scholarly journals Recent Progress on Organic Electrodes Materials for Rechargeable Batteries and Supercapacitors

Materials ◽  
2019 ◽  
Vol 12 (11) ◽  
pp. 1770 ◽  
Author(s):  
Alain Mauger ◽  
Christian Julien ◽  
Andrea Paolella ◽  
Michel Armand ◽  
Karim Zaghib

Rechargeable batteries are essential elements for many applications, ranging from portable use up to electric vehicles. Among them, lithium-ion batteries have taken an increasing importance in the day life. However, they suffer of several limitations: safety concerns and risks of thermal runaway, cost, and high carbon footprint, starting with the extraction of the transition metals in ores with low metal content. These limitations were the motivation for an intensive research to replace the inorganic electrodes by organic electrodes. Subsequently, the disadvantages that are mentioned above are overcome, but are replaced by new ones, including the solubility of the organic molecules in the electrolytes and lower operational voltage. However, recent progress has been made. The lower voltage, even though it is partly compensated by a larger capacity density, may preclude the use of organic electrodes for electric vehicles, but the very long cycling lives and the fast kinetics reached recently suggest their use in grid storage and regulation, and possibly in hybrid electric vehicles (HEVs). The purpose of this work is to review the different results and strategies that are currently being used to obtain organic electrodes that make them competitive with lithium-ion batteries for such applications.

Metals ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 1091
Author(s):  
Eva Gerold ◽  
Stefan Luidold ◽  
Helmut Antrekowitsch

The consumption of lithium has increased dramatically in recent years. This can be primarily attributed to its use in lithium-ion batteries for the operation of hybrid and electric vehicles. Due to its specific properties, lithium will also continue to be an indispensable key component for rechargeable batteries in the next decades. An average lithium-ion battery contains 5–7% of lithium. These values indicate that used rechargeable batteries are a high-quality raw material for lithium recovery. Currently, the feasibility and reasonability of the hydrometallurgical recycling of lithium from spent lithium-ion batteries is still a field of research. This work is intended to compare the classic method of the precipitation of lithium from synthetic and real pregnant leaching liquors gained from spent lithium-ion batteries with sodium carbonate (state of the art) with alternative precipitation agents such as sodium phosphate and potassium phosphate. Furthermore, the correlation of the obtained product to the used type of phosphate is comprised. In addition, the influence of the process temperature (room temperature to boiling point), as well as the stoichiometric factor of the precipitant, is investigated in order to finally enable a statement about an efficient process, its parameter and the main dependencies.


Author(s):  
Krishnashis Chatterjee ◽  
Pradip Majumdar ◽  
David Schroeder ◽  
S. Rao Kilaparti

Development of electric and hybrid electric vehicles is of great interest to the transportation industry due to increased demand and cost of imported fuel, uncertainty in the steady supply of oil, and increased standards for reduced emissions. Lithium-ion batteries are considered as one of the leading types for the battery systems to be employed in electric vehicles (EVs) or hybrid electric vehicles (HEVs). Using a regenerative braking system and storing it in battery stacks and using it later for propulsion and acceleration can improve the overall efficiency and reduction of fuel consumption. The objective of this study is to evaluate experimentally the battery performance considering different discharge and charge rates, and investigate the thermal behavior and thermal management requirements of the batteries under a variety of environmental conditions. An experimental test facility has been developed to evaluate thermal performance during charging and discharging modes. Environmental temperatures were varied in environmental chamber to analyze their effects on the charging and discharging patterns of the battery by using the CADEX battery analyzer in order to find the temperature range for optimum battery performance. The batteries were monitored with thermal sensors and a thermal imaging camera while they were run through different load scenarios. In the present study, lithium-ion batteries have been tested and battery performance in terms of polarization curves and discharge capacity were measured using a computerized battery analyzer system for different discharge and charge rates, and over a range of ambient temperatures. Results indicate that at higher discharge and charge rates battery performance decreases due to increased polarization losses, which results in increased internal heat generation and temperature of the battery. Battery performance also depends strongly on the ambient temperature conditions.


2018 ◽  
Vol 2 (8) ◽  
pp. 1726-1736 ◽  
Author(s):  
Jialong Liu ◽  
Qiangling Duan ◽  
Haodong Chen ◽  
Jinhua Sun ◽  
Qingsong Wang

Herein, an optimal multistage charge strategy for commercial lithium ion batteries is proposed to enhance the performance of electric vehicles and hybrid electric vehicles.


Energies ◽  
2020 ◽  
Vol 13 (10) ◽  
pp. 2543 ◽  
Author(s):  
Zeyu Chen ◽  
Jiahuan Lu ◽  
Bo Liu ◽  
Nan Zhou ◽  
Shijie Li

The performance of lithium-ion batteries will inevitably degrade during the high frequently charging/discharging load applied in electric vehicles. For hybrid electric vehicles, battery aging not only declines the performance and reliability of the battery itself, but it also affects the whole energy efficiency of the vehicle since the engine has to participate more. Therefore, the energy management strategy is required to be adjusted during the entire lifespan of lithium-ion batteries to maintain the optimality of energy economy. In this study, tests of the battery performances under thirteen different aging stages are involved and a parameters-varying battery model that represents the battery degradation is established. The influences of battery aging on energy consumption of a given plug-in hybrid electric vehicle (PHEV) are analyzed quantitatively. The results indicate that the variations of capacity and internal resistance are the main factors while the polarization and open circuit voltage (OCV) have a minor effect on the energy consumption. Based on the above efforts, the optimal energy management strategy is proposed for optimizing the energy efficiency concerning both the fresh and aging batteries in PHEV. The presented strategy is evaluated by a simulation study with different driving cycles, illustrating that it can balance out some of the harmful effects that battery aging can have on energy efficiency. The energy consumption is reduced by up to 2.24% compared with that under the optimal strategy without considering the battery aging.


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