scholarly journals Hydrothermal Synthesis of Iodine-Doped Nanoplates with Enhanced Visible and Ultraviolet-Induced Photocatalytic Activities

2012 ◽  
Vol 2012 ◽  
pp. 1-12 ◽  
Author(s):  
Jiang Zhang ◽  
Zheng-Hong Huang ◽  
Yong Xu ◽  
Feiyu Kang
Keyword(s):  
Photocatalytic Activity ◽  
Photoelectron Spectroscopy ◽  
Oxygen Vacancies ◽  
Diffuse Reflectance Spectroscopy ◽  
Synergetic Effect ◽  
X Ray Diffraction ◽  
X Ray ◽  
Selected Area Electron Diffraction ◽  
Transmission Electron ◽  
Photocatalytic Activities

The iodine-doped Bi2WO6(I-BWO) photocatalyst was prepared via a hydrothermal method using potassium iodide as the source of iodine. The samples were characterized by X-ray diffraction (XRD), scanning electron microscope (SEM), transmission electron microscopy (TEM) and selected area electron diffraction (SAED), X-ray photoelectron spectroscopy (XPS), UV-vis diffuse reflectance spectroscopy (DRS), and photoluminescence (PL) spectroscopy. The photocatalytic activity of I-BWO for the degradation of rhodamine B (RhB) was higher than that of pure BWO and I2-BWO regardless of visible light (>420 nm) or ultraviolet light (<400 nm) irradiation. The results of DRS analysis showed that the I-BWO and I2-BWO catalysts had narrower band gaps. XPS analysis proved that the multivalent iodine species including I0and were coadsorbed on the defect surface of Bi2WO6in I-BWO. The enhanced PL intensity revealed that a large number of defects of oxygen vacancies were formed by the doping of iodine. The enhanced photocatalytic activity of I-BWO for degradation of RhB was caused by the synergetic effect of a small crystalline size, a narrow band gap, and plenty of oxygen vacancies.

scholarly journals Improved Visible Light Photocatalytic Activity for TiO2Nanomaterials by Codoping with Zinc and Sulfur

2015 ◽  
Vol 2015 ◽  
pp. 1-8 ◽  
Author(s):  
Qianzhi Xu ◽  
Xiuying Wang ◽  
Xiaoli Dong ◽  
Chun Ma ◽  
Xiufang Zhang ◽  
...  
Keyword(s):  
Photocatalytic Activity ◽  
Visible Light ◽  
Photoelectron Spectroscopy ◽  
Diffuse Reflectance Spectroscopy ◽  
Sol Gel ◽  
X Ray Diffraction ◽  
Sunlight Irradiation ◽  
X Ray ◽  
Transmission Electron ◽  
Photoinduced Charge

S/Zn codoped TiO2nanomaterials were synthesized by a sol-gel method. X-ray diffraction, UV-vis diffuse reflectance spectroscopy, transmission electron microscopy, photoluminescence spectroscopy, and X-ray photoelectron spectroscopy were used to characterize the morphology, structure, and optical properties of the prepared samples. The introduction of Zn and S resulted in significant red shift of absorption edge for TiO2-based nanomaterials. The photocatalytic activity was evaluated by degrading reactive brilliant red X-3B solution under simulated sunlight irradiation. The results showed S/Zn codoped TiO2exhibited higher photocatalytic activity than pure TiO2and commercial P25, due to the photosynergistic effect of obvious visible light absorption, efficient separation of photoinduced charge carriers, and large surface area. Moreover, the content of Zn and S in the composites played important roles in photocatalytic activity of TiO2-based nanomaterials.

A Facile Synthesis of CuInS2 Nanoparticles from Molecular Single Source Precursors

2007 ◽  
Vol 7 (12) ◽  
pp. 4353-4364 ◽  
Author(s):  
Dimple P. Dutta ◽  
Garima Sharma ◽  
A. K. Tyagi
Keyword(s):  
Photoelectron Spectroscopy ◽  
Diffuse Reflectance ◽  
Optical Band Gap ◽  
Diffuse Reflectance Spectroscopy ◽  
Reflectance Spectroscopy ◽  
X Ray Diffraction ◽  
Facile Synthesis ◽  
X Ray ◽  
Selected Area Electron Diffraction ◽  
Transmission Electron

CuInS2 nanoparticles have been synthesized via solvent thermolysis of novel bimetallic complexes of the general formula [(Ph3P)2 CuIn(S2COR)4] (where R = CH3; C2H5; C(CH3)2; and [(Ph3P)2 CuIn(SCH2CH2S)2]. These complexes have been prepared by the reactions of Na/KS2 COR and NaSCH2 CH2 SNa with InCl3 and [(Ph3 P)2 CuNO3] in methanol, respectively. Solvent thermolyses of these complexes were carried out in ethylene glycol at 196 °C for different time periods. The nanoparticles obtained were characterized extensively by techniques like powder X-ray diffraction, transmission electron microscopy, selected area electron diffraction, and X-ray photoelectron spectroscopy. The optical band gap of the nanoparticles was determined by diffuse reflectance spectroscopy (DRS).

