scholarly journals The Use of Click-Type Reactions in the Preparation of Thermosets

Polymers ◽  
2020 ◽  
Vol 12 (5) ◽  
pp. 1084
Author(s):  
Osman Konuray ◽  
Xavier Fernández-Francos ◽  
Silvia De la Flor ◽  
Xavier Ramis ◽  
Àngels Serra
Keyword(s):  
Click Chemistry ◽  
Network Formation ◽  
Polymer Networks ◽  
Click Reactions ◽  
Basic Concepts ◽  
Enhanced Properties ◽  
Polymerization Method ◽  
Advanced Applications

Click chemistry has emerged as an effective polymerization method to obtain thermosets with enhanced properties for advanced applications. In this article, commonly used click reactions have been reviewed, highlighting their advantages in obtaining homogeneous polymer networks. The basic concepts necessary to understand network formation via click reactions, together with their main characteristics, are explained comprehensively. Some of the advanced applications of thermosets obtained by this methodology are also reviewed.

scholarly journals Enhanced properties of well-defined polymer networks prepared by a sequential thiol-Michael - radical thiol-ene strategy (STMRT)

2021 ◽  
pp. 110440
Author(s):  
Sergio Cespedes ◽  
Rachel A. Hand ◽  
Nikola Chmel ◽  
Graeme Moad ◽  
Daniel J. Keddie ◽  
...  
Keyword(s):  
Polymer Networks ◽  
Enhanced Properties

CuAAC click reactions for the design of multifunctional luminescent ruthenium complexes

2016 ◽  
Vol 45 (6) ◽  
pp. 2338-2351 ◽  
Author(s):  
Natalia Zabarska ◽  
Anne Stumper ◽  
Sven Rau
Keyword(s):  
Click Chemistry ◽  
Ruthenium Complexes ◽  
Click Reactions ◽  
Versatile Tool ◽  
Potential Applicability

CuAAC (Cu(i) catalyzed azide–alkyne cycloaddition) click chemistry has emerged as a versatile tool in the development of photoactive ruthenium complexes with multilateral potential applicability. Three general concepts for their synthesis and selected applications are discussed.

Stoichiometric imbalance-promoted step-growth polymerization based on self-accelerating 1,3-dipolar cycloaddition click reactions

2020 ◽  
Vol 11 (1) ◽  
pp. 125-134 ◽  
Author(s):  
Xianfeng Liu ◽  
Lue Xiang ◽  
Jiayi Li ◽  
Ying Wu ◽  
Ke Zhang
Keyword(s):  
Dipolar Cycloaddition ◽  
Click Reactions ◽  
Step Growth ◽  
Step Growth Polymerization ◽  
Polymerization Method

A stoichiometric imbalance-promoted step growth polymerization method was developed based on self-accelerating 1,3-dipolar cycloaddition click reactions of Sondheimer diyne and varied 1,3-dipoles, such as diazo, sydnone, and nitrone groups.

scholarly journals Orthogonal click reactions enable the synthesis of ECM-mimetic PEG hydrogels without multi-arm precursors

2018 ◽  
Vol 6 (30) ◽  
pp. 4929-4936 ◽  
Author(s):  
Faraz Jivan ◽  
Natalia Fabela ◽  
Zachary Davis ◽  
Daniel L. Alge
Keyword(s):  
Tissue Engineering ◽  
Ethylene Glycol ◽  
Click Chemistry ◽  
Bioactive Peptides ◽  
Poly Ethylene Glycol ◽  
Click Reactions ◽  
Peg Hydrogels ◽  
Poly Ethylene

A two-step, click chemistry approach to create user-defined hydrogels consisting of poly(ethylene glycol) and bioactive peptides without the use of multi-arm precursors for tissue engineering.

scholarly journals Econometric Models of Network Formation

2020 ◽  
Vol 12 (1) ◽  
pp. 775-799 ◽  
Author(s):  
Áureo de Paula
Keyword(s):  
Statistical Models ◽  
Network Formation ◽  
Recent Literature ◽  
Theoretical Models ◽  
Econometric Models ◽  
Selective Review ◽  
Conditionally Specified Models ◽  
Basic Concepts ◽  
Further Development ◽  
Link Formation

This article provides a selective review of the recent literature on econometric models of network formation. I start with a brief exposition on basic concepts and tools for the statistical description of networks; then I offer a review of dyadic models, focusing on statistical models on pairs of nodes, and I describe several developments of interest to the econometrics literature. I also present a discussion of nondyadic models in which link formation might be influenced by the presence or absence of additional links, which themselves are subject to similar influences. This argument is related to the statistical literature on conditionally specified models and the econometrics of game theoretical models. I close with a (nonexhaustive) discussion of potential areas for further development.

Modular synthesis of glycopolymers with well-defined sugar units in the side chain via Ugi reaction and click chemistry: hetero vs. homo

2016 ◽  
Vol 7 (25) ◽  
pp. 4263-4271 ◽  
Author(s):  
Lulu Xue ◽  
Xinhong Xiong ◽  
Kui Chen ◽  
Yafei Luan ◽  
Gaojian Chen ◽  
...  
Keyword(s):  
Click Chemistry ◽  
Ugi Reaction ◽  
Side Chain ◽  
Click Reactions ◽  
Modular Synthesis

Modularized glycopolymers were prepared via Ugi and click reactions, and used as models to investigate their binding abilities.

scholarly journals Facile synthesis of novel hybrid POSS biomolecules via “Click” reactions

RSC Advances ◽  
2017 ◽  
Vol 7 (59) ◽  
pp. 37474-37477 ◽  
Author(s):  
Youssef El Aziz ◽  
Nazia Mehrban ◽  
Peter G. Taylor ◽  
Martin A. Birchall ◽  
James Bowen ◽  
...  
Keyword(s):  
Click Chemistry ◽  
High Yield ◽  
Facile Synthesis ◽  
Click Reactions

A novel alkyne-terminated cubic-octameric POSS was synthesised in high yield and click chemistry has been used to attach bio-oligomers.

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