scholarly journals Sorption Properties of the Bottom Sediment of a Lake Restored by Phosphorus Inactivation Method 15 Years after the Termination of Lake Restoration Procedures

Water ◽  
2019 ◽  
Vol 11 (10) ◽  
pp. 2175 ◽  
Author(s):  
Renata Augustyniak ◽  
Jolanta Grochowska ◽  
Michał Łopata ◽  
Katarzyna Parszuto ◽  
Renata Tandyrak ◽  
...  

Artificial mixing and phosphorus inactivation methods using aluminum compounds are among the most popular lake restoration methods. Długie Lake (Olsztyńskie Lakeland, Poland) was restored using these two methods. Primarily, P precipitation and inactivation methods significantly increased the sorption properties of Długie Lake bottom sediment. Fifteen years after the termination of the restoration procedure, the alum-modified “active” sediment layer still has higher P adsorption abilities, which can limit P internal loading. Relatively low amounts of phosphates in the near-bottom water of Długie Lake, even in anoxia, as well as the fact that the assessed maximum sediment P sorption capacity is still higher than NH4Cl–P (labile P) and BD–P (Fe-bound P) sum (“native exchangeable P”), confirm that hypothesis. Among the tested P adsorption models for the sediment, the double Langmuir model showed the best fit to the experimental data (the highest R2 values). This may indicate that phosphorus adsorption by the tested sediments most likely occurs through phosphate binding at two types of active sorption sites. P adsorption by the studied lake sediment during experiments was significantly connected to aluminum content in sediment. The research into the adsorption properties of sediment can be used as a tool for the evaluation of lake restoration effects.

Land ◽  
2021 ◽  
Vol 10 (4) ◽  
pp. 411
Author(s):  
Renata Augustyniak ◽  
Renata Tandyrak ◽  
Michał Łopata ◽  
Jolanta Grochowska

Lake restoration is a part of geoengineering, which is a useful tool for landscape management. The phosphorus inactivation method is one of the most popular lake restoration methods. Using chemical compounds for P binding is leading to the creation of sediment “active layer”, which should show higher P adsorption abilities, compared to non-modified sediment. Howewer, it provides rather little information, how long the modified sediment remains active, and whether it is effective in continuous P binding. Lake meromixis is not commonly observed phenomenon, and sediment located in monimolimnion area is subjected long term anoxia. Therefore, observation of “active layer” in a meromictic lake can give very important data about durability of restoration effects. The object of our study was meromictic Starodworskie Lake (5.57 ha, max. depth 24.5 m), located in Olsztyn Lakeland, Poland. In the past the analyzed lake was subjected to various restoration methods, and phosphorus inactivation method by alum use (1994–1995) was the last used treatment type. The mixing regime of this lake had changed from bradimictic (before and during restoration time) into durable meromictic (post-restoration period). The research made two decades after implementing of P inactivation showed the presence of “active” sediment layer 10–15 cm below sediment surface. This sediment layer showed much higher content of P bound to aluminum, compared to surficial sediment layer. P binding molar ratio was assessed and amounted to 16.1 straightly after restoration and 6.1 after 21 years. This fraction amounts were higher that the values noted before restoration (ca. 358% higher than in 1994 and during restoration (ca. 86% higher than in 1995), which was probably the effect of continuous phosphorus adsorption by “active layer” in post-restoration period.


