scholarly journals Improved Solvothermal Synthesis of γ-Fe2O3 Magnetic Nanoparticles for SiO2 Coating

Nanomaterials ◽  
2021 ◽  
Vol 11 (8) ◽  
pp. 1889
Author(s):  
Rashmi Mahajan ◽  
Subramanian Suriyanarayanan ◽  
Ian A. Nicholls

Monodisperse magnetic γ-Fe2O3 nanoparticles (MNPs) were prepared by a simple, improved, one-pot solvothermal synthesis using SDS and PEG 6000 as double capping reagents. This double protecting layer afforded better MNP uniformity (Z average 257 ± 11.12 nm, PDI = 0.18) and colloidal stability. Materials were characterized by DLS, SEM, TEM, XPS, and XRD. The use of these MNPs in the synthesis of core–shell structures with uniform and tunable silica coatings was demonstrated, as silica coated MNPs are important for use in a range of applications, including magnetic separation and catalysis and as platforms for templated nanogel synthesis.

2018 ◽  
Vol 915 ◽  
pp. 163-168 ◽  
Author(s):  
Xiao Shan Zhu ◽  
Violeta G. Demillo ◽  
Si Qi Chen ◽  
Athanasios G. Mamalis

I-III-VI QDs (CuInS2/ZnS or AgInS2/ZnS core/shell structures) possess low toxicity, and are a logical replacement for cadmium-based QDs for biomedical applications. Our synthesis of I-III-VI QDs is based on thermal decomposition of less toxic precursors and can be easily scaled up for mass production for sustainable and reliable imaging and sensing experiments. Through nonstoichiometric composition adjustment, we synthesized I-III-VI QDs with reliable and controllable optical properties, including high QYs and tunable photoluminescence. We also developed new zwitterionic amphiphiles and applied them to encapsulate I-III-VI QDs to achieve colloidal stability in proteinaceous solutions with wide pH/ionic ranges, low non-specific binding, and easily bio-conjugation. On the basis of these developments, we applied our I-III-VI QDs in cellular imaging to to specifically target human brain tumor cells.


2008 ◽  
pp. 5342 ◽  
Author(s):  
Chih-Wei Lai ◽  
Yu-Hsiu Wang ◽  
Borade Prajakta Uttam ◽  
Yu-Chun Chen ◽  
Jong-Kai Hsiao ◽  
...  

RSC Advances ◽  
2012 ◽  
Vol 2 (12) ◽  
pp. 5062 ◽  
Author(s):  
Zian Lin ◽  
Jiangnan Zheng ◽  
Zhiwei Xia ◽  
Huanghao Yang ◽  
Lan Zhang ◽  
...  

2017 ◽  
Vol 36 (4) ◽  
pp. 01 ◽  
Author(s):  
Vagner Sargentelli ◽  
Antônio A. P. Ferreira

Nanotechnology is the understanding and control f matter at dimensions of roughly 1 – 100 nm. At the nanoscale, the properties like electrical conductivity and mechanical strength are not the same as the materials with particles in dimensions much more than 100 nm. The electronic structure changes dramatically too. Between nanomaterials, there is recently a great number of works that investing as the synthesis as the properties of the magnetic nanoparticles. The interest in these materials is due to its magnetic applications. Some of more representative magnetic materials are the metallic oxides, as some ferrites. However, the ferrites are often obtained as mixture of some oxides, which implies that the magnetic properties are not always well defined and reproducible. Thus, the researches has been turned to use of the magnetic metals, between which the cobalt. The cobalt is investigated because its high magnetic susceptility. However, this transition metal is easily oxidate in air and is toxic to human organism. For this reason, it has looked for to effect synthesis involving core – shell structures, which no to allow the oxidation of the cobalt and prevent against its toxicity. Between the shells that come being obtained it is of silica and of gold. In addition, in if treating to catalysis in a general way, the price of the cobalt and its magnetic properties are adjusted for the attainment core – shell catalysts, Cocore@Ptshell, (Co@Pt). So, the aim of this article is to present and to do an analysis of the more representative synthetic route used until the present moment to obtain the core – shell structures: Co@SiO2, Co@Au and Co@Pt.


2018 ◽  
Vol 2018 ◽  
pp. 1-9 ◽  
Author(s):  
Aslam Khan ◽  
Ahmed Mohamed El-Toni ◽  
Javed Alam ◽  
Ali Aldalbahi ◽  
Mukhtar Ahmed ◽  
...  

Herein, we report a simple and easy procedure for the synthesis of core-shell structures of glucose-sensitive 3-acrylamidophenylboronic acid (APBA) and temperature-responsive P(NIPAm-AAc) shell nanogel particles using MBA as a cross-linker via free radical polymerization. The synthesized particles were approximately 100 nm and were cross-linked to one another. The shell thickness of the nanogel particles was adjusted by increasing the concentrations of NIPAm through the semibath approach during the process of polymerization. The synthesized colloidal nanogel particle shows thermoresponsive behaviors. The dynamic light scattering technique also confirmed the change in the size of particles dispersed in an aqueous solution upon increase/decrease in temperatures, which is the result of its volume phase transition temperatures (VPTT). The size and morphology of the particles were characterized by TEM, FE-SEM, and AFM. The sensitivity of these nanogel particles to temperature and glucose suggests that they have the potential for applications related to the delivery of self-regulated insulin.


RSC Advances ◽  
2016 ◽  
Vol 6 (48) ◽  
pp. 41724-41733 ◽  
Author(s):  
Yi-Feng Cheng ◽  
Han Bi ◽  
Chao Wang ◽  
Qi Cao ◽  
Wenling Jiao ◽  
...  

A facile one-pot method has developed to assemble Cu/ZnO core/shell nanocrystals with different aspect ratios for enhanced microwave absorption. Besides, the one-pot method has shown the appreciable yields and no cumbersome multistep operations.


2015 ◽  
Vol 3 (15) ◽  
pp. 3517-3521 ◽  
Author(s):  
Xi-Long Qiu ◽  
Yue Zhou ◽  
Xiao-Yu Jin ◽  
Ai-Di Qi ◽  
Ying-Wei Yang

A facile one-step procedure for solvothermal synthesis of highly water-dispersible biocompatible magnetic Fe3O4 nanoparticles mediated by cucurbit[n]urils (CB[n]s) was presented.


2019 ◽  
Vol 5 (4) ◽  
pp. 61 ◽  
Author(s):  
Katz

Magnetic nanoparticles and magnetic nano-species of complex topology (e.g., nanorods, nanowires, nanotubes, etc.) are overviewed briefly in the paper, mostly giving attention to the synthetic details and particle composition (e.g., core-shell structures made of different materials). Some aspects related to applications of magnetic nano-species are briefly discussed. While not being a comprehensive review, the paper offers a large collection of references, particularly useful for newcomers in the research area.


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