scholarly journals Haze Optical Properties from Long-Term Ground-Based Remote Sensing over Beijing and Xuzhou, China

2018 ◽  
Vol 10 (4) ◽  
pp. 518 ◽  
Author(s):  
Kai Qin ◽  
Luyao Wang ◽  
Jian Xu ◽  
Husi Letu ◽  
Kefei Zhang ◽  
...  
Keyword(s):  
Optical Properties ◽  
Radiative Forcing ◽  
Fine Particles ◽  
Global Climate ◽  
Complex Refractive Index ◽  
Eastern China ◽  
Single Scattering ◽  
Dust Particles ◽  
Haze Pollution

Aerosol haze pollution has had a significant impact on both global climate and the regional air quality of Eastern China, which has a high proportion of high level pollution days. Statistical analyses of aerosol optical properties and direct radiative forcing at two AERONET sites (Beijing and Xuzhou) were conducted from 2013 to 2016. Results indicate: (1) Haze pollution days accounted for 26% and 20% of days from 2013 to 2016 in Beijing and Xuzhou, respectively, with the highest proportions in winter; (2) The averaged aerosol optical depth (AOD) at 550 nm on haze days were about 3.7 and 1.6 times greater than those on clean days in Beijing and Xuzhou, respectively. At both sites, the maximum AOD occurred in summer; (3) Hazes were dominated by fine particles at both sites. However, as compared to Xuzhou, Beijing had larger coarse mode AOD and higher percentage of small α. This data, together with an analysis of size distribution, suggests that the hazes in Beijing were more susceptible to coarse dust particles than Xuzhou; (4) During hazes in Beijing, the single scattering albedo (SSA) is significantly higher when compared to clean conditions (0.874 vs. 0.843 in SSA440 nm), an increase much less evident in Xuzhou. The most noticeable differences in both SSA and the imaginary part of the complex refractive index between Beijing and Xuzhou were found in winter; (5) In Beijing, the haze radiative forcing produced an averaged cooling effect of −113.6 ± 63.7 W/m2 at the surface, whereas the averaged heating effect of 77.5 ± 49.7 W/m2 within the atmosphere was at least twice as strong as clean days. In Xuzhou, such a radiative forcing effect appeared to be much smaller and the difference between haze and clean days was insignificant. Derived from long-term observation, these findings are more significant for the improvement of our understanding of haze formation in China and the assessment of its impacts on radiative forcing of climate change than previous short-term case studies.

scholarly journals A new approach for retrieving the UV–vis optical properties of ambient aerosols

2016 ◽  
Vol 9 (8) ◽  
pp. 3477-3490 ◽  
Author(s):  
Nir Bluvshtein ◽  
J. Michel Flores ◽  
Lior Segev ◽  
Yinon Rudich
Keyword(s):  
Optical Properties ◽  
Atmospheric Aerosols ◽  
Radiative Forcing ◽  
Complex Refractive Index ◽  
Single Scattering ◽  
Aerosol Size Distribution ◽  
Distribution Data ◽  
Ambient Aerosols ◽  
New Approach ◽  
Effective Radiative Forcing

Abstract. Atmospheric aerosols play an important part in the Earth's energy budget by scattering and absorbing incoming solar and outgoing terrestrial radiation. To quantify the effective radiative forcing due to aerosol–radiation interactions, researchers must obtain a detailed understanding of the spectrally dependent intensive and extensive optical properties of different aerosol types. Our new approach retrieves the optical coefficients and the single-scattering albedo of the total aerosol population over 300 to 650 nm wavelength, using extinction measurements from a broadband cavity-enhanced spectrometer at 315 to 345 nm and 390 to 420 nm, extinction and absorption measurements at 404 nm from a photoacoustic cell coupled to a cavity ring-down spectrometer, and scattering measurements from a three-wavelength integrating nephelometer. By combining these measurements with aerosol size distribution data, we retrieved the time- and wavelength-dependent effective complex refractive index of the aerosols. Retrieval simulations and laboratory measurements of brown carbon proxies showed low absolute errors and good agreement with expected and reported values. Finally, we implemented this new broadband method to achieve continuous spectral- and time-dependent monitoring of ambient aerosol population, including, for the first time, extinction measurements using cavity-enhanced spectrometry in the 315 to 345 nm UV range, in which significant light absorption may occur.

