scholarly journals The Perron Gold Deposit, Archean Abitibi Belt, Canada: Exceptionally High-Grade Mineralization Related to Higher Gold-Carrying Capacity of Hydrocarbon-Rich Fluids

Minerals ◽  
2021 ◽  
Vol 11 (10) ◽  
pp. 1066
Author(s):  
Damien Gaboury ◽  
Dominique Genna ◽  
Jacques Trottier ◽  
Maxime Bouchard ◽  
Jérôme Augustin ◽  
...  
Keyword(s):  
Mass Spectrometry ◽  
Trace Element ◽  
Gold Deposit ◽  
Gold Mineralization ◽  
Gold Deposits ◽  
Orogenic Gold ◽  
Magmatic Fluid ◽  
High Grade ◽  
Host Rocks ◽  
Mineralizing Fluids

The Perron deposit, an Archean orogenic gold deposit located in the Abitibi belt, hosts a quartz vein-type gold-bearing zone, known as the high-grade zone (HGZ). The HGZ is vertically continuous along >1.2 km, and is exceptionally rich in visible gold throughout its vertical extent, with grades ranging from 30 to 500 ppm. Various hypotheses were tested to account for that, such as: (1) efficient precipitating mechanisms; (2) gold remobilization; (3) particular fluids; (4) specific gold sources for saturating the fluids; and (5) a different mineralizing temperature. Host rocks recorded peak metamorphism at ~600 °C based on an amphibole geothermometer. Visible gold is associated with sphalerite (<5%) which precipitated at 370 °C, based on the sphalerite GGIMFis geothermometer, during late exhumation of verticalized host rocks. Pyrite chemistry analyzed by LA-ICP-MS (Laser Ablation Inductively Coupled Plasma Mass Spectrometry) is comparable to classical orogenic gold deposits of the Abitibi belt, without indication of a possible magmatic fluid and gold contribution. Comparison of pyrite trace element signatures for identifying a potential gold source was inconclusive to demonstrate that primary base-metal rich volcanogenic gold mineralization, dispersed in the host rhyolitic dome, could be the source for the later formation of the HGZ. Rather, nodular pyrites in graphitic shales, sharing similar trace element signatures with pyrite of the HGZ, are considered a potential source. The most striking outcome is the lack of water in the mineralizing fluids, implying that gold was not transported under aqueous complexes, even if fugacity of sulfur (−6) and oxygen (−28), and pH (~7) are providing the best conditions at a temperature of 350 °C for solubilizing gold in water. Fluid inclusions, analyzed by solid-probe mass spectrometry, are rather comparable to fossil gas composed mostly of hydrocarbons (methane and ethane and possibly butane and propane and other unidentified organic compounds), rich in CO2, with N2 and trace of Ar, H2S, and He. It is interpreted that gold and zinc were transported as hydrocarbon-metal complexes or as colloidal gold nanoparticles. The exceptional high content of gold and zinc in the HGZ is thus explained by the higher transporting capacity of these unique mineralizing fluids.

scholarly journals Genesis of the Koka Gold Deposit in Northwest Eritrea, NE Africa: Constraints from Fluid Inclusions and C-H-O-S Isotopes

2019 ◽  
Author(s):  
Kai Zhao ◽  
Huazhou Yao ◽  
Jianxiong Wang ◽  
Ghebsha Fitwi Ghebretnsae ◽  
Wenshuai Xiang ◽  
...  
Keyword(s):  
Gold Deposit ◽  
Meteoric Water ◽  
Gold Mineralization ◽  
Early Stage ◽  
Gold Deposits ◽  
Orogenic Gold ◽  
Quartz Veins ◽  
Three Phase ◽  
Igneous Origin ◽  
Ne Africa

