scholarly journals Electrochemical Behaviour of Ti and Ti-6Al-4V Alloy in Phosphate Buffered Saline Solution

Materials ◽  
2021 ◽  
Vol 14 (24) ◽  
pp. 7495
Author(s):  
Senka Gudić ◽  
Ladislav Vrsalović ◽  
Dario Kvrgić ◽  
Aleš Nagode
Keyword(s):  
Oxide Film ◽  
Barrier Layer ◽  
Saline Solution ◽  
Electrochemical Impedance ◽  
Electrochemical Behaviour ◽  
Pure Titanium ◽  
Commercially Pure Titanium ◽  
Corrosion Stability ◽  
Cp Ti ◽  
Phosphate Buffered Saline

The electrochemical behavior of commercially pure titanium (CP Ti) and Ti-6Al-4V (Grade 5) alloy in phosphate buffered saline solution (PBS, pH = 7.4) at 37 °C (i.e., in simulated physiological solution in the human body) was examined using open circuit potential measurements, linear and potentiodynamic polarization and electrochemical impedance spectroscopy methods. After the impedance measurements and after potentiodynamic polarizationmeasurements, the surface of the samples was investigated by scanning electron microscopy, while the elemental composition of oxide film on the surface of each sample was determined by EDS analysis. The electrochemical and corrosion behavior of CP Ti and Ti-6Al-4V alloys is due to forming a two-layer model of surface oxide film, consisting of a thin barrier-type inner layer and a porous outer layer. The inner barrier layer mainly prevents corrosion of CP Ti and Ti-6Al-4V alloy, whose thickness and resistance increase sharply in the first few days of exposure to PBS solution. With longer exposure times to the PBS solution, the structure of the barrier layer subsequently settles, and its resistance increases further. Compared to Ti-6Al-4V alloy, CP Ti shows greater corrosion stability.

scholarly journals Comparison of Biocompatible Coatings Produced by Plasma Electrolytic Oxidation on cp-Ti and Ti-Zr-Nb Superelastic Alloy

Coatings ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 401
Author(s):  
Ruzil Farrakhov ◽  
Olga Melnichuk ◽  
Evgeny Parfenov ◽  
Veta Mukaeva ◽  
Arseniy Raab ◽  
...  
Keyword(s):  
Plasma Electrolytic Oxidation ◽  
Electrochemical Impedance ◽  
Pure Titanium ◽  
Commercially Pure Titanium ◽  
X Ray ◽  
Kinetic Coefficients ◽  
Electrolytic Oxidation ◽  
Plasma Electrolytic ◽  
Cp Ti ◽  
Peo Coatings

The paper compares the coatings produced by plasma electrolytic oxidation (PEO) on commercially pure titanium and a novel superelastic alloy Ti-18Zr-15Nb (at. %) for implant applications. The PEO coatings were produced on both alloys in the identical pulsed bipolar regime. The properties of the coatings were examined using scanning electron microscopy (SEM), X-ray diffraction (XRD), and energy-dispersive X-ray spectroscopy (EDX), potentiodynamic polarization (PDP), and electrochemical impedance spectroscopy (EIS). The PEO process kinetics was modeled based on the Avrami theorem and Cottrell equation using a relaxation method. The resultant coatings contain TiO2, for both alloys, and NbO2, Nb2O5, ZrO2 for Ti-18Zr-15Nb alloy. The coating on the Ti-18Zr-15Nb alloy has a higher thickness, porosity, and roughness compared to that on cp-Ti. The values of the kinetic coefficients of the PEO process—higher diffusion coefficient and lower time constant for the processing of Ti-18Zr-15Nb—explain this effect. According to the electrochemical studies, PEO coatings on Ti-18Zr-15Nb alloy provide better corrosion protection. Higher corrosion resistance, porosity, and roughness contribute to better biocompatibility of the PEO coating on Ti-18Zr-15Nb alloy compared to cp-Ti.

scholarly journals Corrosion Resistance of Ti-29Nb-13Ta-4.6Zr Alloy in a Fluoride-Containing Solution

2012 ◽  
Vol 529-530 ◽  
pp. 584-587
Author(s):  
Shinji Takemoto ◽  
Masaaki Nakai ◽  
Masayuki Hattori ◽  
Masao Yoshinari ◽  
Eiji Kawada ◽  
...  
Keyword(s):  
Oxide Film ◽  
Saline Solution ◽  
Pure Titanium ◽  
Marked Change ◽  
Commercially Pure Titanium ◽  
Subsequent Increase ◽  
Commercially Pure ◽  
Outermost Surface ◽  
Before And After ◽  
Constituent Elements

The objective of this study was to evaluate the corrosion behavior of Ti-29Nb-13Ta-4.6Zr alloy (TNTZ) with immersion in an acidic saline solution containing fluoride by investigating change in color and the surface structure of the oxide film. With immersion in fluoride-containing solution, TNTZ showed a less marked change in color than commercially pure titanium (TI), and a smaller decrease in glossiness. The outermost surface was covered with oxides from its constituent elements at before and after immersion in solution with or without fluoride. When immersed in fluoride-containing solution, the film consisted of larger niobium and tantalum oxides than that before or after immersion in solution without fluoride. In summary, TNTZ showed superior resistance to discoloration to TI after immersion in fluoride-containing solution. The results suggest that the subsequent increase in niobium and tantalum fractions in the oxide film in TNTZ improves resistance to corrosion.

