scholarly journals Properties of Graphene-Related Materials Controlling the Thermal Conductivity of Their Polymer Nanocomposites

Nanomaterials ◽  
2020 ◽  
Vol 10 (11) ◽  
pp. 2167
Author(s):  
Samuele Colonna ◽  
Daniele Battegazzore ◽  
Matteo Eleuteri ◽  
Rossella Arrigo ◽  
Alberto Fina
Keyword(s):  
Thermal Conductivity ◽  
Polymer Nanocomposites ◽  
Surface Functionalization ◽  
Lateral Size ◽  
Large Scatter ◽  
Preparation Methods ◽  
Conductivity Enhancement ◽  
Melt Polymerization ◽  
Wide Range ◽  
Different Types

Different types of graphene-related materials (GRM) are industrially available and have been exploited for thermal conductivity enhancement in polymers. These include materials with very different features, in terms of thickness, lateral size and composition, especially concerning the oxygen to carbon ratio and the possible presence of surface functionalization. Due to the variability of GRM properties, the differences in polymer nanocomposites preparation methods and the microstructures obtained, a large scatter of thermal conductivity performance is found in literature. However, detailed correlations between GRM-based nanocomposites features, including nanoplatelets thickness and size, defectiveness, composition and dispersion, with their thermal conductivity remain mostly undefined. In the present paper, the thermal conductivity of GRM-based polymer nanocomposites, prepared by melt polymerization of cyclic polybutylene terephtalate oligomers and exploiting 13 different GRM grades, was investigated. The selected GRM, covering a wide range of specific surface area, size and defectiveness, secure a sound basis for the understanding of the effect of GRM properties on the thermal conductivity of their relevant polymer nanocomposites. Indeed, the obtained thermal conductivity appeares to depend on the interplay between the above GRM feature. In particular, the combination of low GRM defectiveness and high filler percolation density was found to maximize the thermal conductivity of nanocomposites.

Thermal Conductivity of Metal-Oxide Nanofluids: Particle Size Dependence and Effect of Laser Irradiation

2006 ◽  
Vol 129 (3) ◽  
pp. 298-307 ◽  
Author(s):  
Sang Hyun Kim ◽  
Sun Rock Choi ◽  
Dongsik Kim
Keyword(s):  
Thermal Conductivity ◽  
Particle Size ◽  
Effective Thermal Conductivity ◽  
Laser Irradiation ◽  
Volume Fraction ◽  
Suspended Particle ◽  
Titanium Dioxide Nanoparticles ◽  
Size Change ◽  
Conductivity Enhancement ◽  
Wide Range

The thermal conductivity of water- and ethylene glycol-based nanofluids containing alumina, zinc-oxide, and titanium-dioxide nanoparticles is measured using the transient hot-wire method. Measurements are performed by varying the particle size and volume fraction, providing a set of consistent experimental data over a wide range of colloidal conditions. Emphasis is placed on the effect of the suspended particle size on the effective thermal conductivity. Also, the effect of laser-pulse irradiation, i.e., the particle size change by laser ablation, is examined for ZnO nanofluids. The results show that the thermal-conductivity enhancement ratio relative to the base fluid increases linearly with decreasing the particle size but no existing empirical or theoretical correlation can explain the behavior. It is also demonstrated that high-power laser irradiation can lead to substantial enhancement in the effective thermal conductivity although only a small fraction of the particles are fragmented.

scholarly journals Surface functionalization on the thermal conductivity of graphene–polymer nanocomposites

2014 ◽  
Vol 5 (2) ◽  
pp. 123-132 ◽  
Author(s):  
Mingchao Wang ◽  
Dilini Galpaya ◽  
Zheng Bo Lai ◽  
Yanan Xu ◽  
Cheng Yan
Keyword(s):  
Thermal Conductivity ◽  
Polymer Nanocomposites ◽  
Surface Functionalization

Critical Invalidation of Temperature Dependence of Nanofluid Thermal Conductivity Enhancement

