Polyesters by ADMET Copolymerization of Dianhydro-D-glucityl bis(undec-10-enoate) with 1,9-Decadiene and Tandem Hydrogenation
Keyword(s):
Acyclic diene metathesis (ADMET) copolymerization of dianhydro-D-glucityl bis(undec-10-enoate) (M1) with 1,9-decadiene (DCD) using ruthenium-carbene catalyst, RuCl2(IMesH2)(CH-2-OiPr-C6H4) [IMesH2 = 1,3-bis(2,4,6-trimethylphenyl)imidazolin-2-ylidene, HG2], afforded unsaturated polyesters (Mn = 9300–23,400) under the optimized conditions. Subsequent tandem hydrogenation (H2 1.0 MPa, 50 °C) with the addition of a small amount of Al2O3 resulted in the saturated polymers having a melting temperature of 71.7–107.6 °C, depending on the molar ratio of M1 and DCD.
2021 ◽
Keyword(s):
2018 ◽
Vol 56
(15)
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pp. 1705-1710
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2020 ◽
Vol 97
(5)
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pp. 517-530
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2015 ◽
Vol 4
(11)
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pp. 1225-1228
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