scholarly journals Two-Step Synthesis of Bismuth-Based Hybrid Halide Perovskite Thin-Films

Materials ◽  
2021 ◽  
Vol 14 (24) ◽  
pp. 7827
Author(s):  
Vanira Trifiletti ◽  
Sally Luong ◽  
Giorgio Tseberlidis ◽  
Stefania Riva ◽  
Eugenio S. S. Galindez ◽  
...  
Keyword(s):  
Thin Film ◽  
Thin Films ◽  
Good Alternative ◽  
Bismuth Iodide ◽  
Earth Abundant ◽  
Low Toxicity ◽  
Halide Perovskites ◽  
Halide Perovskite ◽  
Scalable Methods ◽  
Lead Halide

Lead halide perovskites have been revolutionary in the last decade in many optoelectronic sectors. Their bismuth-based counterparts have been considered a good alternative thanks to their composition of earth-abundant elements, good chemical stability, and low toxicity. Moreover, their electronic structure is in a quasi-zero-dimensional (0D) configuration, and they have recently been explored for use beyond optoelectronics. A significant limitation in applying thin-film technology is represented by the difficulty of synthesizing compact layers with easily scalable methods. Here, the engineering of a two-step synthesis in an air of methylammonium bismuth iodide compact thin films is reported. The critical steps of the process have been highlighted so that the procedure can be adapted to different substrates and application areas.

scholarly journals Interaction of light with lead halide perovskites: A review

2019 ◽  
Vol 2 (2) ◽  
pp. 67
Author(s):  
Zhiya Dang ◽  
Duc Anh Dinh
Keyword(s):  
Thin Film ◽  
Thin Films ◽  
Light Illumination ◽  
Low Light ◽  
Practical Applications ◽  
Halide Perovskites ◽  
Halide Perovskite ◽  
First Time ◽  
Lead Halide ◽  
Sample Environment

Lead halide perovskites are the new rising generation of semiconductor materials due to their unique optical and electrical properties. The investigation of the interaction of halide perovskites and light is a key issue not only for understanding their photophysics but also for practical applications. Hence, tremendous efforts have been devoted to this topic and brunch into two: (i) decomposition of the halide perovskites thin films under light illumination; and (ii) influence of light soaking on their photoluminescence (PL) properties. In this review, we for the first time thoroughly compare the illumination conditions and the sample environment to correlate the PL changes and decomposition of perovskite under light illumination. In the case of vacuum and dry nitrogen, PL of the halide perovskite (MAPbI3–xClx, MAPbBr3–xClx, MAPbI3) thin films decreases due to the defects induced by light illumination, and under high excitations, the thin film even decomposes. In the presence of oxygen or moisture, light induces the PL enhancement of halide perovskite (MAPbI3) thin films at low light illumination, while increasing the excitation, which causes the PL to quench and perovskite thin film to decompose. In the case of mixed halide perovskite ((MA)Pb(BrxI1-x)3) light induces reversible segregation of Br domains and I domains. 

scholarly journals Interaction of light with lead halide perovskites: A review

2018 ◽  
Vol 1 (4) ◽  
Author(s):  
Zhiya Dang 1 ◽  
Duc Anh Dinh 1
Keyword(s):  
Thin Film ◽  
Thin Films ◽  
Light Illumination ◽  
Low Light ◽  
Practical Applications ◽  
Halide Perovskites ◽  
Halide Perovskite ◽  
First Time ◽  
Lead Halide ◽  
Sample Environment

Lead halide perovskites are the new rising generation of semiconductor materials due to theirunique optical and electrical properties. The investigation of the interaction of halide perovskites and light is a key issue not only for understanding theirphotophysicsbut also for practical applications. Hence, tremendous efforts have been devoted to this topic andbrunch into two:(i)decompositionof the halide perovskites thin films under light illumination and(ii)influence of light soaking on their photoluminescence (PL) properties. In this review, we for the first time thoroughly compare the illumination conditions and the sample environment to correlate the PL changes and decomposition of perovskite under light illumination. Inthe case of vacuum and dry nitrogen, PL of the halide perovskite ( PbI3–xClx, PbBr3–xClx, MAPbI3) thin films decreases due to the defects induced by light illumination, and under high excitations the thin film even decomposes. In thepresence of oxygen or moisture,light induces the PL enhancement of halide perovskite (MAPbI3) thin films at low light illumination, while increasing the excitationcauses the PL to quench and perovskite thin film to decompose. In the case of mixed halide perovskite (MAPb(BrxI1-x)3) light inducesreversible segregation of Br domains and I domains. 

