scholarly journals Long Term Sediment Modification Effects after Applications of P Inactivation Method in Meromictic Lake (Starodworskie Lake, Olsztyn Lakeland, Poland)

Land ◽  
2021 ◽  
Vol 10 (4) ◽  
pp. 411
Author(s):  
Renata Augustyniak ◽  
Renata Tandyrak ◽  
Michał Łopata ◽  
Jolanta Grochowska

Lake restoration is a part of geoengineering, which is a useful tool for landscape management. The phosphorus inactivation method is one of the most popular lake restoration methods. Using chemical compounds for P binding is leading to the creation of sediment “active layer”, which should show higher P adsorption abilities, compared to non-modified sediment. Howewer, it provides rather little information, how long the modified sediment remains active, and whether it is effective in continuous P binding. Lake meromixis is not commonly observed phenomenon, and sediment located in monimolimnion area is subjected long term anoxia. Therefore, observation of “active layer” in a meromictic lake can give very important data about durability of restoration effects. The object of our study was meromictic Starodworskie Lake (5.57 ha, max. depth 24.5 m), located in Olsztyn Lakeland, Poland. In the past the analyzed lake was subjected to various restoration methods, and phosphorus inactivation method by alum use (1994–1995) was the last used treatment type. The mixing regime of this lake had changed from bradimictic (before and during restoration time) into durable meromictic (post-restoration period). The research made two decades after implementing of P inactivation showed the presence of “active” sediment layer 10–15 cm below sediment surface. This sediment layer showed much higher content of P bound to aluminum, compared to surficial sediment layer. P binding molar ratio was assessed and amounted to 16.1 straightly after restoration and 6.1 after 21 years. This fraction amounts were higher that the values noted before restoration (ca. 358% higher than in 1994 and during restoration (ca. 86% higher than in 1995), which was probably the effect of continuous phosphorus adsorption by “active layer” in post-restoration period.

Water ◽  
2019 ◽  
Vol 11 (10) ◽  
pp. 2175 ◽  
Author(s):  
Renata Augustyniak ◽  
Jolanta Grochowska ◽  
Michał Łopata ◽  
Katarzyna Parszuto ◽  
Renata Tandyrak ◽  
...  

Artificial mixing and phosphorus inactivation methods using aluminum compounds are among the most popular lake restoration methods. Długie Lake (Olsztyńskie Lakeland, Poland) was restored using these two methods. Primarily, P precipitation and inactivation methods significantly increased the sorption properties of Długie Lake bottom sediment. Fifteen years after the termination of the restoration procedure, the alum-modified “active” sediment layer still has higher P adsorption abilities, which can limit P internal loading. Relatively low amounts of phosphates in the near-bottom water of Długie Lake, even in anoxia, as well as the fact that the assessed maximum sediment P sorption capacity is still higher than NH4Cl–P (labile P) and BD–P (Fe-bound P) sum (“native exchangeable P”), confirm that hypothesis. Among the tested P adsorption models for the sediment, the double Langmuir model showed the best fit to the experimental data (the highest R2 values). This may indicate that phosphorus adsorption by the tested sediments most likely occurs through phosphate binding at two types of active sorption sites. P adsorption by the studied lake sediment during experiments was significantly connected to aluminum content in sediment. The research into the adsorption properties of sediment can be used as a tool for the evaluation of lake restoration effects.


2017 ◽  
Vol 5 (5) ◽  
pp. 1106-1112 ◽  
Author(s):  
Jong Hwa Lee ◽  
Kang Min Kim ◽  
Woongsik Jang ◽  
Sunyong Ahn ◽  
Young Yun Kim ◽  
...  

PTB7:PC71BM-based organic photovoltaic cell with solvent additive fabricated by transferring a BHJ layer via stamping transfer. This photovoltaic cell exhibited enhanced long-term stability and similar cell performance as compared with those of the spin-coated cells.


2013 ◽  
Vol 5 (2) ◽  
pp. 1845-1870 ◽  
Author(s):  
P. Lübcke ◽  
N. Bobrowski ◽  
S. Arellano ◽  
B. Galle ◽  
G. Garzón ◽  
...  

