scholarly journals Ti2O3/TiO2-Assisted Solar Photocatalytic Degradation of 4-tert-Butylphenol in Water

Catalysts ◽  
2021 ◽  
Vol 11 (11) ◽  
pp. 1379
Author(s):  
Saule Mergenbayeva ◽  
Timur Sh. Atabaev ◽  
Stavros G. Poulopoulos
Keyword(s):  
Photocatalytic Activity ◽  
Treatment Method ◽  
Treatment Temperature ◽  
Tio2 Anatase ◽  
Bicarbonate Ions ◽  
Photocatalytic Activities ◽  
Structure Surface ◽  
Negative Effect ◽  
Water Constituents ◽  
Tio2 Rutile

Colored Ti2O3 and Ti2O3/TiO2 (mTiO) catalysts were prepared by the thermal treatment method. The effects of treatment temperature on the structure, surface area, morphology and optical properties of the as-prepared samples were investigated by XRD, BET, SEM, TEM, Raman and UV–VIS spectroscopies. Phase transformation from Ti2O3 to TiO2 rutile and TiO2 anatase to TiO2 rutile increased with increasing treatment temperatures. The photocatalytic activities of thermally treated Ti2O3 and mTiO were evaluated in the photodegradation of 4-tert-butylphenol (4-t-BP) under solar light irradiation. mTiO heated at 650 °C exhibited the highest photocatalytic activity for the degradation and mineralization of 4-t-BP, being approximately 89.8% and 52.4%, respectively, after 150 min of irradiation. The effects of various water constituents, including anions (CO32−, NO3, Cl and HCO3−) and humic acid (HA), on the photocatalytic activity of mTiO-650 were evaluated. The results showed that the presence of carbonate and nitrate ions inhibited 4-t-BP photodegradation, while chloride and bicarbonate ions enhanced the photodegradation of 4-t-BP. As for HA, its effect on the degradation of 4-t-BP was dependent on the concentration. A low concentration of HA (1 mg/L) promoted the degradation of 4-t-BP from 89.8% to 92.4% by mTiO-650, but higher concentrations of HA (5 mg/L and 10 mg/L) had a negative effect.

scholarly journals The effect of anatase crystal morphology on the photocatalytic conversion of NO by TiO2-based nanomaterials

2012 ◽  
Vol 10 (4) ◽  
pp. 1183-1198 ◽  
Author(s):  
Marco Abreu ◽  
Edisson Morgado ◽  
Paula Jardim ◽  
Bojan Marinkovic
Keyword(s):  
Photocatalytic Activity ◽  
Crystal Morphology ◽  
Hydrothermal Reaction ◽  
High Energy ◽  
Proton Exchange ◽  
Acid Media ◽  
Tio2 Anatase ◽  
Vis Spectroscopy ◽  
Photocatalytic Activities ◽  
Low Activity

AbstractHydrogen titanate nanotubes (H-TTNT) were synthesized by the alkali hydrothermal method followed by proton exchange and then submitted either to thermal treatment or to acid hydrothermal reaction to generate TiO2-anatase nanocrystals of different morphologies. The samples were characterized by XRPD, TGA, sulfur analysis, N2 physisorption, UV-Vis spectroscopy and TEM. Their photocatalytic activities were determined by measuring the NO conversion in inert gas stream passed through the powder catalyst bed under UV radiation. Incomplete transformation into anatase resulted in nanomaterials with low activity due to coexistence with H-TTNT or TiO2-B precursors. Anatase specimens derived from H-TTNT aged in strong sulfuric acid media contained equidimensional nanoparticles, but retention of sulfate negatively affected their photocatalytic activity. Combining milder acidic pH with higher aging temperature, allowed synthesis of a sulfate free anatase with the same optical properties and specific surface area as the counterpart produced by calcination of H-TTNT at 550°C; however, the former exhibited truncated bi-pyramid nanocrystals and the other adopted the form of nanorods. This latter showed the highest photocatalytic activity for NO abatement, outperforming the benchmark photocatatyst TiO2-P25; this improved activity was tentatively ascribed to the maximization of high energy {001} facets in anatase nanorods formed during calcination of H-TTNT.

