scholarly journals Determination of Lead Elemental Concentration and Isotopic Ratios in Coal Ash and Coal Fly Ash Reference Materials Using Isotope Dilution Thermal Ionization Mass Spectrometry

2019 ◽  
Vol 16 (23) ◽  
pp. 4772 ◽  
Author(s):  
Chaofeng Li ◽  
Huiqian Wu ◽  
Xuance Wang ◽  
Zhuyin Chu ◽  
Youlian Li ◽  
...  
Keyword(s):  
Lead Isotope ◽  
Thermal Ionization Mass Spectrometry ◽  
Environmental Science ◽  
Coal Fly Ash ◽  
Lead Isotopes ◽  
Coal Ash ◽  
Isotope Ratios ◽  
Ionization Mass ◽  
Pb Isotope ◽  
Lead Isotope Ratios

The rapid expansion of coal-fired power plants around the world has produced a huge volume of toxic elements associated with combustion residues such as coal fly ash (CFA) and coal ash (CA), which pose great threats to the global environment. It is therefore crucial for environmental science to monitor the migration and emission pathway of toxic elements such as CFA and CA. Lead isotopes have proved to be powerful tracers capable of dealing with this issue. Unfortunately, up to now, few high precision lead isotope data of CFA and CA certified reference materials (CRMs) determined by using the double spike technique have been reported. Hence, to facilitate the application of lead isotopes in environmental science, it is indispensable and urgent to determine a suite of high precision Pb isotope ratios and Pb elemental contents for CFA and CA CRMs. Here, we measured lead isotope ratios from four CFA and CA CRMs using thermal ionization mass spectrometry (TIMS) combined with the 204Pb–207Pb double spike method. Lead isotope ratios values of CRMs (GBW11124, GBW08401, GBW11125d, and JCFA-1) covered wide variation ranges from 17.993 to 19.228 for 206Pb/204Pb, from 15.513 to 15.675 for 207Pb/204Pb, and from 38.184 to 39.067 for 208Pb/204Pb. Lead isotope ratios of these CRMs, except for GBW11124, show good external reproducibility (2 RSD, n = 8), which is better than 0.05% for 206Pb/204Pb and 207Pb/204Pb, 0.07% for 208Pb/204Pb, 0.04% for 206Pb/207Pb, and 0.05% for 208Pb/206Pb. The Pb concentrations of these CRMs were determined using 207Pb single spike method. The reproducibility (1 RSD, n = 4) of Pb elemental content was <0.60%. This indicates the distribution of Pb elements in these CRMs is homogeneous. With the exception of GBW11124, the suite of CRMs can be used for determining CFA and CA matrix composition for quality control of Pb isotope analyses.

Lead- and strontium-isotope geochemistry of Paleozoic Sicker Group and Jurassic Bonanza Group volcanic rocks and Island Intrusions, Vancouver Island, British Columbia

1989 ◽  
Vol 26 (5) ◽  
pp. 894-907 ◽  
Author(s):  
Anne Andrew ◽  
Colin I. Godwin
Keyword(s):  
Lead Isotope ◽  
Isotope Geochemistry ◽  
Lead Isotopes ◽  
Volcanic Rocks ◽  
Isotope Ratios ◽  
Ore Deposits ◽  
Island Arc ◽  
Lead Isotope Ratios ◽  
Rock Suite ◽  
Isotope Analyses

Whole-rock and galena lead-isotope analyses have been obtained from the Sicker Group Paleozoic island-arc volcanic package and from a Jurassic island-arc represented by the Bonanza Group volcanics and Island Intrusions. Galena lead-isotope analyses from the volcanogenic ore deposits at the Buttle Lake mining camp in the Sicker Group provide estimates of the initial lead ratios for the Sicker Group. Lead-isotope signatures are uniform within each of the major orebodies, but the Myra orebody is less radiogenic than the older H–W orebody. This has major significance in terms of ore genesis for these important deposits.There are significant differences in isotopic composition between the Sicker Group and Devonian island-arc type rocks in the Shasta district, California, which rules out direct correlations between the rock units of these two areas. Relatively high initial values of 207Pb/204Pb (> 15.56) and 208Pb/204Pb (> 38.00) suggest that large quantities of crustal lead must have been involved in the formation of the Sicker Group volcanic rocks. Thus it is proposed that the trench related to the Paleozoic island arc had a substantial input of continental detritus and may have lain near a continent.The Jurassic island arc is characterized by low 207Pb/204Pb ratios (< 15.59), suggesting a more primitive arc environment than for the Paleozoic arc. Bonanza Group volcanic rocks contain lead that is less radiogenic than lead in the Island Intrusions. Present and initial lead-isotope ratios of both the Bonanza Group volcanics and Island intrusions follow the same trend, supporting the hypothesis that they are comagmatic. Lead isotopes from a galena vein within the Island Copper porphyry deposit plot with the initial ratios for Bonanza Group volcanics and Island Intrusions. This confirms the hypothesis that this mineralization is related to the Jurassic island-arc volcanic event.Initial lead-isotope ratios for the Jurassic rock suite form a linear array on both 207Pb/204Pb versus 206Pb/204Pb and 208Pb/204Pb versus 206Pb/204Pb plots. If interpreted as due to isotopic mixing, the more radiogenic end member has a composition that is lower in 207Pb/204Pb and higher in 206Pb/204Pb than typical upper continental crust. Assimilation of Sicker Group material during the emplacement of the Jurassic arc can explain the mixing trend.

