scholarly journals Investigating the Potential of Flexible and Pre-Organized Tetraamide Ligands to Encapsulate Anions in One-Dimensional Coordination Polymers: Synthesis, Spectroscopic Studies and Crystal Structures

Crystals ◽  
2021 ◽  
Vol 11 (1) ◽  
pp. 77
Author(s):  
Nur Shuhaila Haryani Haris ◽  
Nafisah Mansor ◽  
Mohd Sukeri Mohd Yusof ◽  
Christopher J. Sumby ◽  
Maisara Abdul Kadir
Keyword(s):  
Coordination Polymers ◽  
Spectroscopic Studies ◽  
Anion Receptors ◽  
One Dimensional ◽  
Molecular Receptors ◽  
X Ray Crystallography ◽  
Potential Applications ◽  
Charge Balancing ◽  
Nitrate Anions ◽  
Significant Attention

The synthesis of amide-based molecules, possessing pre-organized structures, has received significant attention due to their potential applications as molecular receptors and as components of nanomaterials. In this study, four extended tetraamide ligands incorporating ethylene and propylene spacers, namely 1,2-bis[N,N′-6-(3-pyridylmethylamido)pyridyl-2-carboxyamido]ethane (L1), 1,2-bis[N,N′-6-(4-pyridylmethylamido)pyridyl-2-carboxyamido]ethane (L2), 1,2-bis[N,N′-6-(3-pyridylmethylamido)pyridyl-2-carboxyamido]propane (L3) and 1,2-bis[N,N′-6-(4-pyridylmethylamido)pyridyl-2-carboxyamido]propane (L4), were successfully synthesized. Further, reaction of L2 and L4, incorporating pendant 4-pyridyl donors as the metal coordinating sites, with cadmium salts, produced two close-packed one-dimensional coordination polymers, {[Cd3(L2)4(H2O)10](NO3)6·12H2O·CH3OH}n and {[Cd(SO4)(L4)(H2O)2]·4H2O·CH3OH}n. X-ray crystallography reveals that the flexible tetraamide ligands fold upon themselves in the coordination polymer structure. As a consequence, the anion pocket in {[Cd(SO4)(L4)(H2O)2]·4H2O·CH3OH}n incorporating the ligand with the propylene spacer was blocked from encapsulating charge-balancing anions, which were involved in bridging the di-cadmium units. Interestingly, a strong interaction between the 2,6-pyridine dicarboxamide moiety with the nitrate anions was found in {[Cd3(L2)4(H2O)10](NO3)6·12H2O·CH3OH}n, showing potential for materials made from these ligands to serve as anion receptors.

One-dimensional CuIIcoordination polymers containingC2h-symmetric 1,1′:4′,1′′-terphenyl-3,3′-dicarboxylate linkers

2015 ◽  
Vol 71 (10) ◽  
pp. 929-935 ◽  
Author(s):  
Hyun-Chul Kim ◽  
Ja-Min Gu ◽  
Seong Huh ◽  
Chul-Hyun Yo ◽  
Youngmee Kim
Keyword(s):  
Coordination Polymers ◽  
Three Dimensional ◽  
Polymer Chains ◽  
Water Molecules ◽  
Binding Modes ◽  
Bridging Ligands ◽  
One Dimensional ◽  
X Ray Crystallography ◽  
Dimensional Network ◽  
The One

Two new one-dimensional CuIIcoordination polymers (CPs) containing theC2h-symmetric terphenyl-based dicarboxylate linker 1,1′:4′,1′′-terphenyl-3,3′-dicarboxylate (3,3′-TPDC), namelycatena-poly[[bis(dimethylamine-κN)copper(II)]-μ-1,1′:4′,1′′-terphenyl-3,3′-dicarboxylato-κ4O,O′:O′′:O′′′] monohydrate], {[Cu(C20H12O4)(C2H7N)2]·H2O}n, (I), andcatena-poly[[aquabis(dimethylamine-κN)copper(II)]-μ-1,1′:4′,1′′-terphenyl-3,3′-dicarboxylato-κ2O3:O3′] monohydrate], {[Cu(C20H12O4)(C2H7N)2(H2O)]·H2O}n, (II), were both obtained from two different methods of preparation: one reaction was performed in the presence of 1,4-diazabicyclo[2.2.2]octane (DABCO) as a potential pillar ligand and the other was carried out in the absence of the DABCO pillar. Both reactions afforded crystals of different colours,i.e.violet plates for (I) and blue needles for (II), both of which were analysed by X-ray crystallography. The 3,3′-TPDC bridging ligands coordinate the CuIIions in asymmetric chelating modes in (I) and in monodenate binding modes in (II), forming one-dimensional chains in each case. Both coordination polymers contain two coordinated dimethylamine ligands in mutuallytranspositions, and there is an additional aqua ligand in (II). The solvent water molecules are involved in hydrogen bonds between the one-dimensional coordination polymer chains, forming a two-dimensional network in (I) and a three-dimensional network in (II).

