scholarly journals Mechanical Properties, Microstructure, and Chloride Content of Alkali-Activated Fly Ash Paste Made with Sea Water

Materials ◽  
2020 ◽  
Vol 13 (6) ◽  
pp. 1467
Author(s):  
Salman Siddique ◽  
Jeong Gook Jang

The aim of the present study is to investigate the potential of sea water as a feasible alternative to produce alkali-activated fly ash material. The alkali-activated fly ash binder was fabricated by employing conventional pure water, tap water, and sea water based alkali activating solution. The characteristics of alkali-activated materials were examined by employing compressive strength, mercury intrusion porosimetry, XRD, FT-IR, and 29Si NMR along with ion chromatography for chloride immobilization. The results provided new insights demonstrating that sea water can be effectively used to produce alkali activated fly ash material. The presence of chloride in sea water contributed to increase compressive strength, refine microstructure, and mineralogical characteristics. Furthermore, a higher degree of polymerization on the sea water-based sample was observed by FT-IR and 29Si NMR analysis. However, the higher amount of free chloride ion even after immobilization in sea water-based alkali-activated material, should be considered before application in reinforced structural elements.

2011 ◽  
Vol 287-290 ◽  
pp. 1237-1240
Author(s):  
Lan Fang Zhang ◽  
Rui Yan Wang

The aim of this paper is to study the influence of lithium-slag and fly ash on the workability , setting time and compressive strength of alkali-activated slag concrete. The results indicate that lithium-slag and fly-ash can ameliorate the workability, setting time and improve the compressive strength of alkali-activated slag concrete,and when 40% or 60% slag was replaced by lithium-slag or fly-ash, above 10 percent increase in 28-day compressive strength of concrete were obtained.


Author(s):  
Sajid Khan Afridi ◽  
Vanissorn Vimonsatit

Alkali activated pozzolan are known low carbon cementitious binders which can be used to replace cement. The material is also known as geopolymer because of its three dimensional polymeric chain and ring like structure consisting silica and alumina. A common type of pozzolan used is fly ash because of its rich silica content; therefore the term alkali activated fly-ash based binders is adopted. Despite much research and development of this material, there is no specific standard for design mix proportion. This research used the Taguchi’s design of experiment method to determine the optimum mix proportion of alkali activated fly ash based cement paste and mortar. Four factors were considered in the tests, silica fume, sand to cementitious ratio, liquid to solid ratio, and percentage of superplasticiser. Tests were conducted on the 9 batches of alkali activated fly-ash based paste and mortar samples to determine the compressive strength under ambient condition. Tests were also conducted to determine the residual strength of the samples after exposed to elevated temperatures. ANOVA analysis of the test results revealed the main factors contribution on the tested properties and led to the determination of the optimum design proportion of the factors considered in these tests.


Author(s):  
Hyuk Lee ◽  
Vanissorn Vimonsatit

This paper presents the mechanical properties of fly ash-based alkali-activated cement (AAC). A statistical analysis method was used to determine the effect of mix proportion parameters on the dry density and compressive strength of fly ash-based AAC pastes and mortars. For that purpose, sample mixtures were designed according to Taguchi’s experimental design method, i.e., in a L9 orthogonal array. Four factors were selected: “silica fume content” (SF), “sand to solid ratio” (s/c), “liquid to solid ratio” (l/s), and “superplasticiser content” (SP). The experimental results were analysed by using signal to noise for quality control of each mixture, and analysis of variance (ANOVA) was used to determine the significant effect on the compressive strength of fly ash-based AAC. Furthermore, a regression-analysis method was used to predict the compressive strength according to the variation of the four factors. Results indicated that silica fume is the most influencing parameter on compressive strength, which could be decreased by superplasticiser and l/s ratio. There is no significant effect of sand-to-cementitious ratio on compressive strength of fly ash-based AAC. The dry density decreases as the sand-to-cementitious ratio is decreased. The increasing l/s ratio and superplasticiser dosage could further decrease the dry density of fly ash-based AAC.


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