Bio-Monitoring using Lead Isotope Ratios in Seagrass and Oysters

2002 ◽  
Vol 36 (1) ◽  
pp. 52-54 ◽  
Author(s):  
Niels C. Munksgaard ◽  
Cristy M. Moir ◽  
David L. Parry
Keyword(s):  
Environmental Samples ◽  
Isotope Ratio ◽  
Lead Isotope ◽  
Lead Concentration ◽  
Cost Effective ◽  
Isotope Ratios ◽  
Monitoring Tool ◽  
Pb Isotope ◽  
Lead Isotope Ratios ◽  
Bio Monitoring

The combined measurement of lead concentration and isotope ratios in organisms used as bio-monitors may provide a sensitive and cost-effective monitoring tool allowing an unambiguous assessment of the source of lead in environmental samples. Data presented here shows that dispersion of trace amounts of orederived Pb produced distinctive Pb isotope ratio changes in seagrass and oysters acting as sentinel accumulators.

Interpretation of Pb isotope compositions of galenas from the Midland Valley of Scotland and adjacent regions

1984 ◽  
Vol 75 (2) ◽  
pp. 85-96 ◽  
Author(s):  
John Parnell ◽  
Ian Swainbank
Keyword(s):  
Lower Devonian ◽  
Lead Isotope ◽  
Sedimentary Rocks ◽  
Isotope Ratios ◽  
Igneous Rocks ◽  
Pb Isotope ◽  
Lower Carboniferous ◽  
Granite Magma ◽  
Lower Palaeozoic ◽  
Caledonian Granite

ABSTRACTThe lead isotope compositions of 61 galenas from central and southern Scotland vary markedly between different regions. Most galenas from the southern Grampian Highlands yield isotope ratios (206Pb/204Pb 17·77 ± 0·25, 207Pb/204Pb 15·47 ± 0·05, 208Pb/204Pb 37·63 ± 0·26) less radiogenic than those from Midland Valley galenas (18·22 ± 0·12, 15·55 ± 0·05, 38·13 ± 0·14) whilst galena lead from the Southern Uplands (18·28 ± 0·12, 15·56 ± 0·03, 38·21 ± 0·18) is more radiogenic than that from the southern Midland Valley (18·12 ± 0·06, 15·52 ± 0·02, 38·06 ±0·10). The change in isotopie composition across the Highland Boundary fault reflects the presence or absence of Dalradian rocks which included a magmatic component of lead. Galenas from the Dalradian sequence in Islay, where igneous rocks are lacking, have a composition (18·14±0·04, 15·51±0·01, 37·90±0·02) more like Midland Valley galenas. In the Southern Uplands, galenas yield lead isotope ratios similar to those of feldspars from Caledonian granite (18·30 ± 0·14, 15·57 ± 0·04, 37·96 ± 0·15) analysed by Blaxland et al. (1979). The similar ratios reflect the incorporation of Lower Palaeozoic sedimentary rocks into the granite magma, rather than a granitic source for the mineralisation. The granites were then thermal-structural foci for later mineralising fluids which leached metals from the surrounding rocks. Within the Midland Valley, galenas hosted in Lower Devonian-Lower Carboniferous lavas are notably more radiogenic (18·31 ±0·12, 15·58 ± 0·06, 38·20 ± 0·16) than sediment-hosted galenas (18·14 ± 0·07, 15·52 ± 0·02, 38·08 ± 0·10). The Devonian lavas at least may have inherited lead from subducted (? Lower Palaeozoic) rock incorporated in the primary magma.

The identification of lead ammunition as a source of lead exposure in First Nations: The use of lead isotope ratios

2008 ◽  
Vol 393 (2-3) ◽  
pp. 291-298 ◽  
Author(s):  
Leonard J.S. Tsuji ◽  
Bruce C. Wainman ◽  
Ian D. Martin ◽  
Celine Sutherland ◽  
Jean-Philippe Weber ◽  
...  
Keyword(s):  
First Nations ◽  
Lead Exposure ◽  
Lead Isotope ◽  
Isotope Ratios ◽  
Lead Isotope Ratios ◽  
Lead Ammunition

scholarly journals Determination of lead isotope ratios in archeological products by ion microanalyzer.

1985 ◽  
Vol 1 (3) ◽  
pp. 227-230
Author(s):  
Shigenori MAEDA ◽  
Junko TAKASE ◽  
Yoshinori SUGITANI ◽  
Kozo NAGASHIMA
Keyword(s):  
Lead Isotope ◽  
Isotope Ratios ◽  
Lead Isotope Ratios
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