scholarly journals Produced Water Treatment with Conventional Adsorbents and MOF as an Alternative: A Review

Materials ◽  
2021 ◽  
Vol 14 (24) ◽  
pp. 7607
Author(s):  
Humaira Gul Zaman ◽  
Lavania Baloo ◽  
Rajashekhar Pendyala ◽  
Pradeep Kumar Singa ◽  
Suhaib Umer Ilyas ◽  
...  

A large volume of produced water (PW) has been produced as a result of extensive industrialization and rising energy demands. PW comprises organic and inorganic pollutants, such as oil, heavy metals, aliphatic hydrocarbons, and radioactive materials. The increase in PW volume globally may result in irreversible environmental damage due to the pollutants’ complex nature. Several conventional treatment methods, including physical, chemical, and biological methods, are available for produced water treatment that can reduce the environmental damages. Studies have shown that adsorption is a useful technique for PW treatment and may be more effective than conventional techniques. However, the application of adsorption when treating PW is not well recorded. In the current review, the removal efficiencies of adsorbents in PW treatment are critically analyzed. An overview is provided on the merits and demerits of the adsorption techniques, focusing on overall water composition, regulatory discharge limits, and the hazardous effects of the pollutants. Moreover, this review highlights a potential alternative to conventional technologies, namely, porous adsorbent materials known as metal–organic frameworks (MOFs), demonstrating their significance and efficiency in removing contaminants. This study suggests ways to overcome the existing limitations of conventional adsorbents, which include low surface area and issues with reuse and regeneration. Moreover, it is concluded that there is a need to develop highly porous, efficient, eco-friendly, cost-effective, mechanically stable, and sustainable MOF hybrids for produced water treatment.

2018 ◽  
Vol 156 ◽  
pp. 08003 ◽  
Author(s):  
Tutuk Djoko Kusworo ◽  
Danny Soetrisnanto ◽  
Cynthia Santoso ◽  
Tyas Dwi Payanti ◽  
Dani Puji Utomo

Produced water is a wastewater generated from petroleum industry with high concentration of pollutants such as Total Dissolved Solid, Organic content, and Oil and grease. Membrane technology has been currently applied for produced water treatment due to its efficiency, compact, mild and clean process. The main problem of produced water using membrane is fouling on the membrane surface which causes on low permeate productivity. This paper is majority focused on the improvement of anti-fouling performance through several modifications to increase CA membrane hydrophilicity. The membrane was prepared by formulating the dope solution consists of 18 wt-% CA polymer, acetone, and PEG additive (3 wt-%, 5 wt-%, and 7 wt-%). The membranes are casted using NIPS method and being irradiated under UV light exposure. The SEM images show that parepared membrane has asymmetric structure consist of dense layer, intermediete layer, and finger-like support layer. The filtration test shows that PEG addition increase the membrane hydrophilicity and the permeate flux increases. UV light exposure on the membrane improves the membrane stability and hydrophilicity. The imrpovement of membrane anti-fouling performance is essential to achieve the higher productivity without lowering its pollutants rejection.


2021 ◽  
Author(s):  
Steinar Asdahl ◽  
Johann Jansen van Rensburg ◽  
Martin Einarson Waag ◽  
Rune Glenna Nilssen

Abstract Traditionally, produced water from production separators is handled by multiple steps and different technologies in order to meet the required quality for either discharge or reinjection of the water. The development of the latest Compact Flotation Unit (CFU) technology has unlocked the potential for savings on cost, complexity, footprint and weight for the produced water treatment system. The developed CFU technology has proven applicable through field testing as a single treatment technology for reducing Oil-in-Water (OiW) content directly from tie-in at separator and still meet stringent requirements for outlet OiW quality. Field tests were conducted with inlet OiW concentration ranging from 200-2000 ppm, achieving results in the range 2.5 to 21 ppm only with a two-stage latest generation CFU. Compared to a traditional produced water system setup consisting of de-oiling hydrocyclones and a horizontal degassing vessel, the savings in footprint and operational weight is estimated to 54 % and 53 % respectively utilizing a two-stage CFU for a system with a design capacity of 76.000 BWPD. Furthermore, the development of the latest generation CFU technology has enabled the retrofit concept, incorporating the developed CFU internals into existing gravity separation based produced water vessels, converting them to more efficient flotation vessels with increased capacity. For brownfield and debottlenecking applications, operators are challenged by increasing water cut from maturing wells, and as a result exceeding the facilities design capacity for produced water treatment. This challenge is often further reinforced by increasingly stricter environmental legislation for OiW content for discharge or re-injection. The retrofit concept will offer a highly cost-, footprint- and weight-efficient solutions to these challenges utilizing existing vessels. Benefits of the retrofit concept: Bring proven and unique performance of the technology to other produced water separation vessels helping the operators improve the separation efficiency and increase throughput while meeting discharge requirementsShort execution time compared to installation of new process equipmentLow cost compared to installation of new process equipmentUtilization of existing equipment saves valuable footprint.


2015 ◽  
Vol 57 (15) ◽  
pp. 6693-6701 ◽  
Author(s):  
Taleb H. Ibrahim ◽  
Abdul S. Gulistan ◽  
Mustafa I. Khamis ◽  
Hussain Ahmed ◽  
Ahmed Aidan

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