scholarly journals Oxidation Stability of Natural Ester Modified by Means of Fullerene Nanoparticles

Energies ◽  
2021 ◽  
Vol 14 (2) ◽  
pp. 490
Author(s):  
Dominika Szcześniak ◽  
Piotr Przybylek
Keyword(s):  
Aging Process ◽  
Power Transformer ◽  
Oxidation Stability ◽  
Acid Number ◽  
Pure Liquid ◽  
Insulating Liquids ◽  
Fullerene Nanoparticles ◽  
Materials Used ◽  
Insulating Liquid ◽  
Natural Ester

Increasing environmental demands influence the requirements for devices and materials used in the power industry. One example is a power transformer and an electro-insulating liquid used in it. In order to meet these requirements, electro-insulating liquids should be characterized by, inter alia, high biodegradability and good fire properties. One of such liquids is natural ester. However, its oxidation stability is low in comparison to mineral oil and demands improvement, which can be achieved by the addition of an antioxidant. The authors of this work used fullerene nanoparticles for that purpose. Pure natural ester samples were prepared, and samples with two concentrations of fullerene, 250 mg/L and 500 mg/L in natural ester. All these samples were aged in a thermal oxidation process. Thereafter, the aging properties of all the samples were compared to assess the oxidation stability of modified liquids. Moreover, the electrical properties of prepared insulating liquids were investigated to assess if fullerene deteriorates these properties after aging process. Based on the obtained results, it was proved that the aging process slowed down in the case of both fullerene concentrations in ester. The acid number of natural ester modified using fullerene was lower than in the case of pure liquid.

scholarly journals Alternative liquid dielectrics in power transformer insulation: a review

2021 ◽  
Vol 23 (3) ◽  
pp. 1761
Author(s):  
Bokang Agripa Tlhabologo ◽  
Ravi Samikannu ◽  
Modisa Mosalaosi
Keyword(s):  
Power Transformer ◽  
Chemical Properties ◽  
Fire Risk ◽  
Mineral Oil ◽  
Acid Number ◽  
Gas Analysis ◽  
International Standards ◽  
Liquid Dielectrics ◽  
Transformer Insulation ◽  
Natural Ester

Transformer liquid dielectrics evolved where mineral oil has been the dominant choice until emergence of synthetic esters and natural esters. Natural ester-based oils have been under extensive investigations to enhance their properties for replacing petroleum-based mineral oil, which is non-biodegradable and has poor dielectric properties. This paper focuses on exposition of natural ester oil application in mixed transformer liquid dielectrics. Physical, chemical, electrical, and ageing characteristics of these dielectrics and the dissolved gas analysis (DGA) were reviewed. Physical properties include viscosity, pour point, flash and fire point which are vital indicators of heat insulation and fire risk. Chemical properties considered are water content, acid number, DGA, corrosive sulphur, and sludge content to limit and detect degradation and corrosion due to oil ageing. Electrical properties including breakdown voltage were considered for consistent insulation during overload and fault conditions. These properties of evolving alternative dielectrics were reviewed based on ASTM International standards and International Electro technical Commission standards for acceptable transformer liquid dielectrics. This review paper was compiled to avail modern methodologies for both the industry and scholars, also providing the significance of using mixed dielectrics for power transformers as they are concluded to show superiority over non-mixed dielectrics.

scholarly journals Electrostatic Charging Tendency Analysis Concerning Retrofilling Power Transformers with Envirotemp FR3 Natural Ester

Energies ◽  
2020 ◽  
Vol 13 (17) ◽  
pp. 4420 ◽  
Author(s):  
Maciej Zdanowski
Keyword(s):  
Mineral Oil ◽  
Volume Density ◽  
Point Of View ◽  
Pipe Material ◽  
Mineral Oils ◽  
Insulating Liquids ◽  
Electrostatic Charging ◽  
Tendency Analysis ◽  
Insulating Liquid ◽  
Natural Ester