scholarly journals Comment on “ferroelectricity-free lead halide perovskites” by A. Gómez, Q. Wang, A. R. Goñi, M. Campoy-Quiles and A. Abate, Energy Environ. Sci., 2019, 12, 2537

2020 ◽  
Vol 13 (6) ◽  
pp. 1888-1891
Author(s):  
Alexander Colsmann ◽  
Tobias Leonhard ◽  
Alexander D. Schulz ◽  
Holger Röhm
Keyword(s):  
Thin Films ◽  
Metal Halide ◽  
Organic Metal ◽  
Metal Halide Perovskite ◽  
Halide Perovskites ◽  
Halide Perovskite ◽  
Lead Halide ◽  
Energy Environ

This comment analyzes pitfalls when investigating piezoresponse and ferroelectricity in organic-metal halide perovskite thin films.

Luminescence spectroscopy of lead-halide perovskites: materials properties and application as photovoltaic devices

2017 ◽  
Vol 5 (14) ◽  
pp. 3427-3437 ◽  
Author(s):  
Yoshihiko Kanemitsu
Keyword(s):  
Thin Films ◽  
Optical Properties ◽  
Solar Cell ◽  
Single Crystals ◽  
Luminescence Spectroscopy ◽  
Photovoltaic Devices ◽  
Materials Properties ◽  
Halide Perovskites ◽  
Halide Perovskite ◽  
Lead Halide

This review summarizes the optical properties of lead-halide-perovskite thin films, single crystals, and solar-cell devices.

scholarly journals Study on A-Site Compositional Mixing for the Shear Coating Process of FA-Based Lead Halide Perovskites

2021 ◽  
Vol 59 (5) ◽  
pp. 321-328
Author(s):  
Hansol Kim ◽  
Hyewon Gu ◽  
Minju Song ◽  
Choong-Heui Chung ◽  
Yong-Jun Oh ◽  
...  
Keyword(s):  
Thin Film ◽  
Thin Films ◽  
Ab Initio Calculations ◽  
Ab Initio ◽  
Perovskite Solar Cells ◽  
Future Research ◽  
Coating Process ◽  
Lead Iodide ◽  
Halide Perovskites ◽  
Halide Perovskite

Halide perovskite solar cells have been attracting tremendous attention as next-generation solar cell materials because of their excellent optical and electrical properties. Formamidinium lead tri-iodide (FAPbI3) exhibits the narrowest band gap among lead iodide perovskites and shows excellent thermal and chemical stability, also. However, the large-area coating of FAPbI3 needed for commercialization has not been successful because of the instability of the black phase of FAPbI3 at ambient temperature. This study presents a compositional engineering direction to control the polymorph of the FAPbI3 thin film for the shear coating processes, without halide mixing. By adopting a hot substrate above 100 oC, our shear coating process can produce the black phase FA-based halide perovskites without halide mixing. We carefully investigate the Cs-FA and MA-FA mixed lead iodide perovskites’ phase stability by combining the study with thin-film fabrication and ab initio calculations. Cs-FA mixing shows promising behaviors for stabilizing α-FAPbI3 (black phase) compared with MA-FA. Stable FA-rich perovskite films cannot be achieved via shear coating processes with MA-FA mixing. Ab initio calculations revealed that Cs-FA mixing is excellent for inhibiting phase decomposition and water incorporation. This study is the first report that FA-based halide perovskite thin films can be made with the shear coating process without MA-Br mixing. We reveal the origin of the stable film formation with Cs-FA mixing, and present future research directions for fabricating FA-based perovskite thin films using shear coating.

scholarly journals Low defects, large area and high stability of all-inorganic lead halide perovskite CsPbBr3 thin films with micron-grains via heat-spraying process for self-driven photodetector

RSC Advances ◽  
2018 ◽  
Vol 8 (51) ◽  
pp. 29089-29095 ◽  
Author(s):  
Huawei Zhou ◽  
Lin Fan ◽  
Guohang He ◽  
Cang Yuan ◽  
Yunying Wang ◽  
...  
Keyword(s):  
Thin Film ◽  
Thin Films ◽  
High Stability ◽  
Saturated Solution ◽  
Large Area ◽  
Inorganic Lead ◽  
Halide Perovskite ◽  
Spraying Process ◽  
Lead Halide

In this study, large area, low defect and high stable all-inorganic lead halide perovskite CsPbBr3 thin film with micron-grains (MG-CsPbBr3-TF) are prepared via heat-spraying process (HSP) using CsPbBr3 saturated solution (CsPbBr3-SS).