Synthesis, X-ray crystallography, thermogravimetric analysis and spectroscopic characterization of isostructural one-dimensional coordination polymers as sorbents for some anions

CrystEngComm ◽  
2018 ◽  
Vol 20 (13) ◽  
pp. 1783-1796 ◽  
Author(s):  
Bahram Ghanbari ◽  
Leila Shahhoseini ◽  
Agata Owczarzak ◽  
Maciej Kubicki ◽  
Reza Kia ◽  
...  
Keyword(s):  
Thermogravimetric Analysis ◽  
Coordination Polymers ◽  
Spectroscopic Characterization ◽  
One Dimensional ◽  
X Ray ◽  
X Ray Crystallography

A new series of coordination polymers capable of adsorbing anions have been synthesized by employing a dipyridine substituted diazacrown macrocycle as linker.

Synthesis, Characterization and Crystal Structure of Coordination Polymers Developed as Anion Receptor

2018 ◽  
Vol 273 ◽  
pp. 134-139
Author(s):  
M.A. Kadir ◽  
Christopher J. Sumby
Keyword(s):  
Coordination Polymer ◽  
Coordination Polymers ◽  
Cadmium Nitrate ◽  
Two Dimensional ◽  
Anion Receptor ◽  
Slow Evaporation ◽  
One Dimensional ◽  
X Ray ◽  
X Ray Crystallography ◽  
Good Potential

Reaction of diamide ligand, namelyN,N’-2,6-bis (4-pyridylmethyl) pyridine dicarboxamide (L) with cadmium nitrate and cadmium perchlorate has given rise to the formation of two types coordination polymers. Compound (CP1-Cd) with formula molecule {[Cd (L)2(H2O)2](NO3)2·6H2O}nis a one-dimensional coordination polymer while compound (CP2-Cd), with formula molecule {[Cd (L)2(H2O)2](ClO4)2·31⁄2H2O.CH3OH}n, is a two dimensional coordination polymer. These coordination polymers were preparedviaslow evaporation methods and completely characterized by combination of solid state techniques such as Fourier Transform Infrared (FTIR) spectroscopy, elemental analysis and X-ray crystallography. This study revealed that coordination polymers derived fromN,N’-2,6-bis (4-pyridylmethyl) pyridine dicarboxamide can accommodate anions with different sizes, showing good potential as anion receptor.

Syntheses and Spectroscopic Studies of Some New Diazaphospholes and Diazaphosphorinanes. Crystal Structure of 4

2005 ◽  
Vol 60 (10) ◽  
pp. 1021-1026 ◽  
Author(s):  
Khodayar Gholivand ◽  
Zahra Shariatinia ◽  
Mehrdad Pourayoubi ◽  
Sedigheh Farshadian
Keyword(s):  
Crystal Structure ◽  
Ir Spectroscopy ◽  
Spectroscopic Studies ◽  
Coupling Constants ◽  
Crystalline Lattice ◽  
Polymeric Chain ◽  
Ring Strain ◽  
One Dimensional ◽  
X Ray ◽  
X Ray Crystallography

New diazaphospholes and diazaphosphorinanes with formula were synthesized and characterized by 1H, 13C, 31P NMR and IR spectroscopy and elemental analysis. The structure of compound 1 has been determined by X-ray crystallography. A one-dimensional polymeric chain was observed in the crystalline lattice produced by intermolecular -P=O. . .H-N- and -C=O. . .H-N-hydrogen bonds. Compounds 1 and 2 contain five-membered rings and show high values for 2J(PNH) and 2J(P,C) coupling constants due to the ring strain. These constants are reduced seriously in compounds with six-membered rings. In compound 6 with CCl3C(O)NH moiety, all phosphorus-hydrogen couplings are zero.