Natural and synthetic esters are liquids characterized by insulating properties, high flash point, and biodegradability. For this reason, they are more and more often used as an alternative to conventional mineral oils. Esters are used to fill new or operating transformers previously filled with mineral oil (retrofilling). It is technically unfeasible to completely remove mineral oil from a transformer. Its small residues create with esters a mixture with features significantly different from those of the base liquids. This article presents electrostatic charging tendency (ECT) tests for mixtures of fresh and aged Trafo EN mineral oil with Envirotemp FR3 natural ester from the retrofilling point of view. Under unfavorable conditions, the flow electrification phenomenon can damage the solid insulation in transformers with forced oil circulation. The ECT of the insulating liquids has been specified using the volume density of the qw charge. This parameter has been determined using the Abedian–Sonin model on the basis of the electrification current measured in the flow system, as well as selected physicochemical properties of the liquids. It was shown that ECT is strongly dependent on the type of insulating liquid and pipe material, as well as the composition of the mixtures. The most important finding from the research is that a small amount (up to 10%) of fresh and aged mineral oil is effective in reducing the ECT of Envirotemp FR3 natural ester.

scholarly journals Electrical insulating liquid: A review

2017 ◽  
Vol 07 (04) ◽  
pp. 1730001 ◽  
Author(s):  
Deba Kumar Mahanta ◽  
Shakuntala Laskar
Keyword(s):  
Coconut Oil ◽  
Mineral Oil ◽  
Insulating Materials ◽  
Insulating Material ◽  
Insulating Liquids ◽  
Materials Used ◽  
Insulating Liquid ◽  
Transformer Insulation ◽  
Oil Sunflower

Insulating liquid plays an important role for the life span of the transformer. Petroleum-based mineral oil has become dominant insulating liquid of transformer for more than a century for its excellent dielectric and cooling properties. However, the usage of petroleum-based mineral oil, derived from a nonrenewable energy source, has affected the environment for its nonbiodegradability property. Therefore, researchers direct their attention to renewable and biodegradable alternatives. Palm fatty acid ester, coconut oil, sunflower oil, etc. are considered as alternatives to replace mineral oil as transformer insulation liquid. This paper gives an extensive review of different liquid insulating materials used in a transformer. Characterization of different liquids as an insulating material has been discussed. An attempt has been made to classify different insulating liquids-based on different properties.

scholarly journals Lightning Impulse Withstand of Natural Ester Liquid

Energies ◽  
2018 ◽  
Vol 11 (8) ◽  
pp. 1964 ◽  
Author(s):  
Stephanie Haegele ◽  
Farzaneh Vahidi ◽  
Stefan Tenbohlen ◽  
Kevin Rapp ◽  
Alan Sbravati
Keyword(s):  
Breakdown Voltage ◽  
Dielectric Strength ◽  
Mineral Oil ◽  
Homogeneous Field ◽  
Inhomogeneous Field ◽  
Insulating Liquids ◽  
Lightning Impulse ◽  
Insulating Liquid ◽  
Natural Ester ◽  
Inhomogeneity Factor

Due to the low biodegradability of mineral oil, intense research is conducted to define alternative liquids with comparable dielectric properties. Natural ester liquids are an alternative in focus; they are used increasingly as insulating liquid in distribution and power transformers. The main advantages of natural ester liquids compared to mineral oil are their good biodegradability and mainly high flash and fire points providing better fire safety. The dielectric strength of natural ester liquids is comparable to conventional mineral oil for homogeneous field arrangements. However, many studies showed a reduced dielectric strength for highly inhomogeneous field arrangements. This study investigates at which degree of inhomogeneity differences in breakdown voltage between the two insulating liquids occur. Investigations use lightning impulses with different electrode arrangements representing different field inhomogeneity factors and different gap distances. To ensure comparisons with existing transformer geometries, investigations are application-oriented using a transformer conductor model, which is compared to other studies. Results show significant differences in breakdown voltage from an inhomogeneity factor of 0.1 (highly inhomogeneous field) depending on the gap distance. Larger electrode gaps provide a larger inhomogeneity at which differences in breakdown voltages occur.