Rare-earth quantum cutting in metal halide perovskites – a review

2021 ◽  
Author(s):  
Silvia M. Ferro ◽  
Merlinde Wobben ◽  
Bruno Ehrler
Keyword(s):  
Thin Films ◽  
Rare Earth ◽  
Metal Halide ◽  
Quantum Cutting ◽  
Halide Perovskites ◽  
Halide Perovskite ◽  
Lead Halide

Ytterbium-doped lead halide perovskite (Yb3+:CsPbX3 with x = Cl or Cl/Br) nanocrystals and thin films have shown surprisingly efficient downconversion by quantum cutting with PLQYs up to 193%.

scholarly journals A New Route for Caesium Lead Halide Perovskite Deposition

2020 ◽  
Author(s):  
Naomi Falsini ◽  
Andrea Ristori ◽  
Francesco Biccari ◽  
Nicola Calisi ◽  
Giammarco Roini ◽  
...  
Keyword(s):  
Thin Films ◽  
Optoelectronic Devices ◽  
Inhomogeneous Broadening ◽  
Spectroscopy Study ◽  
Radio Frequency Magnetron Sputtering ◽  
High Quality ◽  
Micro Scale ◽  
Halide Perovskites ◽  
Halide Perovskite ◽  
Lead Halide

Abstract Inorganic metal halide perovskites are relevant semiconductors for optoelectronic devices. In this work the successful deposition of thin films of CsPbBr3 and CsPbCl3 have been obtained by Radio-Frequency magnetron sputtering. A detailed photoluminescence (PL) spectroscopy study of the as-grown samples was conducted at the macro and micro scale in a wide temperature range (10-300 K) to fully characterize the PL on sample areas of square centimeters, to assess the origin of the inhomogeneous broadening and to quantify the PL quantum yield quenching. Our results prove that this technique allows for the realization of high quality nanometric films with controlled thickness of relevance for optoelectronic applications.

A thiourea additive-based quadruple cation lead halide perovskite with an ultra-large grain size for efficient perovskite solar cells

Nanoscale ◽  
2019 ◽  
Vol 11 (45) ◽  
pp. 21824-21833 ◽  
Author(s):  
Jyoti V. Patil ◽  
Sawanta S. Mali ◽  
Chang Kook Hong
Keyword(s):  
Thin Films ◽  
Grain Size ◽  
Solar Cells ◽  
Power Conversion Efficiency ◽  
Conversion Efficiency ◽  
Power Conversion ◽  
Perovskite Solar Cells ◽  
Inorganic Perovskite ◽  
Halide Perovskite ◽  
Lead Halide

Controlling the grain size of the organic–inorganic perovskite thin films using thiourea additives now crossing 2 μm size with >20% power conversion efficiency.

scholarly journals Nanometer-Thick [(FPEA)2PbX4; X=I, Br] 2D Halide Perovskite Based Thin Films for Pollutant Detection and Nonconventional Photocatalytic Degradation

2021 ◽  
Author(s):  
Arindam Mondal ◽  
Akash Lata ◽  
Aarya Prabhakaran ◽  
Satyajit Gupta
Keyword(s):  
Thin Films ◽  
Photocatalytic Degradation ◽  
Three Dimensional ◽  
Two Dimensional ◽  
Reduced Dimensionality ◽  
P Application ◽  
Halide Perovskites ◽  
Halide Perovskite ◽  
Pollutant Detection

Application of three-dimensional (3D)-halide perovskites (HaP) in photocatalysis encourages the new exercise with two-dimensional (2D) HaP based thin-films for photocatalytic degradation of dye. The reduced dimensionality to 2D-HaPs, with a...

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