2002 ◽  
Vol 59 (2) ◽  
pp. 349-355 ◽  
Author(s):  
Alex Teixeira Andrade ◽  
Luiz Arnaldo Fernandes ◽  
Valdemar Faquin

Organic residue application is a low cost alternative to reduce the use of inorganic fertilizers and correctives. In order to study the effect of organic residues, limestone and gypsum application on phosphorus adsorption by lowland soils, four experiments were carried out. A Mesic Organosol (OY), a Melanic Gleysol (MG), a Haplic Gleysol (GX), and a Fluvic Neosol (RU) were used in a completely randomized design and factorial scheme (3 x 2), with five replicates: three soil amendment practices (limestone, gypsum and no corrective) and two levels of organic residue (with and without corral manure). Soil samples were incubated for 60 days, with and without organic residue incorporation. After this period, we applied the corrective and incubated the soil for 30 days, then P and basic fertilization (macro and micronutrients) were applied and the soil was incubated for additional 60 days. Equilibrium phosphorus, maximum phosphate adsorption capacity, pH, exchangeable Al and phosphorus-buffering index were measured. Organic residue and limestone application increased soil pH and reduced exchangeable Al, decreasing P adsorption. Gypsum application did not increase the pH but reduced exchangeable Al and P adsorption.


2020 ◽  
Vol 10 (11) ◽  
pp. 3698
Author(s):  
Jolanta Grochowska ◽  
Renata Augustyniak ◽  
Michał Łopata ◽  
Renata Tandyrak

The research was carried out on Karczemne Lake, a water reservoir located in Kartuzy (northern Poland, Pomeranian Lake District). Monitoring of the water and bottom sediment of Karczemne Lake showed a very high level of contamination of the reservoir by a long-term inflow of untreated municipal sewage. The trophic status index of total phosphorus (TP) was unusually high at 101, and the TP content in the bottom sediments—31 mg g−1 (dry weight)—was the highest value recorded worldwide in a lake. Based on the monitoring results, to achieve constant improvement of the water quality, we recommend a completely new, safe and economically justified method of bottom sediment removal and management. A very important aspect of this method is the prevention of uncontrolled sewage discharge back into the lake basin. Removed sediment with interstitial water will be pumped through a pipeline and transported to a sewage treatment plant. In the sediment mining field in which the sludge will be removed, the first phase of phosphorus inactivation will be carried out to chemically precipitate pollutants distributed in the water column as a result of sediment resuspension. After the deepening of the entire lake basin, the method of phosphorus inactivation will be carried out on the entire surface of the lake as the next stage of restoration. A supporting activity will be biomanipulation. Before the restoration is started, the municipal sewerage system will be modernized.


Environments ◽  
2020 ◽  
Vol 7 (3) ◽  
pp. 23
Author(s):  
Guido Perin ◽  
Francesco Romagnoli ◽  
Fabrizio Perin ◽  
Andrea Giacometti

The Tangential Guanabara Bay Aeration and Recovery (TAGUBAR) project derives its origins from a Brazilian government decision to tackle the planning and management challenges related to the restoration of some degraded aquatic ecosystems such as Guanabara Bay (state of Rio de Janeiro), Vitória Bay, and Espírito Santo Bay (state of Espírito Santo). This was performed by using the successful outcomes of a previous Ministry of Foreign Affairs and Directorate General for Cooperation and Development (i.e., Direttore Generale alla Cooperazione allo Sviluppo, MFA–DGCS) cooperation program. The general objective of the program was to contribute to the economic and social development of the population living around Guanabara, Vitória, and Espírito Santo Bays, while promoting the conservation of their natural resources. This objective was supposed to be achieved by investing money to consolidate the local authorities’ ability to plan and implement a reconditioning program within a systemic management framework in severely polluted ecosystems such as Guanabara Bay, where sediments are highly contaminated. Sediments normally represent the final fate for most contaminants. Therefore, it would be highly undesirable to perturb them, if one wishes to avoid contaminant recycling. In this context, we explored a bench-scale novel technology, called the module for the decontamination of units of sediment (MODUS), which produces an oxygenated water flow directed parallel to the sediment floor that is aimed to create “tangential aeration” of the bottom water column. The purpose of this is to avoid perturbing the top sediment layer, as a flow directed toward the bottom sediment would most probably resuspend this layer. Three kinds of tests were performed to characterize a bench-scale version of MODUS (referred to as “mini-MODUS”) behavior: turbulence–sediment resuspension tests, hydrodynamic tests, and oxygenation–aeration tests. In order to understand the functioning of the mini-MODUS, we needed to eliminate as many variables as possible. Therefore, we chose a static version of the module (i.e., no speed for the mini-MODUS as well as no water current with respect to the bottom sediment and no flume setting), leaving dynamic studies for a future paper. The turbulence tests showed that the water enters and exits the mini-MODUS mouths without resuspending the sediment surface at all, even if the sediment is very soft. Water flow was only localized very close to both mouth openings. Hydrodynamic tests showed an interesting behavior. An increase of low air flows produced a sharp linear increase of the water flow. However, a plateau was quickly reached and then no further increase of water flow was observed, implying that for a certain specific geometry of the equipment and for the given experimental conditions, an increase in the air flow does not produce any reduction of the residence time within the aeration reactor. Oxygenation–aeration tests explored three parameters that were deemed to be most important for our study: the oxygen global transfer coefficient, KLa; the oxygenation capacity, OC; and the oxygenation efficiency, OE%. An air flow increase causes an increase of both KLa and OC, while OE% decreases (no plateau was observed for KLa and OC). The better air flow would be a compromise between high KLa and OC, with no disadvantageous OE%, a compromise that will be the topic of the next paper.


