scholarly journals A Highly Sensitive Electrochemical Glucose Sensor Based on Room Temperature Exfoliated Graphite-Derived Film Decorated with Dendritic Copper

Materials ◽  
2021 ◽  
Vol 14 (17) ◽  
pp. 5067
Author(s):  
Jiaxin Tang ◽  
Luo Wei ◽  
Shuaijie He ◽  
Jihui Li ◽  
Ding Nan ◽  
...  

An ultrasensitive enzyme-free glucose sensor was facilely prepared by electrodepositing three-dimensional dendritic Cu on a room temperature exfoliated graphite-derived film (RTEG-F). An excellent electrocatalytic performance was demonstrated for glucose by using Cu/RTEG-F as an electrode. In terms of the high conductivity of RTEG-F and the good catalytic activity of the dendritic Cu structures, the sensor demonstrates high sensitivities of 23.237 mA/mM/cm2, R2 = 0.990, and 10.098 mA/mM/cm2, R2 = 0.999, corresponding to the concentration of glucose ranging from 0.025 mM to 1.0 mM and 1.0 mM to 2.7 mM, respectively, and the detection limit is 0.68 μM. In addition, the Cu/RTEG-F electrode demonstrates excellent anti-interference to interfering species and a high stability. Our work provides a new idea for the preparation of high-performance electrochemical enzyme-free glucose sensor.

2016 ◽  
Vol 120 (45) ◽  
pp. 25752-25759 ◽  
Author(s):  
Arumugam Manikandan ◽  
Vediyappan Veeramani ◽  
Shen-Ming Chen ◽  
Rajesh Madhu ◽  
Ling Lee ◽  
...  

Nanoscale ◽  
2021 ◽  
Author(s):  
Soon-Hwan Kwon ◽  
Tae-Hyeon Kim ◽  
Sang-Min Kim ◽  
Semi Oh ◽  
Kyoung-Kook Kim

Nanostructured semiconducting metal oxides such as SnO2, ZnO, TiO2, and CuO have been widely used to fabricate high performance gas sensors. To improve the sensitivity and stability of gas sensors,...


2019 ◽  
Vol 7 (16) ◽  
pp. 9690-9697 ◽  
Author(s):  
Jie-Song Sun ◽  
Yi-Tong Zhou ◽  
Rui-Qi Yao ◽  
Hang Shi ◽  
Zi Wen ◽  
...  

Chromium-doped NiFe oxyhydroxide nanosheets that are quasi-vertically oriented on three-dimensional nanoporous gold exhibit superior catalytic activity towards the oxygen evolution reaction.


2015 ◽  
Vol 3 (4) ◽  
pp. 556-561 ◽  
Author(s):  
Ni Hui ◽  
Wenting Wang ◽  
Guiyun Xu ◽  
Xiliang Luo

A highly sensitive and stable nonenzymatic glucose sensor was developed through the electrochemical deposition of Cu nanoparticles onto an electrodeposited nanocomposite of conducting polymer PEDOT doped with graphene oxide.


2014 ◽  
Vol 18 (07) ◽  
pp. 604-613 ◽  
Author(s):  
Anna S. Makarova ◽  
Evgeny V. Kudrik ◽  
Sergei V. Makarov ◽  
Oskar I. Koifman

A study of catalytic activity of μ-nitrido- and μ-oxo-dimeric iron tetrasulfophthalocyanines in the oxidation of Orange II by tert-butylhydroperoxide in aqueous solutions has been performed. It is shown that though in one catalytic cycle activity of μ-oxo-dimer is higher, stability of this complex in oxidative conditions is poor. μ-nitrido-dimer combines relatively good catalytic activity with very high stability in the presence of tert-butylhydroperoxide. The mechanisms of oxidative decomposition of dimers and catalytic oxidation of Orange II have been proposed on the base of kinetic results. The products of catalytic processes are shown to be bio-degradable non-toxic small organic compounds.


2020 ◽  
pp. 174751982093947
Author(s):  
Bencai Dai ◽  
Yang Zhou ◽  
Changchun Liu ◽  
Jin Chen ◽  
Zhihao Shen ◽  
...  

Palladium nanoparticles with unique catalytic activity and high stability are synthesized. These nanoparticles exhibit excellent catalytic reduction activity for nitroaromatics in green solvents in the presence of H2 at ambient pressure and temperature. The prominent advantages of this nanotechnology include low consumption of catalyst, excellent chemoselectivity, high reusability of the catalyst, and environmentally green solvents.


2021 ◽  
Vol 21 (10) ◽  
pp. 5319-5328
Author(s):  
Sha-Sha Luo ◽  
Yu-Meng Ma ◽  
Peng-Wei Li ◽  
Ming-Hua Tian ◽  
Qiao-Xia Li

Transition metal and nitrogen co-doped carbon-based catalysts (TM-N-C) have become the most promising catalysts for Pt/C due to their wide range of sources, low cost, high catalytic activity, excellent stability and strong resistance to poisoning, especially Fe–N–C metal-organic frameworks (MOFs), which are some of the most promising precursors for the preparation of Fe–N–C catalysts due to their inherent properties, such as their highly ordered three-dimensional framework structure, controlled porosity, and tuneable chemistry. Based on these, in this paper, different iron sources were added to synthesis a sort of zeolitic imidazole frameworks (ZIF-8). Then the imidazole salt in ZIF-8 was rearranged into high N-doped carbon by high-temperature pyrolysis to prepare the Fe–N–C catalyst. We studied the physical characteristics of the catalysts by different iron sources and their effects on the catalytic properties of the oxygen reduction reaction (ORR). From the point of morphology, various iron sources have a positive influence on maintaining the morphology of ZIF-8 polyhedron. Fe–N/C–Fe(NO3)3 has the same anion as zinc nitrate, and can maintain a polyhedral morphology after high-temperature calcination. It had the highest ORR catalytic activity compared to the other four catalyst materials, which proved that there is a certain relationship between morphology and performance. This paper will provide a useful reference and new models for the development of high-performance ORR catalysts without precious metals.


2016 ◽  
Vol 4 (1) ◽  
pp. 59-66 ◽  
Author(s):  
Chen Deng ◽  
Fei Ding ◽  
Xinyuan Li ◽  
Yaofang Guo ◽  
Wei Ni ◽  
...  

A sponge-shaped three-dimensional MoP (3D MoP) electrocatalyst is prepared and used as a binder-free electrode for the HER, exhibiting promising catalytic activity.


CrystEngComm ◽  
2010 ◽  
Vol 12 (4) ◽  
pp. 1120-1126 ◽  
Author(s):  
Xiaojun Zhang ◽  
Aixia Gu ◽  
Guangfeng Wang ◽  
Yan Wei ◽  
Wen Wang ◽  
...  

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