Dye-Sensitized-Assisted, Enhanced Photocatalytic Activity of TiO2/Bi4V2O11

NANO ◽  
2018 ◽  
Vol 13 (03) ◽  
pp. 1850028 ◽  
Author(s):  
Mengjun Liang ◽  
Zhiyuan Yang ◽  
Ying Mei ◽  
Haoran Zhou ◽  
Shuijin Yang
Keyword(s):  
Photocatalytic Activity ◽  
Photoelectron Spectroscopy ◽  
Diffuse Reflectance Spectroscopy ◽  
X Ray Diffraction ◽  
X Ray ◽  
Dye Sensitized ◽  
Transmission Electron ◽  
Efficient Charge ◽  
Degradation Activity ◽  
Adsorption Desorption

In this study, the TiO2/Bi4V2O[Formula: see text] nanocomposite photocatalysts were prepared by loading different amount of TiO2 nanoparticles onto the surface of Bi4V2O[Formula: see text] nanospheres via a facile hydrothermal method. Afterwards, the as-synthesized samples were characterized by high-resolution transmission electron microscopy (HRTEM), X-ray diffraction (XRD), N2 adsorption–desorption isotherms, X-ray photoelectron spectroscopy (XPS), UV-Vis diffuse reflectance spectroscopy (DRS) and photocurrent techniques. The optimal TiO2/Bi4V2O[Formula: see text] composite with 20[Formula: see text]wt.% TiO2 loading (TB2) exhibited the best photocatalytic activity, which could degrade almost RhB completely within 30[Formula: see text]min under visible light irradiation. The enhanced photocatalytic activity of TiO2/Bi4V2O[Formula: see text] composites for RhB degradation could be mainly ascribed to the efficient charge separation over dye-induced sensitized and the increased specific surface area. Also, the photocatalytic activities of TiO2/Bi4V2O[Formula: see text] for CIP degradation were tested. After five consecutive recycling experiments, the photocatalytic degradation activity of TB2 could still reach 99% which indicated that the catalysts had superior stability. Based on the experimental and bandgap calculations, a possible photocatalytic mechanism of TiO2/Bi4V2O[Formula: see text] for RhB degradation was proposed.

Study of Various Nanostructures Titania with Graphene Composites: The Preparation and Photocatalytic Activities

NANO ◽  
2016 ◽  
Vol 11 (09) ◽  
pp. 1650106 ◽  
Author(s):  
Bolin Dai ◽  
Hong Tao ◽  
Yu-Jung Lin ◽  
Chang-Tang Chang
Keyword(s):  
Photocatalytic Activity ◽  
Photoelectron Spectroscopy ◽  
Reactive Black 5 ◽  
X Ray Diffraction ◽  
Photo Degradation ◽  
X Ray ◽  
Transmission Electron ◽  
Photocatalytic Activities ◽  
Uv Lamp ◽  
Degradation Ability

Different kinds of graphene (GN)/titania nanocomposites using graphene and P25 or Titanium (IV) n-butoxide (TBOT) as precursors were prepared with hydrothermal method. To investigate the differences of the photocatalytic properties of composites with various shapes of titanium dioxide (TiO[Formula: see text], three types of TiO2, including titanium nanotubes (TNT), titanium nanosheets (TNS) and titanium nanoparticles (TNP) were successfully prepared and combined with GN to form the composites. The prepared composites were confirmed by Ultraviolet-visible spectroscopy (UV-Vis), X-ray diffraction (XRD), Fourier transform infrared (FTIR), X-ray Photoelectron Spectroscopy (XPS), and transmission electron microscopy (TEM), etc. Photocatalytic activities of composites were carried out by the degradation of Reactive Black 5 (RBk5) and Norfloxacin (NFXC) under the radiation of UV lamp. Results indicate that the differences in the TiO2 morphology of the composites greatly influence the catalytic properties. In addition, the heterojunction between graphene and TiO2 also play an important role in the photocatalytic abilities of composites. In this study, it can be seen that the prepared composites exhibit higher photocatalytic activity including excellent adsorption capacity and photo-degradation ability than P25. The photocatalytic activity of GN–TNS is higher than that of GN–TiO2 and GN–TNT.

