scholarly journals Nanostructured TiO2 and PEDOT Electrodes with Photovoltaic Application

Nanomaterials ◽  
2021 ◽  
Vol 11 (1) ◽  
pp. 107
Author(s):  
Andrés Mauricio Ramírez ◽  
Linda Cattin ◽  
Jean-Christian Bernède ◽  
Fernando Raúl Díaz ◽  
Manuel Alejandro Gacitúa ◽  
...  

In this work, nanostructured TiO2 and poly-3,4-ethylenedioxythiophene (PEDOT) layers were electrochemically prepared over transparent electrodes. Morphological characterization evidenced the presence of nanostructures as planed with 50-nm-wide TiO2 rod formations followed by 30-nm-wide PEDOT wires. Different characterizations were made to the deposits, establishing their composition and optic properties of the deposits. Finally, photovoltaic cells were prepared using this modified electrode, proving that the presence of PEDOT nanowires in the cell achieves almost double the efficiency of its bulk analogue.

Author(s):  
J. C. Bernède ◽  
L. Cattin

The present manuscript is dedicated to In free transparent conductive andflexible heterostructure electrodes. The new electrodes correspond todielectric/metal/dielectic (D/M/D) multilayer structures deposited under vacuum. In thepresent work, after a fast review of the general properties of D/M/D electrodes using Ag asmetal, we then develop the study of D/Cu/D multilayer structures. We propose to substituteCu to Ag, because it is far cheaper. However, Cu having tendency to diffuse into manydielectrics it is difficult to obtain stable electrodes. We show that using Cu:alloys, i.e. Cu:Niand Cu:Al, as metal it is possible to decrease significantly the Cu ions diffusion and toincrease significantly the stability of the multilayer electrodes with Cu. Finally, we show thatwhen these electrodes are used as anode in organic photovoltaic cells, they can allowachieving efficiency similar to that obtained with ITO.


RSC Advances ◽  
2016 ◽  
Vol 6 (30) ◽  
pp. 25062-25069 ◽  
Author(s):  
Ying Zhou ◽  
Zhiping Wang ◽  
Takeshi Saito ◽  
Tetsuhiko Miyadera ◽  
Masayuki Chikamatsu ◽  
...  

A methodology for fabricating small-molecule photovoltaic cells on carbon nanotube transparent electrodes is demonstrated.


2009 ◽  
Vol 609 ◽  
pp. 269-273
Author(s):  
A. Ould-Abbas ◽  
M. Madani ◽  
N.E. Chabane Sari

We investigate the application of porous silicon (PS) in the field of the photovoltaic. In first step we realise a double porous silicon layer by electrochemical anodisation using two different current densities. The low current leads to a low porosity and during annealing, the recrystallisation of this layer allows epitaxial growth. The second current leads to a high porosity which permits the transfer onto a low cost substrate. During high temperature onto hydrogenation treatments of to passivate the structure and epitaxy in liquid phase, porous silicon is recristallized partially. In this work, a characterization by scanning electron microscopy informs us about the morphology of these porous layers.


2018 ◽  
Vol 276 ◽  
pp. 389-398 ◽  
Author(s):  
Francesca Bettazzi ◽  
Serena Laschi ◽  
Diego Voccia ◽  
Cristina Gellini ◽  
Giangaetano Pietraperzia ◽  
...  

2012 ◽  
Vol 22 (33) ◽  
pp. 17176 ◽  
Author(s):  
Xiaoyang Guo ◽  
Jie Lin ◽  
Hong Chen ◽  
Xin Zhang ◽  
Yi Fan ◽  
...  

2012 ◽  
Vol 22 (43) ◽  
pp. 22873 ◽  
Author(s):  
Xiwei Zhang ◽  
Xiujuan Zhang ◽  
Xiaozhen Zhang ◽  
Yuping Zhang ◽  
Liang Bian ◽  
...  

2014 ◽  
Vol 6 (18) ◽  
pp. 16403-16408 ◽  
Author(s):  
Zhichao Xue ◽  
Xingyuan Liu ◽  
Nan Zhang ◽  
Hong Chen ◽  
Xuanming Zheng ◽  
...  

Molecules ◽  
2019 ◽  
Vol 24 (21) ◽  
pp. 3965 ◽  
Author(s):  
Ivana Panžić ◽  
Krunoslav Juraić ◽  
Nikša Krstulović ◽  
Ana Šantić ◽  
Domagoj Belić ◽  
...  

ZnO has prominent electron transport and optical properties, beneficial for photovoltaic application, but its surface is prone to the formation of defects. To overcome this problem, we deposited nanostructured TiO2 thin film on ZnO nanorods to form a stable shell. ZnO nanorods synthesized by wet-chemistry are single crystals. Three different procedures for deposition of TiO2 were applied. The influence of preparation methods and parameters on the structure, morphology, electrical and optical properties were studied. Nanostructured TiO2 shells show different morphologies dependent on deposition methods: (1) separated nanoparticles (by pulsed laser deposition (PLD) in Ar), (2) a layer with nonhomogeneous thickness (by PLD in vacuum or DC reactive magnetron sputtering), and (3) a homogenous thin layer along the nanorods (by chemical deposition). Based on the structural study, we chose the preparation parameters to obtain an anatase structure of the TiO2 shell. Impedance spectroscopy shows pure electron conductivity that was considerably better in all the ZnO@TiO2 than in bare ZnO nanorods or TiO2 layers. The best conductivity among the studied samples and the lowest activation energy was observed for the sample with a chemically deposited TiO2 shell. Higher transparency in the visible part of spectrum was achieved for the sample with a homogenous TiO2 layer along the nanorods, then in the samples with a layer of varying thickness.


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