2013 ◽  
Vol 135 (5) ◽  
Author(s):  
Kisoo Han ◽  
Wook-Hyun Lee ◽  
Clement Kleinstreuer ◽  
Junemo Koo
Keyword(s):  
Thermal Conductivity ◽  
Natural Convection ◽  
Temperature Dependence ◽  
Temperature Limit ◽  
Thermal Conductivity Enhancement ◽  
Supporting Evidence ◽  
Conductivity Enhancement ◽  
Wide Range ◽  
Wire Method ◽  
The Impact

Of interest is the accurate measurement of the enhanced thermal conductivity of certain nanofluids free from the impact of natural convection. Owing to its simplicity, wide range of applicability and short response time, the transient hot-wire method (THWM) is frequently used to measure the thermal conductivity of fluids. In order to gain a sufficiently high accuracy, special care should be taken to assure that each measurement is not affected by initial heat supply delay, natural convection, and signal noise. In this study, it was found that there is a temperature limit when using THWM due to the incipience of natural convection. The results imply that the temperature-dependence of the thermal conductivity enhancement observed by other researchers might be misleading when ignoring the impact of natural convection; hence, it could not be used as supporting evidence of the effectiveness of micromixing due to Brownian motion. Thus, it is recommended that researchers report how they keep the impact of the natural convection negligible and check the integrity of their measurements in the future researches.

scholarly journals A Multiscale Investigation on the Thermal Transport in Polydimethylsiloxane Nanocomposites: Graphene vs. Borophene

Nanomaterials ◽  
2021 ◽  
Vol 11 (5) ◽  
pp. 1252
Author(s):  
Alessandro Di Pierro ◽  
Bohayra Mortazavi ◽  
Hamidreza Noori ◽  
Timon Rabczuk ◽  
Alberto Fina
Keyword(s):  
Thermal Conductivity ◽  
Electrical Conductivity ◽  
Effective Thermal Conductivity ◽  
Polymer Nanocomposites ◽  
Volume Content ◽  
Thermal Conductance ◽  
Single Layer ◽  
Md Simulations ◽  
Aspect Ratios ◽  
Wide Range

Graphene and borophene are highly attractive two-dimensional materials with outstanding physical properties. In this study we employed combined atomistic continuum multi-scale modeling to explore the effective thermal conductivity of polymer nanocomposites made of polydimethylsiloxane (PDMS) polymer as the matrix and graphene and borophene as nanofillers. PDMS is a versatile polymer due to its chemical inertia, flexibility and a wide range of properties that can be tuned during synthesis. We first conducted classical Molecular Dynamics (MD) simulations to calculate the thermal conductance at the interfaces between graphene and PDMS and between borophene and PDMS. Acquired results confirm that the interfacial thermal conductance between nanosheets and polymer increases from the single-layer to multilayered nanosheets and finally converges, in the case of graphene, to about 30 MWm−2 K−1 and, for borophene, up to 33 MWm−2 K−1. The data provided by the atomistic simulations were then used in the Finite Element Method (FEM) simulations to evaluate the effective thermal conductivity of polymer nanocomposites at the continuum level. We explored the effects of nanofiller type, volume content, geometry aspect ratio and thickness on the nanocomposite effective thermal conductivity. As a very interesting finding, we found that borophene nanosheets, despite having almost two orders of magnitude lower thermal conductivity than graphene, can yield very close enhancement in the effective thermal conductivity in comparison with graphene, particularly for low volume content and small aspect ratios and thicknesses. We conclude that, for the polymer-based nanocomposites, significant improvement in the thermal conductivity can be reached by improving the bonding between the fillers and polymer, or in other words, by enhancing the thermal conductance at the interface. By taking into account the high electrical conductivity of borophene, our results suggest borophene nanosheets as promising nanofillers to simultaneously enhance the polymers’ thermal and electrical conductivity.

THERMAL CONDUCTIVITY ENHANCEMENT OF MATERIAL FOR CALCIUM CHLORIDE/WATER THERMOCHEMICAL ENERGY STORAGE

2018 ◽  
Author(s):  
Takuma Ohtaki ◽  
Maho Mitsuo ◽  
Takayuki Terauchi ◽  
Hiroshi Iguchi ◽  
Keiko Fujioka ◽  
...  
Keyword(s):  
Thermal Conductivity ◽  
Energy Storage ◽  
Calcium Chloride ◽  
Thermal Conductivity Enhancement ◽  
Conductivity Enhancement ◽  
Chloride Water
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