A Patterned TiO2(Anatase)/TiO2(Rutile) Bilayer-Type Photocatalyst: Effect of the Anatase/Rutile Junction on the Photocatalytic Activity

2002 ◽  
Vol 41 (15) ◽  
pp. 2811-2813 ◽  
Author(s):  
Tetsuro Kawahara ◽  
Yasuhiro Konishi ◽  
Hiroaki Tada ◽  
Noboru Tohge ◽  
Junji Nishii ◽  
...  
Keyword(s):  
Photocatalytic Activity ◽  
Anatase Tio2 ◽  
Tio2 Anatase ◽  
Tio2 Rutile

Three novel d7/d10 metal complexes with N-heterocyclic ligand of 2,6-bis(3-pyrazolyl)pyridine: synthesis, structure, surface photovoltage spectroscopy and photocatalytic activity

RSC Advances ◽  
2014 ◽  
Vol 4 (41) ◽  
pp. 21180-21189 ◽  
Author(s):  
Ya Nan Hou ◽  
Zhi Nan Wang ◽  
Feng Ying Bai ◽  
Qing Lin Guan ◽  
Xuan Wang ◽  
...  
Keyword(s):  
Photocatalytic Activity ◽  
Metal Complexes ◽  
Surface Photovoltage ◽  
Heterocyclic Ligand ◽  
Surface Photovoltage Spectroscopy ◽  
D10 Metal ◽  
Photocatalytic Activities ◽  
Structure Surface ◽  
Pyridine Synthesis

We synthesized three novel d7/d10 metal complexes with 2,6-bis(3-pyrazolyl)pyridine and studied their surface photovoltage spectra and photocatalytic activities.

A Patterned TiO2(Anatase)/TiO2(Rutile) Bilayer-Type Photocatalyst: Effect of the Anatase/Rutile Junction on the Photocatalytic Activity

2002 ◽  
Vol 114 (15) ◽  
pp. 2935-2937 ◽  
Author(s):  
Tetsuro Kawahara ◽  
Yasuhiro Konishi ◽  
Hiroaki Tada ◽  
Noboru Tohge ◽  
Junji Nishii ◽  
...  
Keyword(s):  
Photocatalytic Activity ◽  
Anatase Tio2 ◽  
Tio2 Anatase ◽  
Tio2 Rutile

Crystal Engineering of Bi2WO6 to Polar Aurivillius-Phase Oxyhalides

2019 ◽  
Author(s):  
Kazuki Morita ◽  
Ji-Sang Park ◽  
Sunghyun Kim ◽  
Kenji Yasuoka ◽  
Aron Walsh
Keyword(s):  
Photocatalytic Activity ◽  
Crystal Engineering ◽  
First Principles ◽  
Parent Compound ◽  
Aurivillius Phase ◽  
Aurivillius Phases ◽  
Charge Neutrality ◽  
Bismuth Oxides ◽  
Structure Surface ◽  
Electric Dipoles

The Aurivillius phases of complex bismuth oxides have attracted considerable attention due to their lattice polarization (ferroelectricity) and photocatalytic activity. We report a first-principles exploration of Bi<sub>2</sub>WO<sub>6</sub> and the replacement of W<sup>6+</sup> by pentavalent (Nb<sup>5+</sup>, Ta<sup>5+</sup>) and tetravalent (Ti<sup>4+</sup>, Sn<sup>4+</sup>) ions, with charge neutrality maintained by the formation of a mixed-anion oxyhalide sublattice. We find that Bi<sub>2</sub>SnO<sub>4</sub>F<sub>2</sub> is thermodynamically unstable, in contrast to Bi<sub>2</sub>TaO<sub>5</sub>F, Bi<sub>2</sub>NbO<sub>5</sub>F and Bi<sub>2</sub>TiO<sub>4</sub>F<sub>2</sub>. The electric dipoles introduced by chemical substitutions in the parent compound are found to suppress the spontaneous polarization from 61.55 μC/cm<sup>2</sup> to below 15.50 μC/cm<sup>2</sup>. Analysis of the trends in electronic structure, surface structure, and ionization potentials are reported. This family of materials can be further extended with control of layer thicknesses and choice of compensating halide species.<br>

Effects of Heat Treatment Temperature on Photocatalytic Activity of TiO2/SiO2 Composite Aerogels

