scholarly journals Ca-based Catalysts for the Production of High-Quality Bio-Oils from the Catalytic Co-Pyrolysis of Grape Seeds and Waste Tyres

Catalysts ◽  
2019 ◽  
Vol 9 (12) ◽  
pp. 992 ◽  
Author(s):  
Olga Sanahuja-Parejo ◽  
Alberto Veses ◽  
José Manuel López ◽  
Ramón Murillo ◽  
María Soledad Callén ◽  
...  

The catalytic co-pyrolysis of grape seeds and waste tyres for the production of high-quality bio-oils was studied in a pilot-scale Auger reactor using different low-cost Ca-based catalysts. All the products of the process (solid, liquid, and gas) were comprehensively analysed. The results demonstrate that this upgrading strategy is suitable for the production of better-quality bio-oils with major potential for use as drop-in fuels. Although very good results were obtained regardless of the nature of the Ca-based catalyst, the best results were achieved using a high-purity CaO obtained from the calcination of natural limestone at 900 °C. Specifically, by adding 20 wt% waste tyres and using a feedstock to CaO mass ratio of 2:1, a practically deoxygenated bio-oil (0.5 wt% of oxygen content) was obtained with a significant heating value of 41.7 MJ/kg, confirming its potential for use in energy applications. The total basicity of the catalyst and the presence of a pure CaO crystalline phase with marginal impurities seem to be key parameters facilitating the prevalence of aromatisation and hydrodeoxygenation routes over the de-acidification and deoxygenation of the vapours through ketonisation and esterification reactions, leading to a highly aromatic biofuel. In addition, owing to the CO2-capture effect inherent to these catalysts, a more environmentally friendly gas product was produced, comprising H2 and CH4 as the main components.

Nanomaterials ◽  
2020 ◽  
Vol 11 (1) ◽  
pp. 76
Author(s):  
Thanh-Lieu Thi Le ◽  
Lam Tan Nguyen ◽  
Hoai-Hue Nguyen ◽  
Nguyen Van Nghia ◽  
Nguyen Minh Vuong ◽  
...  

Nanostructures of titanium nitride (TiN) have recently been considered as a new class of plasmonic materials that have been utilized in many solar energy applications. This work presents the synthesis of a novel nanostructure of TiN that has a nanodonut shape from natural ilmenite ore using a low-cost and bulk method. The TiN nanodonuts exhibit strong and spectrally broad localized surface plasmon resonance absorption in the visible region centered at 560 nm, which is well suited for thermoplasmonic applications as a nanoscale heat source. The heat generation is investigated by water evaporation experiments under simulated solar light, demonstrating excellent solar light harvesting performance of the nanodonut structure.


Atmosphere ◽  
2021 ◽  
Vol 12 (1) ◽  
pp. 91
Author(s):  
Santiago Lopez-Restrepo ◽  
Andres Yarce ◽  
Nicolás Pinel ◽  
O.L. Quintero ◽  
Arjo Segers ◽  
...  

The use of low air quality networks has been increasing in recent years to study urban pollution dynamics. Here we show the evaluation of the operational Aburrá Valley’s low-cost network against the official monitoring network. The results show that the PM2.5 low-cost measurements are very close to those observed by the official network. Additionally, the low-cost allows a higher spatial representation of the concentrations across the valley. We integrate low-cost observations with the chemical transport model Long Term Ozone Simulation-European Operational Smog (LOTOS-EUROS) using data assimilation. Two different configurations of the low-cost network were assimilated: using the whole low-cost network (255 sensors), and a high-quality selection using just the sensors with a correlation factor greater than 0.8 with respect to the official network (115 sensors). The official stations were also assimilated to compare the more dense low-cost network’s impact on the model performance. Both simulations assimilating the low-cost model outperform the model without assimilation and assimilating the official network. The capability to issue warnings for pollution events is also improved by assimilating the low-cost network with respect to the other simulations. Finally, the simulation using the high-quality configuration has lower error values than using the complete low-cost network, showing that it is essential to consider the quality and location and not just the total number of sensors. Our results suggest that with the current advance in low-cost sensors, it is possible to improve model performance with low-cost network data assimilation.


