scholarly journals Study of Al2O3 Sol-Gel Coatings on X20Cr13 in Artificial North German Basin Geothermal Water at 150 °C

Coatings ◽  
2021 ◽  
Vol 11 (5) ◽  
pp. 526
Author(s):  
Gabriela Aristia ◽  
Le Quynh Hoa ◽  
Marianne Nofz ◽  
Regine Sojref ◽  
Ralph Bäßler

Al2O3 has been widely used as a coating in industrial applications due to its excellent chemical and thermal resistance. Considering high temperatures and aggressive mediums exist in geothermal systems, Al2O3 can be a potential coating candidate to protect steels in geothermal applications. In this study, γ-Al2O3 was used as a coating on martensitic steels by applying AlOOH sol followed by a heat treatment at 600 °C. To evaluate the coating application process, one-, two-, and three-layer coatings were tested in the artificial North German Basin (NGB), containing 166 g/L Cl−, at 150 °C and 1 MPa for 168 h. To reveal the stability of the Al2O3 coating in NGB solution, three-layer coatings were used in exposure tests for 24, 168, 672, and 1296 h, followed by surface and cross-section characterization. SEM images show that the Al2O3 coating was stable up to 1296 h of exposure, where the outer layer mostly transformed into boehmite AlOOH with needle-like crystals dominating the surface. Closer analysis of cross-sections showed that the interface between each layer was affected in long-term exposure tests, which caused local delamination after 168 h of exposure. In separate experiments, electrochemical impedance spectroscopy (EIS) was performed at 150 °C to evaluate the changes of coatings within the first 24 h. Results showed that the most significant decrease in the impedance is within 6 h, which can be associated with the electrolyte penetration through the coating, followed by the formation of AlOOH. Here, results of both short-term EIS measurements (up to 24 h) and long-term exposure tests (up to 1296 h) are discussed.

Author(s):  
Seremak Wioletta ◽  
Baszczuk Agnieszka ◽  
Jasiorski Marek ◽  
Gibas Anna ◽  
Winnicki Marcin

AbstractThis work shows that the titanium dioxide coatings obtained by low-pressure cold gas spraying with the use of the sol–gel amorphous TiO2 powder are characterized by photocatalytic activity despite their partial amorphous content. Moreover, the research outcome suggests that the decomposition rate of organic pollutants is enhanced after long-term exposure to moisture. The condensation humidity test is not detrimental to the continuity and integrity of the coating, but the phase composition of coatings changes—with the exposure to water vapor, the portion of the amorphous phase crystallizes into brookite. The mechanism responsible for the conversion of amorphous TiO2 into brookite is attributed to the water-driven dissolution and reprecipitation of TiO6 octahedra. It has been shown that an additional parameter necessary for the stabilization of the brookite is the oxygen depletion of the amorphous structure of titanium dioxide. Considering the results presented in this paper and the advantages of a portable, low-pressure cold spray system for industrial applications, it is expected that TiO2 coatings produced from a sol–gel feedstock powder can be further developed and tested as efficient photocatalysts.


Author(s):  
Kenji Kako ◽  
Susumu Yamada ◽  
Masatsugu Yaguchi ◽  
Yusuke Minami

Type IV damage has been found at several ultra-supercritical (USC) plants that used high-chromium martensitic steels in Japan, and the assessment of the remaining life of the steels is important for electric power companies. The assessment of the remaining life needs long-term creep data for over 10 years, but such data are limited. We have attempted to assess the remaining life by creep tests and by microstructural observation of Grade 91 steels welded pipes which were used in USC plants for over 10 years. Following the results of microstructural observation of USC plant pipes, we find that microstructures, especially distribution of MX precipitates, have large effect on the creep life of Grade 91 steels.


Geophysics ◽  
2005 ◽  
Vol 70 (4) ◽  
pp. R45-R56 ◽  
Author(s):  
Lars Nielsen ◽  
Hans Thybo ◽  
Martin Glendrup

Seismic wide-angle data were recorded to more than 300-km offset from powerful airgun sources during the MONA LISA experiments in 1993 and 1995 to determine the seismic-velocity structure of the crust and uppermost mantle along three lines in the southeastern North Sea with a total length of 850 km. We use the first arrivals observed out to an offset of 90 km to obtain high-resolution models of the velocity structure of the sedimentary layers and the upper part of the crystalline crust. Seismic tomographic traveltime inversion reveals 2–8-km-thick Paleozoic sedimentary sequences with P-wave velocities of 4.5–5.2 km/s. These sedimentary rocks are situated below a Mesozoic-Cenozoic sequence with variable thickness: ∼2–3 km on the basement highs, ∼2–4 km in the Horn Graben and the North German Basin, and ∼6–7 km in the Central Graben. The thicknesses of the Paleozoic sedimentary sequences are ∼3–5 km in the Central Graben, more than 4 km in the Horn Graben, up to ∼4 km on the basement highs, and up to 8 km in the North German Basin. The Paleozoic strata are clearly separated from the shallower and younger sequences with velocities of ∼1.8–3.8 km/s and the deeper crystalline crust with velocities of more than 5.8–6.0 km/s in the tomographic P-wave velocity model. Resolution tests show that the existence of the Paleozoic sediments is well constrained by the data. Hence, our wide-angle seismic models document the presence of Paleozoic sediments throughout the southeastern North Sea, both in the graben structures and in deep basins on the basement highs.


2020 ◽  
Vol 318 ◽  
pp. 01040
Author(s):  
Dimitrios I. Zagkliveris ◽  
Azarias Mavropoulos ◽  
Efstathios Ntovinos ◽  
Georgios K. Triantafyllidis

A large variety of protective coating is being used in industrial applications to improve the resistance of the metallic substrates against corrosion. The pack-cementation method for boronizing and borochromizing is effective to produce extremely hard and corrosion resistant thick coatings and, additionally, is a low-cost and simple technique. In the present study, AISI 4140 steel specimens underwent boronizing and afterwards chromizing by the pack-cementation method using B4C as boron source and Fe-Cr as chromium source, respectively. In both treatments the appropriate activators were used. After chromizing the boronized substrate, a mixed boride phase FeCrB was formed, as it was confirmed by X-ray Diffractometry (XRD). The boronized and the borochromized specimens were subjected to Electrochemical Impedance Spectroscopy (EIS). From the analysis of the frequency response of the coating systems (Bode and Nyquist display), the conclusion that the borochromized specimens were significantly more corrosion resistant was extracted. Finally, data of optical and electron microscopy contribute to the validity of the conclusions.


2011 ◽  
Vol 86 (12) ◽  
pp. 2895-2899 ◽  
Author(s):  
Kiyoyuki Shiba ◽  
Hiroyasu Tanigawa ◽  
Takanori Hirose ◽  
Hideo Sakasegawa ◽  
Shiro Jitsukawa

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