scholarly journals Microencapsulated Comb-Like Polymeric Solid-Solid Phase Change Materials via In-Situ Polymerization

Polymers ◽  
2018 ◽  
Vol 10 (2) ◽  
pp. 172 ◽  
Author(s):  
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...  
Keyword(s):  
Phase Change ◽  
Phase Change Materials ◽  
In Situ Polymerization ◽  
Solid Phase ◽  
Polymeric Solid

Preparation and Characterization of Hexadecane Microcapsule Phase Change Materials by In Situ Polymerization

2013 ◽  
Vol 815 ◽  
pp. 367-370 ◽  
Author(s):  
Xiao Qiu Song ◽  
Yue Xia Li ◽  
Jing Wen Wang
Keyword(s):  
Particle Size ◽  
Phase Change ◽  
Phase Change Materials ◽  
In Situ Polymerization ◽  
Urea Formaldehyde ◽  
Agitation Speed ◽  
Urea Formaldehyde Resin ◽  
Formaldehyde Resin ◽  
Mass Ratio

Hexadecane microcapsule phase change materials were prepared by the in-situ polymerization method using hexadecane as core materials, urea-formaldehyde resin and urea-formaldehyde resin modified with melamine as shell materials respectively. Effect of melamine on the properties of microcapsules was studied by FTIR, biomicroscopy (UBM), TGA and HPLC. The influences of system concentration, agitation speed and mass ratio of wall to core were also investigated. The results indicated that hexadecane was successfully coated by the two types of shell materials. The addition of melamine into the urea-formaldehyde resin microcapsule reduced microcapsule particle size and microencapsulation efficiency. The influences of factors such as system concentration, agitation speed and mass ratio of wall to core to different wall materials microcapsules presented different variety trends of the microcapsule particle size.

Studies on the synthesis, characterization and application of a novel copolymer macromonomer for polymeric solidsolid phase change materials

e-Polymers ◽  
2008 ◽  
Vol 8 (1) ◽  
Author(s):  
Peng Xi ◽  
Xiao-hua Gu ◽  
Bowen Cheng
Keyword(s):  
Phase Change ◽  
Phase Change Material ◽  
Phase Change Materials ◽  
Solid Phase ◽  
The Novel ◽  
Structure And Properties ◽  
Crystal Properties ◽  
Polymeric Solid ◽  
Vinyl Group ◽  
Change Material

AbstractA novel copolymer as a macromonomer with a polyethylene glycol (PEG) unit as the phase change element and a vinyl group was synthesized for the preparation of polymeric solid-solid phase change materials. The IR, 1HNMR, DSC and WAXD and POM were employed to determine the structure and properties of the novel monomer. The results show that the novel monomer possess steady molecular structure, excellent crystal properties, higher phase change enthalpy and reactivity. Furthermore, the novel polymeric solid-solid phase change material was also prepared via the copolymerization of the novel copolymer macromonomer and styrene. The phase change properties of the polymeric solid-solid phase change material were characterized.

Phase Change Materials of Microcapsules Containing Paraffin

2012 ◽  
Vol 482-484 ◽  
pp. 1596-1599
Author(s):  
Dian Wu Huang ◽  
Hong Mei Wang
Keyword(s):  
Particle Size ◽  
Thermal Properties ◽  
Phase Change ◽  
Phase Change Materials ◽  
In Situ Polymerization ◽  
Core Material ◽  
Study Phase ◽  
Shell Material ◽  
Core Content

In this study, phase change microcapsules were prepared by in situ polymerization using paraffin as core material, poly(MMA -co- MAA) as shell material, Tween60/span60 as emulsifier. The surface morphology, thermal properties and particle size distribution of the prepared microcapsules were investigated by using SEM, TGA, DSC and ELS. The effects of paraffin core content and amount of emulsifier on the properties of microcapsules were studied.

Microstructure regulation of microencapsulated bio-based n-dodecanol as phase change materials via in situ polymerization

2017 ◽  
Vol 41 (23) ◽  
pp. 14696-14707 ◽  
Author(s):  
Hong Zhang ◽  
Wei Li ◽  
Rui Huang ◽  
Ning Wang ◽  
Jianping Wang ◽  
...  
Keyword(s):  
Phase Change ◽  
Phase Change Materials ◽  
In Situ Polymerization

Micronencapsulated bio-based n-dodcanol as phase change materials by in situ polymerization.

Preparation and Characterization of MicroPCMsContaining Paraffin

2012 ◽  
Vol 430-432 ◽  
pp. 647-650
Author(s):  
Dian Wu Huang ◽  
Yuan Lian ◽  
Hong Mei Wang
Keyword(s):  
Particle Size ◽  
Thermal Properties ◽  
Energy Storage ◽  
Phase Change ◽  
Phase Change Materials ◽  
In Situ Polymerization ◽  
Particle Size Analyzer ◽  
Good Potential

Microcapsules containing paraffin phase change materials with MMA-MAA copolymer shell were synthesised by in situ polymerization. The Structure, diameter, encapsulation ratio of paraffin and thermal properties of the prepared microcapsules were investigated by using FTIR, ELS particle size analyzer, differential scanning calorimeter (DSC), thermogravimetic analysis (TGA). This encapsulated phase change paraffin could have good potential for energy storage.

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