Thermomechanical Response of Commercially Pure Titanium under Large Plastic Deformation at High Strain Rates

2012 ◽  
Vol 548 ◽  
pp. 174-178 ◽  
Author(s):  
Chong Yang Gao ◽  
Wei Ran Lu
Keyword(s):  
Pure Titanium ◽  
Optimal Solution ◽  
Optimization Method ◽  
Strain Rates ◽  
Commercially Pure Titanium ◽  
Thermomechanical Response ◽  
Commercially Pure ◽  
Different Temperatures ◽  
Cp Ti ◽  
Constitutive Parameters

By using a dislocation-based plastic constitutive model for hcp metals developed by us recently, the dynamic thermomechanical response of an important industrial material, commercially pure titanium (CP-Ti), was described at different temperatures and strain rates. The constitutive parameters of the material are determined by an efficient optimization method for a globally optimal solution. The model can well predict the dynamic response of CP-Ti by the comparison with experimental data and the Nemat-Nasser-Guo model.

Oxidation Effects during High Temperature Deformation of CP Ti Alloy

2007 ◽  
Vol 539-543 ◽  
pp. 3678-3683
Author(s):  
Ming Jen Tan ◽  
X.J. Zhu ◽  
S. Thiruvarudchelvan ◽  
K.M. Liew
Keyword(s):  
High Temperature ◽  
Oxide Film ◽  
High Temperatures ◽  
Pure Titanium ◽  
Initial Strain Rate ◽  
High Temperature Deformation ◽  
Temperature Deformation ◽  
Uniaxial Tensile ◽  
Commercially Pure Titanium ◽  
Commercially Pure

This work reports the influence of oxidation on the superplasticity of commercially pure titanium at high temperatures. Uniaxial tensile tests were conducted at temperatures in the range 600-800°C with an initial strain rate of 10s-1 to 10s-3. This study shows that oxidization at the surface of the alloy causes oxide film on the surface of commercially pure titanium alloy, and the thickness of oxide film increase with increasing exposure time and temperature. XRD analysis shows that the oxide film consists of TiO2. Because this oxide film is very brittle, it can induce clefts and degrade the ductility of the titanium at high temperatures. The mechanism of the initial clefts was investigated and a model for the cleft initiation and propagation during high temperature tensile test was proposed.

The Influence of Laser Irradiation Parameters on Tribological Behaviour of Commercially Pure Titanium for Dental Prostheses

2016 ◽  
Author(s):  
Karibeeran Shanmuga Sundaram ◽  
Gurusami Kiliyappan ◽  
Senthil Kumaran Selvadurai
Keyword(s):  
Surface Roughness ◽  
Wear Resistance ◽  
Pure Titanium ◽  
Laser Surface ◽  
Commercially Pure Titanium ◽  
Laser Shock ◽  
Micro Hardness ◽  
Dental Prostheses ◽  
Commercially Pure ◽  
Cp Ti

Laser shock peening (LSP) is one of the innovative technique that produces a compressive residual stress on the surface of metallic materials, thereby significantly increasing its fatigue life in applications where failure is caused by surface-initiated cracks. The specimens were treated with laser shock waves with different processing parameters, and characterization studies were made on treated specimens. The purpose of the present study was to investigate the influence of Nd:YAG laser on commercially pure titanium (CP-Ti) used in prosthetic dental restorations. The treatment influenced change in microstructure, micro hardness, surface roughness, and wear resistance characteristics. Though CP-Ti is considered as an excellent material for dental applications due to its outstanding biocompatibility, it is not suitable when high mastication forces are applied. In the present study, pulsed Nd:YAG laser surface treatment technique was adopted to improve the wear resistance of CP-Ti. The wear test pin specimens of CP-Ti were investment cast with centrifugal titanium casting machine. The wear properties of specimens were evaluated after LSP on a “pin-on-disc” wear testing tribometer, as per ASTM G99-05 standards. The results of the wear experiment showed that the treated laser surface has higher wear resistance, micro hardness, and surface roughness compared to as-cast samples. The improvement of wear resistance may be attributed due to grain refinement imparted by LSP processes. The microstructure, wear surfaces, wear debris, and morphology of the specimen were analyzed by using optical electron microscope, scanning electron microscope, and X-ray diffraction (XRD). The data were compared using ANOVA and post-hoc Tukey tests. The characteristic change resulted in increase in wear resistance and decrease in wear rate. Hence, it is evident that the more reliable and removable partial denture metal frameworks for dental prostheses may find its applications.

scholarly journals The influence of mold temperature on the fit of cast crowns with commercially pure titanium