scholarly journals Investigation of Survival/Hazard Rate of Natural Ester Treated with Al2O3 Nanoparticle for Power Transformer Liquid Dielectric

Energies ◽  
2021 ◽  
Vol 14 (5) ◽  
pp. 1510
Author(s):  
Raymon Antony Raj ◽  
Ravi Samikannu ◽  
Abid Yahya ◽  
Modisa Mosalaosi
Keyword(s):  
Survival Rate ◽  
Hazard Rate ◽  
Power Transformer ◽  
Mineral Oil ◽  
Interpolation Polynomial ◽  
Distribution Functions ◽  
Flash Fire ◽  
Predicted Values ◽  
Natural Ester ◽  
Electrical Apparatus

Increasing usage of petroleum-based insulating oils in electrical apparatus has led to increase in pollution and, at the same time, the oils adversely affect the life of electrical apparatus. This increases the demand of Mineral Oil (MO), which is on the verge of extinction and leads to conducting tests on natural esters. This work discusses dielectric endurance of Marula Oil (MRO), a natural ester modified using Conductive Nano Particle (CNP) to replace petroleum-based dielectric oils for power transformer applications. The Al2O3 is a CNP that has a melting point of 2072 °C and a low charge relaxation time that allows time to quench free electrons during electrical discharge. Al2O3 is blended with the MRO and Mineral Oil (MO) in different concentrations. The measured dielectric properties are transformed into mathematical equations using the Lagrange interpolation polynomial functions and compared with the predicted values either using Gaussian or Fourier distribution functions. Addition of Al2O3 indicates that 0.75 g/L in MRO has an 80% survival rate and 20% hazard rate compared to MO which has 50% survival rate and 50% hazard rate. Considering the measured or interpolated values and the predicted values, they are used to identify the MRO and MO’s optimum concentration produces better results. The test result confirms the enhancement of the breakdown voltage up to 64%, kinematic viscosity is lowered by up to 40% at 110 °C, and flash/fire points of MRO after Al2O3 treatment enhanced to 14% and 23%. Hence the endurance of Al2O3 in MRO proves to be effective against electrical, physical and thermal stress.

scholarly journals Effect of the natural antioxidant eugenol on quality preservation of commercial biodiesels produced with soybean oil or waste frying oil during storage at different temperatures

2018 ◽  
Vol 40 ◽  
pp. 61
Author(s):  
Eliane Ferreira de Souza ◽  
Talita Cuenca Pina Moreira Ramos ◽  
Mikaelly Nayara Santos ◽  
Juliana Rodrigues Ferraz ◽  
Margarete Soares da Silva ◽  
...  
Keyword(s):  
Soybean Oil ◽  
Oxidation Stability ◽  
Oxidative Degradation ◽  
Acid Number ◽  
Natural Antioxidant ◽  
Waste Frying Oil ◽  
Antioxidant Efficiency ◽  
Accelerated Oxidation ◽  
Oxidation Test ◽  
Rancimat Method

The objetive of this study was to evaluate the eugenol antioxidant efficiency on the oxidation stability of commercial biodiesel synthesized from soybean oil (SB) and wast fring oil (ORB) by determining induction period (IP) and acid number (AN) during storage at 10 °C or in accelerated oxidation test at 85 °C. For the oxidation stability evaluation, the Rancimat method (EN 14112) and AN (ASTM D664) analyses were used. The initial studies showed that the antioxidants eugenol and TBHQ when added separately increased IP values for the two types of biodiesel analyzed. During the storage at 10 °C, the IP was reduced for all samples. However, the lowest reduction percentages were for samples containing eugenol (-2.07 and -11.30% for SB and ORB, respectively). In relation to AN, the samples with the antioxidant eugenol led a greater decrease of this index, with the 10000 mg kg-1 concentration being the most efficient in the conservation of biodiesel. In the accelerated oxidation test in oven at 85 °C, pure BS presented higher susceptibility to degradation than the sample containing 10000 mg kg-1 of eugenol. In both storage studies, the eugenol natural antioxidant efficiency in the control of oxidative degradation of biodiesel becomes evident. 

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