Ln-Ag heterometallic coordination polymers

2015 ◽  
Vol 35 (2) ◽  
pp. 81-113 ◽  
Author(s):  
Ming Fang ◽  
Bin Zhao
Keyword(s):  
Coordination Polymer ◽  
Coordination Polymers ◽  
Luminescent Properties ◽  
Research Development ◽  
Carboxylate Ligands ◽  
One Dimensional ◽  
Potential Applications ◽  
Heterometallic Coordination Polymers ◽  
Intense Activity ◽  
2D And 3D

AbstractThe last few years have seen an increasing interest in the study of lanthanide-silver (Ln-Ag) heterometallic coordination polymers due to their potential applications. It has led to intense activity of chemists to produce Ln-Ag heterometallic coordination polymers and investigate their properties. In this review, we summarize recent research development in the fascinating and challenging field of Ln-Ag heterometallic coordination polymers. This review covers 182 Ln-Ag heterometallic coordination polymers, which are categorized by the kind of ligand as N-heterocyclic carboxylate ligands and others. There are three categories of Ln-Ag coordination polymer based on N-heterocyclic carboxylate ligands: one dimensional (1D), 2D, and 3D. The 3D part was divided into Ln-Ag coordination polymers based on pyridine carboxylate ligands and other N-heterocyclic carboxylate ligands. This perspective illustrates the coordination features of compounds constructed by N-heterocyclic carboxylate ligands. Luminescent properties are also discussed.

Two-dimensional ZnIIand one-dimensional CoIIcoordination polymers based on benzene-1,4-dicarboxylate and pyridine ligands

2016 ◽  
Vol 72 (2) ◽  
pp. 133-138 ◽  
Author(s):  
Li-Juan Zhou ◽  
Chang-Bao Han ◽  
Yu-Ling Wang
Keyword(s):  
Coordination Polymers ◽  
Three Dimensional ◽  
Chain Structure ◽  
Two Dimensional ◽  
Compound I ◽  
One Dimensional ◽  
Pyridine Ligands ◽  
Carboxylate Groups ◽  
Potential Applications ◽  
Compound Ii

Coordination polymers constructed from metal ions and organic ligands have attracted considerable attention owing to their diverse structural topologies and potential applications. Ligands containing carboxylate groups are among the most extensively studied because of their versatile coordination modes. Reactions of benzene-1,4-dicarboxylic acid (H2BDC) and pyridine (py) with ZnIIor CoIIyielded two new coordination polymers, namely, poly[(μ4-benzene-1,4-dicarboxylato-κ4O:O′:O′′:O′′′)(pyridine-κN)zinc(II)], [Zn(C8H4O2)(C5H5N)]n, (I), andcatena-poly[aqua(μ3-benzene-1,4-dicarboxylato-κ3O:O′:O′′)bis(pyridine-κN)cobalt(II)], [Co(C8H4O2)(C5H5N)2(H2O)]n, (II). In compound (I), the ZnIIcation is five-coordinated by four carboxylate O atoms from four BDC2−ligands and one pyridine N atom in a distorted square-pyramidal coordination geometry. Four carboxylate groups bridge two ZnIIions to form centrosymmetric paddle-wheel-like Zn2(μ2-COO)4units, which are linked by the benzene rings of the BDC2−ligands to generate a two-dimensional layered structure. The two-dimensional layer is extended into a three-dimensional supramolecular structure with the help of π–π stacking interactions between the aromatic rings. Compound (II) has a one-dimensional double-chain structure based on Co2(μ2-COO)2units. The CoIIcations are bridged by BDC2−ligands and are octahedrally coordinated by three carboxylate O atoms from three BDC2−ligands, one water O atom and two pyridine N atoms. Interchain O—H...O hydrogen-bonding interactions link these chains to form a three-dimensional supramolecular architecture.