scholarly journals A Facile Synthesis of Graphene-WO3Nanowire Clusters with High Photocatalytic Activity for O2Evolution

2014 ◽  
Vol 2014 ◽  
pp. 1-6
Author(s):  
M.-J. Zhou ◽  
N. Zhang ◽  
Z. H. Hou
Keyword(s):  
Photocatalytic Activity ◽  
Water Splitting ◽  
Photoelectron Spectroscopy ◽  
Diffuse Reflectance Spectroscopy ◽  
High Photocatalytic Activity ◽  
X Ray Diffraction ◽  
X Ray ◽  
Transmission Electron ◽  
Charge Transfer Rate ◽  
Ft Ir

In the present work, graphene-WO3nanowire clusters were synthesizedviaa facile hydrothermal method. The obtained graphene-WO3nanowire clusters were characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), Fourier transform infrared spectroscopy (FT-IR), Raman spectroscopy, and ultraviolet-visible diffuse reflectance spectroscopy (DRS) techniques. The photocatalytic oxygen (O2) evolution properties of the as-synthesized samples were investigated by measuring the amount of evolved O2from water splitting. The graphene-WO3nanowire clusters exhibited enhanced performance compared to pure WO3nanowire clusters for O2evolution. The amount of evolved O2from water splitting after 8 h for the graphene-WO3nanowire clusters isca.0.345 mmol/L, which is more than 1.9 times as much as that of the pure WO3nanowire clusters (ca.0.175 mmol/L). The high photocatalytic activity of the graphene-WO3nanowire clusters was attributed to a high charge transfer rate in the presence of graphene.

scholarly journals Photocatalytic Degradation of Estriol Using Iron-Doped TiO2 under High and Low UV-Irradiation

2018 ◽  
Author(s):  
Irwing M. Ramírez-Sánchez ◽  
Erick R. Bandala
Keyword(s):  
Photocatalytic Activity ◽  
Electron Microscope ◽  
Uv Irradiation ◽  
Photoelectron Spectroscopy ◽  
Diffuse Reflectance Spectroscopy ◽  
Bet Surface Area ◽  
Doped Tio2 ◽  
X Ray ◽  
Transmission Electron ◽  
Iron Doped

Iron Doped TiO2 nanoparticles (Fe-TiO2) were synthesized and photocatalitically investigated under high and low fluence values of UV-radiation. The Fe-TiO2 physical characterization was performed using X-ray Powder Diffraction (XRD), Brunauer-Emmett-Teller (BET) surface area analysis, Transmission Electron Microscope (TEM), Scanning Electron Microscope (SEM), Diffuse Reflectance Spectroscopy (DRS), and X-Ray Photoelectron Spectroscopy (XPS) technique. The XPS evidenced that ferric ion (Fe3+) was in the lattice of TiO2 and co-dopants no intentionally added were also present due to the precursors of the synthetic method. The Fe3+ concentration played a key role in the photocatalytic generation of hydroxyl radical (&bull;OH) and estriol (E3) degradation. Fe-TiO2 materials accomplished E3 degradation, and it was found that the catalyst with 0.3 at. % content of Fe (0.3 Fe-TiO2) enhanced the photocatalytic activity under low UV-irradiation compared with no intentionally Fe-added TiO2 (zero-iron TiO2) and Aeroxide&reg; TiO2 P25. Furthermore, the enhanced photocatalytic activity of 0.3 Fe-TiO2 under low UV-irradiation may have applications when radiation intensity must be controlled, as in medical applications, or when strong UV absorbing species are present in water.

scholarly journals Defective TiO2 Core-Shell Magnetic Photocatalyst Modified with Plasmonic Nanoparticles for Visible Light-Induced Photocatalytic Activity

Catalysts ◽  
2020 ◽  
Vol 10 (6) ◽  
pp. 672 ◽  
Author(s):  
Zuzanna Bielan ◽  
Agnieszka Sulowska ◽  
Szymon Dudziak ◽  
Katarzyna Siuzdak ◽  
Jacek Ryl ◽  
...  
Keyword(s):  
Photocatalytic Activity ◽  
Photoelectron Spectroscopy ◽  
Diffuse Reflectance Spectroscopy ◽  
Phenol Degradation ◽  
Magnetic Core ◽  
Magnetic Photocatalyst ◽  
X Ray ◽  
Transmission Electron ◽  
First Time

In the presented work, for the first time, the metal-modified defective titanium(IV) oxide nanoparticles with well-defined titanium vacancies, was successfully obtained. Introducing platinum and copper nanoparticles (NPs) as surface modifiers of defective d-TiO2 significantly increased the photocatalytic activity in both UV-Vis and Vis light ranges. Moreover, metal NPs deposition on the magnetic core allowed for the effective separation and reuse of the nanometer-sized photocatalyst from the suspension after the treatment process. The obtained Fe3O4@SiO2/d-TiO2-Pt/Cu photocatalysts were characterized by X-ray diffractometry (XRD) and specific surface area (BET) measurements, UV-Vis diffuse reflectance spectroscopy (DR-UV/Vis), X-ray photoelectron spectroscopy (XPS) and transmission electron microscopy (TEM). Further, the mechanism of phenol degradation and the role of four oxidative species (h+, e−, •OH, and •O2−) in the studied photocatalytic process were investigated.