Abstract. The molar ratio of BrO to SO2 is, like other halogen/sulphur ratios, a~possible precursor for dynamic changes in the shallow part of a volcanic system. While the predictive significance of the BrO/SO2 ratio has not been well constrained yet, it has the major advantage that this ratio can be readily measured using the remote-sensing technique Differential Optical Absorption Spectroscopy (DOAS) in the UV. While BrO/SO2 ratios have been measured during several short-term field campaigns this article presents an algorithm that can be used to obtain long-term time series of BrO/SO2 ratios from the scanning DOAS instruments of the Network for Observation of Volcanic and Atmospheric Change (NOVAC) or comparable networks. Parameters of the DOAS retrieval of both trace gases are given and the influence of co-adding spectra on the retrieval error will be investigated. Difficulties in the evaluation of spectroscopic data from monitoring instruments in volcanic environments and possible solutions are discussed. The new algorithm is demonstrated by evaluating data from the NOVAC scanning DOAS systems at Nevado del Ruiz, Colombia encompassing almost four years of measurements between November 2009 and end of June 2013. This dataset shows variations of the BrO/SO2 ratio several weeks prior to the eruption on 30 June 2012.


2009 ◽  
Vol 421-422 ◽  
pp. 471-474 ◽  
Author(s):  
Dedy Eka Priyanto ◽  
Hidenobu Shiroishi ◽  
Satoshi Tanimoto ◽  
Shunsuke Hirukawa ◽  
Morihiro Saito ◽  
...  

Proton conducting ZrO2-yP2O5 (y = 1.0, 1.2, 1.4. 1.6, 1.8) electrolytes based on a shell-core structure were synthesized with diammonium hydrogen phosphate by a solid state reaction, and their conductivities were investigated by ac-impedance spectroscopy. Among the ZrO2-yP2O5 compositions, ZrO2-1.6P2O5 showed the highest proton conductivity of 0.13 Scm-1 at 250°C. The conductivity increased with increasing P2O5 molar ratio and were significantly influenced by heat-treatments in the preparation process. Polytetraflouroethylene (PTFE) was also mixed into these electrolytes in order to improve the mechanical strength and long term durability.


2019 ◽  
Vol 65 (9) ◽  
pp. 1262-1272 ◽  
Author(s):  
Luciano Colpo Gatiboni ◽  
Djalma Eugênio Schmitt ◽  
Paulo Cezar Cassol ◽  
Jucinei José Comin ◽  
Joice Crescêncio Heidemann ◽  
...  

The Holocene ◽  
2019 ◽  
Vol 29 (9) ◽  
pp. 1401-1410 ◽  
Author(s):  
Stepan P Varlamov ◽  
Yuri B Skachkov ◽  
Pavel N Skryabin

The relevance of the problem under review is explained by the need to study the thermal response of permafrost to the modern climate change. Evolution of the thermal state of grounds has been studied with a view to evaluate the effects of modern climate warming on permafrost in Central Yakutia. The leading method to study this problem is the arrangement and performance of long-term monitoring observations of the permafrost thermal state that enable quantitative evaluation of the thermal response of upper permafrost layers to climatic fluctuations of recent decades. The analysis of long-term records from weather stations in the region has clearly revealed one of the highest increasing trends in the mean annual air temperature in northern Russia. Quantitative relationships in the long-term variability of ground thermal parameters, such as ground temperature at the bottom of the active layer, at the bottom of the annual heat exchange layer, and active thaw depth, have been established. The thermal state dynamics of the annual heat exchange layer under climate warming indicates that both warm and cold permafrost are thermally stable. Short-term variability of the snow accumulation regime is the main factor controlling the thermal state of the ground in permafrost landscapes. The active-layer thickness is characterized by low interannual variability and exhibits little response to climate warming, with no statistically meaningful increasing or decreasing trend. The results of ground thermal monitoring can be extended to similar landscapes in the region, providing a reliable basis for predicting heat transfer in natural landscapes.