The Koka gold deposit is located in the Elababu shear zone between the Nakfa terrane and the Adobha Abiy terrane, NW Eritrea. Based on the paragenetic study two main stages of gold mineralization were identified in the Koka gold deposit: 1) an early stage of pyrite-chalcopyrite-sphalerite-galena-gold-quartz vein; and 2) a second stage of pyrite-quartz veins. NaCl-aqueous inclusions, CO2-rich inclusions, and three-phase CO2-H2O inclusions occur in the quartz veins at Koka. The ore-bearing quartz veins formed at 268℃, from NaCl-CO2-H2O(-CH4) fluids averaging 5 wt% NaCl eq. The ore-forming mechanisms include fluid immiscibility during stage I, and mixing with meteoric water during stage II. Oxygen, hydrogen and carbon isotopes suggest that the ore-forming fluids originated as mixtures of metamorphic water, meteoric water and magmatic water, whereas sulfur isotope suggest an igneous origin. Features of geology and ore-forming fluid at Koka deposit are similar to those of orogenic gold deposits, suggesting the Koka deposit might be an orogenic gold deposit related to granite.

U-Pb Dating on Hydrothermal Rutile and Monazite from the Badu Gold Deposit Supports an Early Cretaceous Age for Carlin-Type Gold Mineralization in the Youjiang Basin, Southwestern China

2021 ◽  
Author(s):  
Wei Gao ◽  
Ruizhong Hu ◽  
Albert H. Hofstra ◽  
Qiuli Li ◽  
Jingjing Zhu ◽  
...  
Keyword(s):  
Gold Deposit ◽  
Early Cretaceous ◽  
Gold Mineralization ◽  
Gold Deposits ◽  
Detrital Zircons ◽  
Youjiang Basin ◽  
Host Rocks ◽  
Gold Bearing ◽  
Carlin Type Gold Deposits

Abstract The Youjiang basin on the southwestern margin of the Yangtze block in southwestern China is the world’s second largest Carlin-type gold province after Nevada, USA. The lack of precise age determinations on gold deposits in this province has hindered understanding of their genesis and relation to the geodynamic setting. Although most Carlin-type gold deposits in the basin are hosted in calcareous sedimentary rocks, ~70% of the ore in the Badu Carlin-type gold deposit is hosted by altered and sulfidized dolerite. Although in most respects Badu is similar to other Carlin-type gold deposits in the province, alteration of the unusual dolerite host produced hydrothermal rutile and monazite that can be dated. Field observations show that gold mineralization is spatially associated with, but temporally later than, dolerite. In situ secondary ion mass spectrometry (SIMS) U-Pb dating on magmatic zircon from the least altered dolerite yielded a robust emplacement age of 212.2 ± 1.9 Ma (2σ, mean square of weighted deviates [MSWD] = 0.55), providing a maximum age constraint on gold mineralization. The U-Th/He ages of detrital zircons from hydrothermally mineralized sedimentary host rocks at Badu and four other Carlin-type gold deposits yielded consistent weighted mean ages of 146 to 130 Ma that record cooling from a temperature over 180° to 200°C and place a lower limit on the age of gold mineralization in the basin. Hydrothermal rutile and monazite that are coeval with gold mineralization have been identified in the mineralized dolerite. Rutile is closely associated with hydrothermal ankerite, sericite, and gold-bearing pyrite. It has high concentrations of W, Fe, V, Cr, and Nb, as well as growth zones that are variably enriched in W, Fe, Nb, and U. Monazite contains primary two-phase fluid inclusions and is intergrown with gold-bearing pyrite and hydrothermal minerals. In situ SIMS U-Pb dating of rutile yielded a Tera-Wasserburg lower intercept age of 141.7 ± 5.8 Ma (2σ, MSWD = 1.04) that is within error of the in situ SIMS Th-Pb age of 143.5 ± 1.4 Ma (2σ, MSWD = 1.5) on monazite. These ages are ~70 m.y. younger than magmatic zircons in the host dolerite and are similar to the aforementioned U-Th/He cooling ages on detrital zircons from hydrothermally mineralized sedimentary host rocks. We, therefore, conclude that the Badu Carlin-type gold deposit formed at ca. 144 Ma. The agreement of the rutile and monazite ages with the U-Th-He cooling ages of Badu and four other Carlin-type gold deposits in the Youjiang basin suggests that ca. 144 Ma is representative of a regional Early Cretaceous Carlin-type hydrothermal event formed during back-arc extension.