Fabrication and Characterization of Titanium Based Nanotubes

2009 ◽  
Vol 79-82 ◽  
pp. 581-584 ◽  
Author(s):  
Li Ang Song ◽  
Li Xin Cao ◽  
Ge Su ◽  
Wei Liu ◽  
Hui Liu ◽  
...  
Keyword(s):  
Diffuse Reflectance Spectroscopy ◽  
Cost Effective ◽  
Outer Diameter ◽  
X Ray Diffraction ◽  
X Ray ◽  
Amorphous Phases ◽  
Selected Area Electron Diffraction ◽  
Transmission Electron ◽  
Inner Diameter

Titanium based nanotubes (8-12nm outer diameter and 4-6nm inner diameter) were successfully fabricated by a simple and cost-effective hydrothermal method. The nanotube-like amorphous phases TNT(Na) and TNT(H) were obtained with different post treatment. The samples were characterized by means of high resolution transmission electron microscopy (HRTEM), X-ray diffraction (XRD), selected area electron diffraction (SAED), energy dispersive X-ray spectrum (EDS) and UV-Vis diffuse reflectance spectroscopy (DRS). The photocatalytic activities of the nanotubes were evaluated using photo-oxidation of methyl orange.

scholarly journals Impact of Preparative pH on the Morphology and Photocatalytic Activity of BiVO4

2012 ◽  
Vol 2012 ◽  
pp. 1-7 ◽  
Author(s):  
Yongbiao Wan ◽  
Sihong Wang ◽  
Wenhao Luo ◽  
Lianhua Zhao
Keyword(s):  
Photocatalytic Activity ◽  
Photoelectron Spectroscopy ◽  
Diffuse Reflectance Spectroscopy ◽  
Ammonia Solution ◽  
Synthesis Process ◽  
X Ray Diffraction ◽  
X Ray ◽  
Blue Solution ◽  
Absorption Performance ◽  
The Impact

Adjusting pH with an ammonia solution during the synthesis, single-crystalline BiVO4has been prepared using Bi(NO3)3·5H2O and NH4VO3as starting materials through aqueous-phase precipitation at room temperature. The prepared samples are characterized by X-ray diffraction (XRD), diffuse reflectance spectroscopy (DRS), X-ray photoelectron spectroscopy (XPS), and scanning electron microscope (SEM). The impact of pH on structure, surface morphology, visible-light photocatalytic activity, and light absorption performance of BiVO4is explored and discussed. During the synthesis process, neither extremely acidic (low pH) nor basic (high pH) conditions are desirable for the formation of BiVO4in monoclinic phase. The highest photocatalytic performance on the degradation of a methylene blue solution is observed under pH=7.0for BiVO4in monoclinic scheelite, which is attributed to its small grain size and marked surface oxygen evolution ability.

Solvothermal Synthesis of CeO2 Nanoparticles

2011 ◽  
Vol 236-238 ◽  
pp. 2000-2003
Author(s):  
Yong Cai Zhang ◽  
En Ren Zhang
Keyword(s):  
Electron Microscopy ◽  
Transmission Electron Microscopy ◽  
Absorption Spectrum ◽  
Photoelectron Spectroscopy ◽  
Solvothermal Synthesis ◽  
Oxygen Vacancies ◽  
Cubic Phase ◽  
X Ray Diffraction ◽  
X Ray ◽  
Transmission Electron

Ultrafine CeO2 nanoparticles were synthesized directly via solvothermal treatment of Ce(NO3)3·6H2O powder in toluene at 180 °C for 48 h, and characterized by X-ray diffraction (XRD), Raman, X-ray photoelectron spectroscopy (XPS), transmission electron microscopy (TEM), and UV-vis absorption spectrum. The results from XRD, Raman and XPS revealed the formation of pure cubic phase CeO2 with some oxygen vacancies. The TEM image disclosed that the as-synthesized CeO2 comprised nanoparticles of about 5–8 nm. The UV-vis absorption spectrum showed that the as-synthesized CeO2 nanoparticles had a wide UV absorption band centered at around 326 nm (3.8 eV).

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