scholarly journals Optical properties of atmospheric fine particles near Beijing during the HOPE-J<sup>3</sup>A Campaign

2015 ◽  
Vol 15 (22) ◽  
pp. 33675-33730
Author(s):  
X. Xu ◽  
W. Zhao ◽  
Q. Zhang ◽  
S. Wang ◽  
B. Fang ◽  
...  
Keyword(s):  
Refractive Index ◽  
Optical Properties ◽  
Fine Particles ◽  
Complex Refractive Index ◽  
Single Scattering ◽  
Single Scattering Albedo ◽  
Organic Mass ◽  
Absorption Coefficients ◽  
Aerosol Composition ◽  
Inorganic Species

Abstract. The optical properties and chemical composition of PM1.0 (particulate with an aerodynamic diameter of less than 1.0 μm) particles in a suburban environment (Huairou) near the mega-city Beijing were measured during the HOPE-J3A (Haze Observation Project Especially for Jing-Jin-Ji Area) field campaign. The campaign covered the period November 2014 to January 2015 during the winter coal heating season. The average and standard deviations for the extinction, scattering, absorption coefficients, and the aerosol single scattering albedo (SSA) at λ = 470 nm during the measurement period were 201 ± 240, 164 ± 202, 37 ± 43 Mm-1, and 0.80 ± 0.08, respectively. The mean mass scattering (MSE) and absorption (MAE) efficiencies were 4.77 ± 0.01 and 0.87 ± 0.03 m2g-1, respectively. Highly time-resolved air pollution episodes clearly show the dramatic evolution of the PM1.0 size distribution, extensive optical properties (extinction, scattering, and absorption coefficients) and intensive optical properties (single scattering albedo and complex refractive index) during haze formation, development and decline. Time periods were classified into three different pollution levels (clear, slightly polluted, and polluted) for further analysis. It was found that: (1) The diurnal patterns of the aerosol extinction, scattering, absorption coefficients, and SSA differed for the three pollution classes. (2) The real and imaginary part of complex refractive index (CRI) increased, while the SSA decreased from clear to polluted days. (3) The relative contributions of organic and inorganic species to observed aerosol composition changed significantly from clear to polluted days: the organic mass fraction decreased (50 to 43 %) while the proportion of sulfates, nitrates, and ammonium increased strongly (34 to 44 %). (4) The fractional contribution of chemical components to extinction coefficients was calculated by using the modified IMPROVE algorithm. Organic mass was the largest contributor (58 %) to the total extinction of PM1.0. When the air quality deteriorated, the change of the relative contribution of sulfate aerosol to the total extinction was small, but the contribution of nitrate aerosol increased significantly (from 17 % on clear days to 23 % on polluted days). (5) The observed mass scattering efficiencies increased consistently with the pollution extent, however, the observed mass absorption efficiencies increased consistently with increasing mass concentration in slightly pollution conditions, but decreased under polluted conditions.

scholarly journals Aerosol optical properties and direct radiative effect over Gobabeb, Namibia

2019 ◽  
Vol 29 (2) ◽  
Author(s):  
Joseph A. Adesina ◽  
Stuart J. Piketh ◽  
Paola Formenti ◽  
Gillian Maggs-Kölling ◽  
Brent N. Holben ◽  
...  
Keyword(s):  
Optical Properties ◽  
Atmospheric Aerosols ◽  
Radiative Forcing ◽  
Fine Particles ◽  
Single Scattering ◽  
Columnar Water Vapor ◽  
Moderate Resolution ◽  
Resolution Imaging ◽  
Moderate Resolution Imaging Spectroradiometer ◽  
Visible Wavelengths