Micro-Nanoscale Characteristics of Pyrite and Its Implications for Gold Mineralization: Two Cases of Gold Deposits in the Youjiang Basin and Southwestern Tianshan Mountains

2021 ◽  
Vol 21 (1) ◽  
pp. 246-261
Author(s):  
Hongye Feng ◽  
Yiwen Ju ◽  
Bo Chen ◽  
Weixuan Fang ◽  
Hongjian Zhu ◽  
...  
Keyword(s):  
Mass Spectrometry ◽  
Gold Deposit ◽  
Gold Mineralization ◽  
Hydrothermal Solution ◽  
Economic Benefits ◽  
Gold Deposits ◽  
Formation Mechanisms ◽  
Mineralization Process ◽  
Nano Gold ◽  
Gold Bearing

The mineralogical and compositional characteristics of gold-bearing minerals and the occurrence of gold are not only of great significance to exploring the sources of ore-forming materials and their formation mechanisms but also helpful for designing reasonable beneficiations and smelting schemes and achieving remarkable economic benefits. This paper presents an integrated study on the crystal characteristics, elemental composition and distribution of pyrite (the main gold-bearing minerals), on the basis of electron probe microanalysis (EPMA), scanning electron microscopy (SEM), laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) and nano-secondary ion mass spectrometry (NanoSIMS). The occurrence of gold in the Shuiyindong gold deposit and Ashawayi gold deposit has been studied by means of microscopy, SEM, and EPMA images, elemental correlations, S–Fe–As ternary diagrams, logAs–logAu diagrams and Au/As ratios. The gold in pyrite of the Shuiyindong deposit is in the form of nano gold inclusions and lattice gold. The gold in pyrite of the Ashawayi deposit dominantly exists in the form of nano gold inclusions or is present as micro-nano gold particles in the cracks or edges of pyrite, some of which can exist as lattice gold. The ore-forming hydrothermal solution of the Shuiyindong gold deposit is mainly underground hot brine, but it may be reformed by a deep magmatic hydrothermal solution or volcanic-subvolcanic hydrothermal solution. The ore-forming hydrothermal solution of the Ashawayi gold deposit is mainly derived from the metamorphic hydrothermal solution formed during the orogenic process, and the ore-forming process or post-mineralization process may be reformed by the leaching of underground hot brine. Finally, the characteristics of ore-forming fluids and evolution of the two types of deposits are determined via pyrite element surface scanning. This paper shows that micro-nanoscale study of gold-bearing pyrite is of great significance to understanding the gold mineralization process and is worth further study.

scholarly journals Genesis of the Koka Gold Deposit in Northwest Eritrea, NE Africa: Constraints from Fluid Inclusions and C–H–O–S Isotopes

Minerals ◽  
2019 ◽  
Vol 9 (4) ◽  
pp. 201 ◽  
Author(s):  
Kai Zhao ◽  
Huazhou Yao ◽  
Jianxiong Wang ◽  
Ghebsha Fitwi Ghebretnsae ◽  
Wenshuai Xiang ◽  
...  
Keyword(s):  
Gold Deposit ◽  
Gold Mineralization ◽  
Early Stage ◽  
Gold Deposits ◽  
Orogenic Gold ◽  
Quartz Veins ◽  
Second Stage ◽  
Three Phase ◽  
Igneous Origin ◽  
Ne Africa

: The Koka gold deposit is located in the Elababu shear zone between the Nakfa terrane and the Adobha Abiy terrane, NW Eritrea. Based on a paragenetic study, two main stages of gold mineralization were identified in the Koka gold deposit: (1) an early stage of pyrite–chalcopyrite–sphalerite–galena–gold–quartz vein; and (2) a second stage of pyrite–quartz veins. NaCl-aqueous inclusions, CO2-rich inclusions, and three-phase CO2–H2O inclusions occur in the quartz veins at Koka. The ore-bearing quartz veins formed at 268 °C from NaCl–CO2–H2O(–CH4) fluids averaging 5 wt% NaCl eq. The ore-forming mechanisms include fluid immiscibility during stage I, and mixing with meteoric water during stage II. Oxygen, hydrogen, and carbon isotopes suggest that the ore-forming fluids originated as mixtures of metamorphic water and magmatic water, whereas the sulfur isotope suggests an igneous origin. The features of geology and ore-forming fluid at the Koka deposit are similar to those of orogenic gold deposits, suggesting that the Koka deposit might be an orogenic gold deposit related to granite.