Photo-induced variation of magnetism in coordination polymers with ligand-based electron transfer

2021 ◽  
Author(s):  
Yan-Lei Lu ◽  
Wen-Long Lan ◽  
Wei Shi ◽  
Qionghua Jin ◽  
Peng Cheng
Keyword(s):  
Electron Transfer ◽  
Coordination Polymers ◽  
Optical Memory ◽  
High Density ◽  
Information Storage ◽  
Memory Devices ◽  
Storage Materials ◽  
Potential Applications ◽  
Induced Variation

Photo-induced variation of magnetism from ligand-based electron transfer have been extensively studied because of their potential applications in magneto-optical memory devices, light-responsive switches, and high-density information storage materials. In this...

Anion and solvent controlled growth of crystalline and amorphous zinc(II) coordination polymers and a molecular complex

2021 ◽  
Author(s):  
Claire Deville ◽  
Henrik Særkjær Jeppesen ◽  
Vickie McKee ◽  
Nina Lock
Keyword(s):  
Coordination Polymers ◽  
Molecular Complex ◽  
Research Field ◽  
Metal Coordination ◽  
Controlled Growth ◽  
Bottom Up ◽  
One Dimensional

Controlled bottom-up synthesis of amorphous coordination polymers with tailored metal coordination is a research field in its infancy. In this study, synthesis control was achieved to selectively prepare one-dimensional (1D)...

scholarly journals Quantifying photoinduced carriers transport in exciton–polariton coupling of MoS2 monolayers

2021 ◽  
Vol 5 (1) ◽  
Author(s):  
Min-Wen Yu ◽  
Satoshi Ishii ◽  
Shisheng Li ◽  
Ji-Ren Ku ◽  
Jhen-Hong Yang ◽  
...  
Keyword(s):  
Electronic Energy ◽  
Plasmonic Nanostructures ◽  
Transition Metal Dichalcogenide ◽  
Metallic Nanoparticle ◽  
Rabi Splitting ◽  
One Dimensional ◽  
Induced Dipole ◽  
Mos2 Monolayers ◽  
Plasmon Polaritons ◽  
Significant Attention

AbstractExciton–polariton coupling between transition metal dichalcogenide (TMD) monolayer and plasmonic nanostructures generates additional states that are rich in physics, gaining significant attention in recent years. In exciton–polariton coupling, the understanding of electronic-energy exchange in Rabi splitting is critical. The typical structures that have been adopted to study the coupling are “TMD monolayers embedded in a metallic-nanoparticle-on-mirror (NPoM) system.” However, the exciton orientations are not parallel to the induced dipole direction of the NPoM system, which leads to inefficient coupling. Our proposed one-dimensional plasmonic nanogrooves (NGs) can align the MoS2 monolayers’ exciton orientation and plasmon polaritons in parallel, which addresses the aforementioned issue. In addition, we clearly reveal the maximum surface potential (SP) change on intermediate coupled sample by the photo-excitation caused by the carrier rearrangement. As a result, a significant Rabi splitting (65 meV) at room temperature is demonstrated. Furthermore, we attribute the photoluminescence enhancement to the parallel exciton–polariton interactions.

scholarly journals Topological guided-mode resonances at non-Hermitian nanophotonic interfaces

Nanophotonics ◽  
2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Ki Young Lee ◽  
Kwang Wook Yoo ◽  
Youngsun Choi ◽  
Gunpyo Kim ◽  
Sangmo Cheon ◽  
...  
Keyword(s):  
Fundamental Study ◽  
One Dimensional ◽  
Guided Mode ◽  
Wall Structures ◽  
Potential Applications ◽  
Photonic Microstructures ◽  
Guided Mode Resonance ◽  
The One ◽  
Photonic Band ◽  
Topological Correlations

Abstract The topological properties of photonic microstructures are of great interest because of their experimental feasibility for fundamental study and potential applications. Here, we show that robust guided-mode-resonance states exist in photonic domain-wall structures whenever the complex photonic band structures involve certain topological correlations in general. Using the non-Hermitian photonic analogy of the one-dimensional Dirac equation, we derive essential conditions for photonic Jackiw-Rebbi-state resonances taking advantage of unique spatial confinement and spot-like spectral features which are remarkably robust against random parametric errors. Therefore, the proposed resonance configuration potentially provides a powerful method to create compact and stable photonic resonators for various applications in practice.

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