Atmospheric aerosols contribute significantly to the uncertainty in radiative forcing effects that influence the climate and pose a significant health risk to humans.   The climatic implications of aerosols are dependent on many variables, including aerosol size, shape, chemical composition, and position in the atmospheric column. The radiative impact of aerosols transported over the west coast of southern Africa has been found, in particular, to be complicated by the aforementioned aerosol properties.  This study investigated the columnar optical properties of aerosols over Gobabeb, Namibia (23.56oS, 15.04oE, 400 m asl) using sunphotometer data between December 2014 and November 2015. Aerosol mean optical depth AOD500 had its maximum and minimum values in 2015 August (0.37±0.30) and June (0.06±0.02), respectively. The Angström parameter was mostly above unity during the study period and indicated the prevalence of fine particles for the most part of the year with maximum and minimum values observed in August 2015 (1.44±0.19) and December 2014 (0.57±0.19), respectively. The columnar water vapor was highest in January (2.62±0.79) and lowest in June (0.76±0.27). The volume size distribution showed the fine particles having a mean radius of about 0.16 μm and the coarse mode had variation in sizes with a radius ranging between 3 μm and 7 μm. The single scattering albedo at visible wavelengths ranged between 0.87 and 0.88. The phase function was high at small angles but minimum at about 140o in all seasons. The radiative forcing showed a heating effect in all seasons with maximum and minimum in winter (9.41 Wm-2) and autumn (3.64 Wm-2), respectively. Intercomparison of the sunphotometer data with the Moderate Resolution Imaging Spectroradiometer (MODIS) showed that the satellite sensor overestimates the aerosol loading compared to the ground-based sunphotometer measurements. Both sets of observations were better correlated during the spring and winter seasons than for summer and autumn.

scholarly journals Optical properties of atmospheric fine particles near Beijing during the HOPE-J<sup>3</sup>A campaign

2016 ◽  
Vol 16 (10) ◽  
pp. 6421-6439 ◽  
Author(s):  
Xuezhe Xu ◽  
Weixiong Zhao ◽  
Qilei Zhang ◽  
Shuo Wang ◽  
Bo Fang ◽  
...  
Keyword(s):  
Optical Properties ◽  
Fine Particles ◽  
Complex Refractive Index ◽  
Single Scattering ◽  
Organic Mass ◽  
Absorption Coefficients ◽  
Aerosol Composition ◽  
Average Mass ◽  
Enhanced Absorption ◽  
Inorganic Species

Abstract. The optical properties and chemical composition of PM1.0 particles in a suburban environment (Huairou) near the megacity of Beijing were measured during the HOPE-J3A (Haze Observation Project Especially for Jing–Jin–Ji Area) field campaign. The campaign covered the period November 2014 to January 2015 during the winter coal heating season. The average values and standard deviations of the extinction, scattering, absorption coefficients, and the aerosol single scattering albedo (SSA) at λ  =  470 nm during the measurement period were 201 ± 240, 164 ± 202, 37 ± 43 Mm−1, and 0.80 ± 0.08, respectively. The average values for the real and imaginary components of the effective complex refractive index (CRI) over the campaign were 1.40 ± 0.06 and 0.03 ± 0.02, while the average mass scattering and absorption efficiencies (MSEs and MAEs) of PM1.0 were 3.6 and 0.7 m2 g−1, respectively. Highly time-resolved air pollution episodes clearly show the dramatic evolution of the PM1.0 size distribution, extensive optical properties (extinction, scattering, and absorption coefficients), and intensive optical properties (SSA and CRI) during haze formation, development, and decline. Time periods were classified into three different pollution levels (clear, slightly polluted, and polluted) for further analysis. It was found that (1) the relative contributions of organic and inorganic species to observed aerosol composition changed significantly from clear to polluted days: the organic mass fraction decreased from 50 to 43 % while the proportion of sulfates, nitrates, and ammonium increased strongly from 34 to 44 %. (2) Chemical apportionment of extinction, calculated using the IMPROVE algorithm, tended to underestimate the extinction compared to measurements. Agreement with measurements was improved by modifying the parameters to account for enhanced absorption by elemental carbon (EC). Organic mass was the largest contributor (52 %) to the total extinction of PM1.0, while EC, despite its low mass concentration of  ∼  4 %, contributed about 17 % to extinction. When the air quality deteriorated, the contribution of nitrate aerosol increased significantly (from 15 % on clear days to 22 % on polluted days). (3) Under polluted conditions, the average MAEs of EC were up to 4 times as large as the reference MAE value for freshly generated black carbon (BC). The temporal pattern of MAE values was similar to that of the OC / EC ratio, suggesting that non-BC absorption from secondary organic aerosol also contributes to particle absorption.

scholarly journals A new approach for measuring the UV-Vis optical properties of ambient aerosols