scholarly journals Significance of Calcite Trace Elements Contents and C-O Isotopic Compositions for Ore-Forming Fluids and Gold Prospecting in the Zhesang Carlin-Like Gold Deposit of Southeastern Yunnan, China

Minerals ◽  
2020 ◽  
Vol 10 (4) ◽  
pp. 338
Author(s):  
Jiasheng Wang ◽  
Jinyang Chang ◽  
Chao Li ◽  
Zhenchun Han ◽  
Tao Wang ◽  
...  
Keyword(s):  
Rare Earth ◽  
Rare Earth Elements ◽  
Gold Deposit ◽  
Meteoric Water ◽  
Gold Mineralization ◽  
Mining Area ◽  
Gold Deposits ◽  
Hydrothermal Fluids ◽  
Magmatic Fluid ◽  
Isotopic Compositions

The Zhesang gold deposit of southeastern Yunnan is an important component of the Dian-Qian-Gui (Yunnan, Guizhou, and Guangxi) “Golden Triangle”, which hosts a multitude of Carlin-like gold deposits (CLGDs). Calcite is one of the most common gangue minerals in Zhesang. The calcites that have been found in the mining area are classified as ore-stage and post-ore calcites. The ore-stage calcite exhibits a clear paragenetic relationship with gold-bearing arsenopyrite and with an alteration halo that has been cut by the post-ore calcite. To elucidate the origin of the ore-forming fluids of the Zhesang gold deposit and to investigate the possibility of utilizing calcite geochemistry as prospecting indicators, the rare earth elements (REEs), Y, Fe, Mn and Mg contents, and C-O isotopic compositions of calcites from Zhesang have been analyzed. The ore-stage calcite is enriched in middle rare earth elements (MREEs) relative to light rare earth elements (LREEs) and heavy rare earth elements (HREEs) (MREE/LREE = 1.11–1.61, MREE/HREE = 6.12–8.22), whereas post-ore calcite exhibits an enrichment in LREE (LREE/HREE = 4.39–14.93, MREE/LREE = 0.35–0.71). The ore-stage and post-ore calcites were both formed by hydrothermal fluids; however, these hydrothermal fluids may have different sources. The Fe contents of the ore-stage calcite are significantly higher than those of post-ore calcite (4690–6300 μg/g versus 2030–2730 μg/g). Ore-stage calcite also has significantly lower δ18OV-SMOW values than post-ore calcite (11.03–12.49‰ versus 16.48–17.14‰). These calcites with an MREE/LREE ratio greater than 0.92, MREE/HREE ratio greater than 5.69, Fe content greater than 3827 μg/g, and δ18OV-SMOW value less than 14.40‰ represent ore-stage calcites and are important prospecting guidelines. According to the REE, C-O isotopic characteristics of the calcites and the previous findings, it is inferred that the ore-forming fluids of the Zhesang gold deposit were a mixture of crustal fluid by meteoric water leaching wall rocks and a small amount of basic magmatic fluid. The formation of post-ore calcite might be derived from meteoric water and marine carbonates interaction. The ore-forming fluids of the Zhesang gold deposit may be associated with the intrusion of diabase that outcrops in the mining area, and that the basic magmatic activities of the Indosinian period also provided some of the ore-forming materials and heat for gold mineralization.

scholarly journals The Metamorphic Rocks-Hosted Gold Mineralization At Rumbia Mountains Prospect Area In The Southeastern Arm of Sulawesi Island, Indonesia