1992 ◽  
Vol 6 ◽  
pp. 81-81
Author(s):  
David J. Davies ◽  
Molly F. Miller

Compared to their terrigenous counterparts, carbonate shell accumulations have until recently been relatively little studied to determine either descriptive or genetic classifications of shell bed types, the preservation potential of each type, or their relative ability to preserve community-level information. A partial classification of Paleozoic carbonate shell-rich soft sediment accumulations is proposed using sedimentation patterns in the Lebanon limestone of the Stones River Group. Paleoecological information preserved therein is then contrasted by shell bed type. The Lebanon represents typical Ordovician shallow to moderate subtidal carbonate shelf deposits in outcrops flanking the Nashville Dome and peritidal deposits in the Sequatchie Anticline of Eastern Tennessee; shell beds alternate with shell poor sediments (micrites, wackestones and diagenetically enhanced dolomites and clay-rich partings).None of the analyzed shell beds was strictly biological in origin; most are sedimentological although >10% are combined sedimentological/diagenetic. While the majority are single simple shell beds, >20% are amalgamated. All are thin (1 shell to 15 cm) stringers that pinch and swell showing poor lateral continuity (outcrop scale, tens to hundreds of meters) likely enhanced by burial dissolution. These shell beds differ greatly in fabric (packing/sorting), clast composition, taphonomic signature, and intensity of time averaging; thus community information retrieval is biased in predictable patterns. Virtually no shell beds show common shell dissolution or encrustation from long-term sediment surface exposure or hardground formation. Five major categories of accumulation are herein proposed using a DESCRIPTIVE, non-genetic terminology modified from previous works of DJD, as well as a Genetic interpretation for each. These are easily distinguished in the field and are also discriminated by Q-mode cluster analysis.Categories include, in decreasing frequency of occurrence: 1. SHELL GRAVELS; Storm/“event” beds: Sharp bases; poorly sorted coarse basal bioclasts and/or intraclasts, often with no preferred orientation; clasts fine upward to comminuted shell material and micrite. Horizontal platy brachiopods often cap the beds. High diversity and a wide range in shell alteration is represented, from whole unaltered brachiopods to minor abraded fragments, indicating extreme time averaging and poor resolution of short-term community dynamics. 2. COMMINUTED SHELLY LS; Current/ripple concentrations: Small tidal channel fill and discrete ripple trough accumulations are composed of cross-stratified bioclastic deposits with local concentrations of rip-ups. Beds are not graded; typically clasts are abraded, rounded and concordant with cross-beds. Intense time averaging and mixing of discrete communities is inferred due to continual reworking in these background deposits. 3. SHELL/CEMENT LS; Early cementation beds: Intense early diagenetic alteration is inferred due to red discoloration and rapid intergranular cementation; some beds show diagenetic micritic rinds. Beds may be brecciated and show deep burial stylolitization cutting bioclasts and cement. They may represent zones of preferred early cementation rather than a change in shell accumulation rate. Many shells from some beds show little postmortem alteration; these units may preserve much of the original community structure. 4. DENSE SHELL PAVEMENTS; Subtidal surficial pavements: Single layers of shells, commonly concave down, overlie mudstones/wackestones with no basal erosion. No obrution deposits were noted. Bioclasts are typically disarticulated and reoriented, but are not substantially abraded, broken, or dissolved. Diversity is low. Only minor temporal and lateral community mixing with small environmental fluctuation is indicated. 5. VERTICALLY IMBRICATE SHELLY LS; High energy beach zones: Platy whole and major fragments of brachiopods are deposited in low diversity, high angle imbricate beds. Less postmortem reworking and time averaging is evident compared to types 1 and 2.Thus, the most common (physically reworked) shell bed types show the most intense loss of short-term paleocommunity information. There are surprisingly few insitu community pavements or obligate long-term accumulations. This pattern differs from some described Ordovician carbonates, which may contain common community beds or hardgrounds/hiatal accumulations. This implies a relatively low rate of net sediment accumulation on a shallow, periodically wave swept shelf, and no major flooding surfaces or other indications of significant sea level change. Delineation of the sequence stratigraphic position of these carbonates is enhanced from this type of integrated community/biostratinomic analysis.


Water ◽  
2019 ◽  
Vol 11 (3) ◽  
pp. 616 ◽  
Author(s):  
Renata Dondajewska ◽  
Katarzyna Kowalczewska-Madura ◽  
Ryszard Gołdyn ◽  
Anna Kozak ◽  
Beata Messyasz ◽  
...  

Nature-based solutions in lake restoration enable gradual ecosystem reconstruction without drastic and expensive intervention. Sustainable lake restoration involves limited external interference strong enough to initiate and maintain positive changes in the ecosystem. It was introduced in Lake Durowskie, an urban, flow-through lake situated in Western Poland, using hypolimnetic aeration, phosphorus precipitation with small doses of chemicals and biomanipulation in 2009, and is continued until today. Oxygen conditions in the lake hypolimnion after initial deterioration were gradually improved, and finally a shortening of the duration and range of oxygen deficits was observed. Nitrogen transformations were induced in the hypolimnion by water aeration as well, reducing ammonium N (30% during 2013–2017 in comparison to 2008) and increasing nitrates (90% in 2013–2017 in comparison to 2008). Phosphorus content was diminished (19% during 2015–2017 in relation to 2008 for SRP) due to effective iron-binding and a smaller amount of fresh organic matter being decomposed. Its reduction was related to lower phytoplankton biomass, expressed in a decrease of chlorophyll-a concentrations (55% reduction during 2013–2017 in comparison to 2008) and an increase in water transparency (two-fold during 2013–2017 in relation to 2008) throughout the nine years of treatment. A long-term restoration program, based on non-aggressive, multiple in-lake techniques was applied and, despite the lack of a reduction in total external loading, was able to suppress progressive eutrophication.


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