2016 ◽  
Author(s):  
Nir Bluvshtein ◽  
J. Michel Flores ◽  
Lior Segev ◽  
Yinon Rudich
Keyword(s):  
Optical Properties ◽  
Atmospheric Aerosols ◽  
Radiative Forcing ◽  
Complex Refractive Index ◽  
Single Scattering ◽  
Aerosol Size Distribution ◽  
Distribution Data ◽  
Ambient Aerosols ◽  
New Approach ◽  
Effective Radiative Forcing

Abstract. Atmospheric aerosols play an important part in the Earth's energy budget by scattering and absorbing incoming solar and outgoing terrestrial radiation. To quantify the effective radiative forcing due to aerosol–radiation interactions, researchers must obtain a detailed understanding of the spectrally dependent intensive and extensive optical properties of different aerosol types. Our new approach obtains the optical coefficients and the single scattering albedo of the total aerosol population over 300–650 nm wavelength, using a broadband cavity-enhanced spectrometer (extinction), a photoacoustic cell coupled to a cavity ring down spectrometer (extinction and absorption), and a nephelometer (scattering). Combining these coefficients with aerosol size distribution data, we retrieved the time- and wavelength-dependent effective complex refractive index of the aerosols. Retrieval simulations and laboratory measurements of brown carbon proxies showed low absolute errors and good agreement with expected and reported values. Finally, we utilized our new broadband method to achieve continuous spectral and time-dependent monitoring of an ambient polydisperse aerosols population, including, for the first time, extinction measurements using cavity enhanced spectrometry in the 315 to 345 nm UV range, in which significant light absorption may occur.

scholarly journals Ground-Based Remote Sensing of Aerosol Properties over a Coastal Megacity of Pakistan

2018 ◽  
Vol 2018 ◽  
pp. 1-12
Author(s):  
Salman Tariq ◽  
Zia Ul-Haq
Keyword(s):  
Atmospheric Aerosols ◽  
Global Climate ◽  
Single Scattering ◽  
Dust Particles ◽  
Fine Mode ◽  
Autumn And Winter ◽  
Coastal Megacity ◽  
Aerosol Properties ◽  
Peak Value

Atmospheric aerosols are considered to be an important constituent of Earth’s atmosphere because of their climatic, environmental, and health effects. Therefore, while studying the global climate change, investigation of aerosol concentrations and properties is essential both at local and regional levels. In this paper, we have used relatively long-term Aerosol Robotic Network (AERONET) data during September 2006–August 2014 to analyze aerosol properties such as aerosol optical depth at 500 nm (AOD), Ångström exponent (440–870 nm) (AE), refractive index (RI), and asymmetry parameter over Karachi, a coastal megacity of Pakistan. The average annual values of AOD and AE were found to be 0.48 ± 0.20 and 0.59 ± 0.29, respectively. The peak (0.88 ± 0.31) AOD was recorded in July with corresponding AE of 0.30 ± 0.22 representing reasonably higher concentration of coarse size particles over Karachi. The cluster analysis using the scatter plot between absorption AE and extinction AE revealed that desert dust prevailed in the atmosphere of Karachi in spring and summer, while biomass burning aerosols dominate in autumn and winter. The peak values of volume concentrations of coarse and fine-mode particulate matter were found in summer and autumn, respectively. Also, we found significant growing trend in single-scattering albedo with wavelength, indicating the domination of dust particles during summer and spring. The peak value of the real part of the RI was observed in spring (1.53) and modest in winter (1.50). On the contrary, the peak value of the imaginary part of the RI was observed to be constantly elevated in winter and lesser in spring.

scholarly journals Does afforestation deteriorate haze pollution in Beijing–Tianjin–Hebei (BTH), China?

2018 ◽  
Author(s):  
Xin Long ◽  
Naifang Bei ◽  
Jiarui Wu ◽  
Xia Li ◽  
Tian Feng ◽  
...  
Keyword(s):  
Forest Cover ◽  
Fine Particles ◽  
Control Strategies ◽  
Surface Wind ◽  
Forecast Model ◽  
Surface Wind Speed ◽  
Satellite Measurements ◽  
Haze Pollution ◽  
The Impact