2005 ◽  
Vol 19 (2) ◽  
pp. 139-143 ◽  
Author(s):  
Wagner Sotero Fragoso ◽  
Guilherme Elias Pessanha Henriques ◽  
Edwin Fernando Ruiz Contreras ◽  
Marcelo Ferraz Mesquita
Keyword(s):  
Pure Titanium ◽  
Mold Temperature ◽  
Commercially Pure Titanium ◽  
Mechanical Grinding ◽  
Marginal Fit ◽  
Commercially Pure ◽  
Cp Ti

Commercially pure titanium (CP Ti) has been widely applied to fabricate cast devices because of its favorable properties. However, the mold temperature recommended for the manufacture of casts has been considered relatively low, causing inadequate castability and poor marginal fit of cast crowns. This study evaluated and compared the influence of mold temperature (430°C - as control, 550°C, 670°C) on the marginal discrepancies of cast CP Ti crowns. Eight bovine teeth were prepared on a mechanical grinding device and impressions were used to duplicate each tooth and produce eight master dies. Twenty-four crowns were fabricated using CP Ti in three different groups of mold temperature (n = 8): 430°C (as control), 550°C and 670°C. The gap between the crown and the bovine tooth was measured at 50 X magnification with a traveling microscope. The marginal fit values of the cast CP Ti crowns were submitted to the Kruskal-Wallis test (p = 0.03). The 550°C group (95.0 µm) showed significantly better marginal fit than the crowns of the 430°C group (203.4 µm) and 670°C group (213.8 µm). Better marginal fit for cast CP Ti crowns was observed with the mold temperature of 550°C, differing from the 430°C recommended by the manufacturer.

scholarly journals Corrosion study of metallic biomaterials in simulated body fluid

10.30544/384 ◽  
2011 ◽  
Vol 17 (1) ◽  
pp. 13-22 ◽  
Author(s):  
Hamid Reza Asgari Bidhendi ◽  
Majid Pouranvari
Keyword(s):  
Stainless Steel ◽  
Simulated Body Fluid ◽  
Corrosion Behavior ◽  
Body Fluid ◽  
Pure Titanium ◽  
Localized Corrosion ◽  
Commercially Pure Titanium ◽  
Corrosion Properties ◽  
Cyclic Polarization ◽  
Cp Ti

Titanium alloys and stainless steel 316L are still the most widely used biomaterials for implants despite emerging new materials for this application. There is still someambiguity in corrosion behavior of metals in simulated body fluid (SBF). This paper aims at investigating the corrosion behavior of commercially pure titanium (CP-Ti), Ti–6Al–4V and 316LVM stainless steel (316LVM) in SBF (Hank’s solution) at37 ºC using the cyclic polarization test. Corrosion behavior was described in terms of breakdown potential, the potential and rate ofcorrosion, localized corrosion resistance, andbreakdown repassivation. The effects of anodizing on CP-Ti samples and the passivation on the 316LVM were studied in detail. It was shown that CP-Ti exhibited superior corrosion properties compared to Ti–6Al–4V and 316LVM.

Pack Cementation Treatment of Titanium Using Tetracalcium Phosphate Powder for Biomedical Applications

2010 ◽  
Vol 654-656 ◽  
pp. 2172-2175
Author(s):  
Kyosuke Ueda ◽  
Hajime Suto ◽  
Kaori Nakaie ◽  
Takayuki Narushima
Keyword(s):  
Reaction Layer ◽  
Biomedical Applications ◽  
Pure Titanium ◽  
Pack Cementation ◽  
Apatite Formation ◽  
Commercially Pure Titanium ◽  
Tetracalcium Phosphate ◽  
Phosphate Powder ◽  
Commercially Pure ◽  
Cp Ti

The surface modification of commercially pure titanium (CP Ti) by pack cementation treatment at 973 K using tetracalcium phosphate (Ca4(PO4)2O, TTCP) slurry was investigated. An HAp phase and a CaTiO3 phase were observed on the reaction layer of the CP Ti substrate after pack cementation treatment at 973 K for 86.4 ks. TTCP powder decomposed to HAp and CaO, and CaO reacted with TiO2 to form CaTiO3. The reaction layer on the CP Ti substrate consisted of inner and outer layers and the particles were in the outer reaction layer. The pores observed on the reaction layer were formed by the detachment of particles from the outer layer. The bonding strength of the reaction layer was 68.1 MPa. Apatite completely covered the surface of the pack-cementation-treated CP Ti after immersion in Kokubo solution for 21.6 ks; such rapid apatite formation suggests that pack cementation treatment improves the biocompatibility of titanium.

scholarly journals Characterisation and modelling of in-plane springback in a commercially pure titanium (CP-Ti)

2018 ◽  
Vol 53 (9) ◽  
pp. 6872-6892 ◽  
Author(s):  
S. Khayatzadeh ◽  
M. J. Thomas ◽  
Y. Millet ◽  
S. Rahimi
Keyword(s):  
Pure Titanium ◽  
Commercially Pure Titanium ◽  
Commercially Pure ◽  
Cp Ti
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