2017 ◽  
Vol 2 (3) ◽  
pp. 217
Author(s):  
Hasria Hasria ◽  
Arifudin Idrus ◽  
I Wayan Warmada
Keyword(s):  
Gold Deposit ◽  
Gold Mineralization ◽  
Gold Deposits ◽  
Orogenic Gold ◽  
Metamorphic Rocks ◽  
Quartz Veins ◽  
Orogenic Gold Deposit ◽  
Ore Mineralization ◽  
Hematite Fe2o3 ◽  
Primary Gold

Recently, in Indonesia gold exploration activities  are not only focused along volcanic-magmatic belts, but also starting to shift along metamorphic and sedimentary terrains. The study area is located in Rumbia mountains, Bombana Regency, Southeast Sulawesi Province. This paper is aimed to describe characteristics of alteration and ore mineralization associated  with metamorphic rock-related gold deposits.  The study area is found the placer and  primary gold hosted by metamorphic rocks. The gold is evidently derived from gold-bearing quartz veins hosted by Pompangeo Metamorphic Complex (PMC). These quartz veins are currently recognized in metamorphic rocks at Rumbia Mountains. The quartz veins are mostly sheared/deformed, brecciated, irregular vein, segmented and  relatively massive and crystalline texture with thickness from 1 cm to 15.7 cm. The wallrock are generally weakly altered. Hydrothermal alteration types include sericitization, argillic, inner propylitic, propylitic, carbonization and carbonatization. There some precious metal identified consist of native gold and ore mineralization including pyrite (FeS2), chalcopyrite (CuFeS2), hematite (Fe2O3), cinnabar (HgS), stibnite (Sb2S3) and goethite (FeHO2). The veins contain erratic gold in various grades from below detection limit <0.0002 ppm to 18.4 ppm. Based on those characteristics, it obviously indicates that the primary gold deposit present in the study area is of orogenic gold deposit type. The orogenic gold deposit is one of the new targets for exploration in Indonesia

scholarly journals Genesis of the Late Cretaceous Longquanzhan Gold Deposit in the Central Tan-Lu Fault Zone, Shandong Province, China: Constraints from Noble Gas and Sulfur Isotopes

Minerals ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 250
Author(s):  
Chuanpeng Liu ◽  
Wenjie Shi ◽  
Junhao Wei ◽  
Huan Li ◽  
Aiping Feng ◽  
...  
Keyword(s):  
Gold Deposit ◽  
Fault Zone ◽  
Late Cretaceous ◽  
Genetic Model ◽  
Gold Mineralization ◽  
Sulfur Isotopes ◽  
Noble Gas ◽  
Gold Deposits ◽  
Shandong Province ◽  
Magma Sources

The Longquanzhan deposit is one of the largest gold deposits in the Yi-Shu fault zone (central section of the Tan-Lu fault zone) in Shandong Province, China. It is an altered-rock type gold deposit in which ore bodies mainly occur at the contact zone between the overlying Cretaceous rocks and the underlying Neoarchean gneissic monzogranite. Shi et al. reported that this deposit formed at 96 ± 2 Ma using pyrite Rb–Sr dating method and represents a new gold mineralization event in the Shandong Province in 2014. In this paper, we present new He–Ar–S isotopic compositions to further decipher the sources of fluids responsible for the Longquanzhan gold mineralization. The results show that the δ34S values of pyrites vary between 0.9‰ and 4.4‰ with an average of 2.3‰. Inclusion-trapped fluids in ore sulfides have 3He/4He and 40Ar/36Ar ratios of 0.14–0.78 Ra and 482–1811, respectively. These isotopic data indicate that the ore fluids are derived from a magmatic source, which is dominated by crustal components with minor mantle contribution. Air-saturated water may be also involved in the hydrothermal system during the magmatic fluids ascending or at the shallow deposit site. We suggest that the crust-mantle mixing signature of the Longquanzhan gold deposit is genetically related to the Late Cretaceous lithospheric thinning along the Tan-Lu fault zone, which triggers constantly uplifting of the asthenosphere surface and persistent ascending of the isotherm plane to form the gold mineralization-related crustal level magma sources. This genetic model can be applied, to some extent, to explain the ore genesis of other deposits near or within the Tan-Lu fault belt.

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