2013 ◽  
Vol 27 (10) ◽  
pp. 1079-1083
Author(s):  
Zhao-Hui LIU ◽  
Gen-Liang HOU ◽  
Xun-Jia SU ◽  
Feng GUO ◽  
Zhou XIAO ◽  
...  
Keyword(s):  
Heat Treatment ◽  
Photocatalytic Activity ◽  
Heat Treatment Temperature ◽  
Treatment Temperature ◽  
Composite Aerogels

scholarly journals Hydrothermal Synthesis of Iodine-Doped Nanoplates with Enhanced Visible and Ultraviolet-Induced Photocatalytic Activities

2012 ◽  
Vol 2012 ◽  
pp. 1-12 ◽  
Author(s):  
Jiang Zhang ◽  
Zheng-Hong Huang ◽  
Yong Xu ◽  
Feiyu Kang
Keyword(s):  
Photocatalytic Activity ◽  
Photoelectron Spectroscopy ◽  
Oxygen Vacancies ◽  
Diffuse Reflectance Spectroscopy ◽  
Synergetic Effect ◽  
X Ray Diffraction ◽  
X Ray ◽  
Selected Area Electron Diffraction ◽  
Transmission Electron ◽  
Photocatalytic Activities

The iodine-doped Bi2WO6(I-BWO) photocatalyst was prepared via a hydrothermal method using potassium iodide as the source of iodine. The samples were characterized by X-ray diffraction (XRD), scanning electron microscope (SEM), transmission electron microscopy (TEM) and selected area electron diffraction (SAED), X-ray photoelectron spectroscopy (XPS), UV-vis diffuse reflectance spectroscopy (DRS), and photoluminescence (PL) spectroscopy. The photocatalytic activity of I-BWO for the degradation of rhodamine B (RhB) was higher than that of pure BWO and I2-BWO regardless of visible light (>420 nm) or ultraviolet light (<400 nm) irradiation. The results of DRS analysis showed that the I-BWO and I2-BWO catalysts had narrower band gaps. XPS analysis proved that the multivalent iodine species including I0and were coadsorbed on the defect surface of Bi2WO6in I-BWO. The enhanced PL intensity revealed that a large number of defects of oxygen vacancies were formed by the doping of iodine. The enhanced photocatalytic activity of I-BWO for degradation of RhB was caused by the synergetic effect of a small crystalline size, a narrow band gap, and plenty of oxygen vacancies.

Photocatalytic Activity of Reduced Graphene Oxide-SnSe Nanohybrids with Efficiency Interface Effect

NANO ◽  
2017 ◽  
Vol 12 (03) ◽  
pp. 1750032 ◽  
Author(s):  
H.-Y. He
Keyword(s):  
Photocatalytic Activity ◽  
Graphene Oxide ◽  
Reduced Graphene Oxide ◽  
Malachite Green ◽  
Interface Effect ◽  
Solution Ph ◽  
Photodegradation Efficiency ◽  
Reduced Graphene ◽  
Narrow Bandgap ◽  
Photocatalytic Activities

Reduced graphene oxide-SnSe (rGO-SnSe) nanohybrids were synthesized with a solution chemical reaction at room temperature. The nanohybrids were characterized by various techniques for their microstructural and photocatalytic activities in photodegradation of alkaline dye malachite green in the water. The effects of rGO/SnSe ratio, initial solution pH, and H2O2 concentration on the photodegradation efficiency were studied. The SnSe nanocrystallines with nanoscale size and narrow bandgap were formed and uniformly adhered on the rGO surface. Raman analysis confirmed the reduction of GO. The experimental results indicated that the nanohybrids showed excellent sunlight-excited photocatalytic activity in degrading malachite green in the water. Significantly, the nanohybrids showed remarkable photo-Fenton-like catalytic activity. The photodegradation rates of the hybrids were greater than that of SnSe nanoparticles, increased with increasing rGO/SnSe ratio, and related to operation parameters. High photocatalytic activities were ascribed to the efficiency interface effect that was confirmed by the calculations of band energy level and photoconductivity. The TOC measurement further verified the photodegradation results. The nanoparticles and nanohybrids also showed excellent reusability.

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