2020 ◽  
Vol 15 (No. 4) ◽  
pp. 220-227
Author(s):  
Jinquan Zhang ◽  
Weiguo Fu

In the initial stage of the rainfall, the nutrient element phosphorus (P) in the farmland, one of the most important factors causing agricultural non-point source pollution, flows into agriculture drainage ditches rapidly, and an instantaneous phosphorus peak value in the ditch water often occurs. Aerated concrete with high P adsorption properties was chosen as the experiment material in the laboratory to reduce the instantaneous P peak value in the drainage water in the initial stage of the rainfall. The three total P (TP) concentrations of the simulated drainage water (1.0, 2.0, and 3.0 mg/L) stood for three treatments were designed in the adsorption experiment; the same three TP concentrations of the simulated drainage water and the three TP concentrations of the simulated natural water (0.2, 0.3, and 0.4 mg/L) stood for nine treatments in the desorption experiment. The sponge effect of the aerated concrete on the P adsorption-desorption was explored by studying the dynamics of the P adsorption-desorption of the aerated concrete with an increase in the experiment’s time. The results showed the following details: (1) Both the adsorption rate and desorption rate of the aerated concrete decrease with an increase in the experiment’s time. The initial adsorption is dominant during the entire adsorption, as with the initial desorption during the entire desorption. (2) The adsorption capacity of the aerated concrete slightly decreases with the increase in the re-adsorption, whereas the desorption capacity of the aerated concrete significantly decreases with the increase in the re-desorption. Thus, the aerated concrete can be introduced into the agricultural drainage ditch to reduce the instantaneous P peak value in the drainage water in the initial stage of the rainfall, and potential further studies should explore the relationship between the different drainage water loads and the amount of the aerated concrete.


2012 ◽  
Vol 16 (1) ◽  
pp. 61-66 ◽  
Author(s):  
Barbara Sapek

Abstract Sorption capacity and the energy of phosphorus adsorption on muck and peat deposits were studied in peat- -muck soil profile from a lowland peatland in the Kuwasy object. Soils of the area are characterised by a laminar structure which results in variable sorption properties of peat deposits of different origin, degree of humification (decomposition - R) and transformation of organic matter of upper muck layers (degree of mucking - Z). There was a relationship between the maximum phosphorus adsorption calculated from the Langmuir isotherm (b) and adsorption energy (k) and the type and degree of humification of peat and transformation of muck mass. Muck deposits of the maximum sorption capacity similar to that of peat deposits bind phosphorus less intensively than peats. One may expect that different sorption capacity and the strength of phosphorus binding will effect in different migration of inorganic and organic P compounds in soil profile and their transfer to ground waters.


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