2021 ◽  
Vol 640 (4) ◽  
pp. 042014
Author(s):  
E N Turin ◽  
A N Susskiy ◽  
R S Stukalov ◽  
M V Shestopalov ◽  
E L Turina ◽  
...  
Keyword(s):  
Low Cost ◽  

Sensors ◽  
2020 ◽  
Vol 20 (19) ◽  
pp. 5697
Author(s):  
Chang Sun ◽  
Shihong Yue ◽  
Qi Li ◽  
Huaxiang Wang

Component fraction (CF) is one of the most important parameters in multiple-phase flow. Due to the complexity of the solid–liquid two-phase flow, the CF estimation remains unsolved both in scientific research and industrial application for a long time. Electrical resistance tomography (ERT) is an advanced type of conductivity detection technique due to its low-cost, fast-response, non-invasive, and non-radiation characteristics. However, when the existing ERT method is used to measure the CF value in solid–liquid two-phase flow in dredging engineering, there are at least three problems: (1) the dependence of reference distribution whose CF value is zero; (2) the size of the detected objects may be too small to be found by ERT; and (3) there is no efficient way to estimate the effect of artifacts in ERT. In this paper, we proposed a method based on the clustering technique, where a fast-fuzzy clustering algorithm is used to partition the ERT image to three clusters that respond to liquid, solid phases, and their mixtures and artifacts, respectively. The clustering algorithm does not need any reference distribution in the CF estimation. In the case of small solid objects or artifacts, the CF value remains effectively computed by prior information. To validate the new method, a group of typical CF estimations in dredging engineering were implemented. Results show that the new method can effectively overcome the limitations of the existing method, and can provide a practical and more accurate way for CF estimation.


1983 ◽  
Vol 105 (1) ◽  
pp. 73-79
Author(s):  
A. A. Kudirka ◽  
R. H. Smoak

Development of ceramic receiver technology for advanced solar thermal energy applications is being pursued in order to achieve significant reductions in energy cost and increase the potential application of solar thermal energy. Basically, structural ceramics are being seriously considered for solar applications because of their high temperature capability, their nonstrategic nature, and their potential for low cost. In this paper, candidate ceramic materials for solar receivers and their characteristics are described, potentially applicable fabrication and processing methods are discussed, and their applicability and promise for solar receivers is assessed. Receiver design requirements as well as system requirements for solar applications are reviewed. Promising areas of application of ceramic receivers in the near future are also discussed. Current ceramic receiver development status and plans are described, including one receiver which has been successfully tested at gas exit temperatures of up to 1425°C.


2003 ◽  
Vol 11 (4) ◽  
pp. 209-215 ◽  
Author(s):  
Keng Chen ◽  
Stephen Shumack ◽  
Richard Wootton

2013 ◽  
Vol 787 ◽  
pp. 382-387
Author(s):  
Li Zhou ◽  
Yuan Kui Ding ◽  
Pai Feng Luo

A facile low-cost non-vacuum process for fabrication of high quality CuInSe2(CIS) films is described, which indicates a promising way for the application in thin film solar cells. First, citrate-capped Cu11In9alloy nanoparticles are synthesized by hot-injection method after a system research on the different reaction time and Cu-In ratio of the raw materials. From the TEM and XRD results, we can see that uniform spherical nanoparticles with dominant Cu11In9phase and less particle-to-particle agglomeration are successfully achieved in this study. Then, employing spray and RTP selenization process, high quality CIS films with dense and big grains are obtained, which show the single chalcopyrite structure and the preferred (112) orientation. An energy band gap about 1.01 eV is measured through the absorption spectroscopy measurement in our work.


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