Abstract. Although aggressive emission control strategies have been implemented recently in the Beijing–Tianjin–Hebei area (BTH), China, pervasive and persistent haze still frequently engulfs the region during wintertime. Afforestation in BTH, primarily concentrated in the Taihang and Yanshan Mountains, has constituted one of the controversial factors exacerbating the haze pollution due to its slowdown of the surface wind speed. We report here an increasing trend of forest cover in BTH during 2001–2013 based on long-term satellite measurements and the impact of the afforestation on the fine particles (PM2.5) level. Simulations using the Weather Research and Forecast model with chemistry reveal that the afforestation in BTH since 2001 generally deteriorates the haze pollution in BTH to some degree, enhancing PM2.5 concentrations by up to 6 % on average. Complete afforestation or deforestation in the Taihang and Yanshan Mountains would increase or decrease the PM2.5 level within 15 % in BTH. Our model results also suggest that implementing a large ventilation corridor system would not be effective or beneficial to mitigate the haze pollution in Beijing.

scholarly journals Multicentury Changes to the Global Climate and Carbon Cycle: Results from a Coupled Climate and Carbon Cycle Model

2005 ◽  
Vol 18 (21) ◽  
pp. 4531-4544 ◽  
Author(s):  
G. Bala ◽  
K. Caldeira ◽  
A. Mirin ◽  
M. Wickett ◽  
C. Delire
Keyword(s):  
Carbon Cycle ◽  
Radiative Forcing ◽  
Fossil Fuel ◽  
Global Climate ◽  
Second Century ◽  
Cycle Model ◽  
Carbon Cycle Model ◽  
Living Biomass ◽  
Long Term Consequences

Abstract A coupled climate and carbon (CO2) cycle model is used to investigate the global climate and carbon cycle changes out to the year 2300 that would occur if CO2 emissions from all the currently estimated fossil fuel resources were released to the atmosphere. By the year 2300, the global climate warms by about 8 K and atmospheric CO2 reaches 1423 ppmv. The warming is higher than anticipated because the sensitivity to radiative forcing increases as the simulation progresses. In this simulation, the rate of emissions peaks at over 30 Pg C yr−1 early in the twenty-second century. Even at the year 2300, nearly 50% of cumulative emissions remain in the atmosphere. Both soils and living biomass are net carbon sinks throughout the simulation. Despite having relatively low climate sensitivity and strong carbon uptake by the land biosphere, these model projections suggest severe long-term consequences for global climate if all the fossil fuel carbon is ultimately released into the atmosphere.

scholarly journals Atmospheric radiative effects of an in-situ measured Saharan dust plume and the role of large particles

2007 ◽  
Vol 7 (3) ◽  
pp. 7767-7817 ◽  
Author(s):  
S. Otto ◽  
M. de Reus ◽  
T. Trautmann ◽  
A. Thomas ◽  
M. Wendisch ◽  
...  
Keyword(s):  
Complex Refractive Index ◽  
Single Scattering ◽  
Single Scattering Albedo ◽  
Saharan Dust ◽  
Dust Particles ◽  
Modal Parameters ◽  
Size Distributions ◽  
Radiative Effects ◽  
Enhanced Absorption ◽  
Large Particles

Abstract. This work will present aerosol size distributions measured in a Saharan dust plume between 0.9 and 12 km altitude during the ACE-2 campaign 1997. The distributions contain a significant fraction of large particles of diameters from 4 to 30 μm. Radiative transfer calculations have been performed using these data as input. Shortwave, longwave as well as total atmospheric radiative effects (AREs) of the dust plume are investigated over ocean and desert within the scope of sensitivity studies considering varied input parameters like solar zenith angle, scaled total dust optical depth, tropospheric standard aerosol profiles and particle complex refractive index. The results indicate that the large particle fraction has a predominant impact on the optical properties of the dust. A single scattering albedo of ωo=0.75–0.96 at 550 nm was simulated in the entire dust column as well as 0.76 within the Saharan dust layer at ~4 km altitude indicating enhanced absorption. The measured dust leads to cooling over the ocean but warming over the desert due to differences in their spectral surface albedo and surface temperature. The large particles absorb strongly and they contribute at least 20% to the ARE in the dusty atmosphere. From the measured size distributions modal parameters of a bimodal lognormal column volume size distribution were deduced, resulting in a coarse median diameter of ~9 μm and a column single scattering albedo of 0.78 at 550 nm. A sensitivity study demonstrates that variabilities in the modal parameters can cause completely different AREs and emphasises the warming effect of the large mineral dust particles.

scholarly journals Intercomparison of biomass burning aerosol optical properties from in situ and remote-sensing instruments in ORACLES-2016

2019 ◽  
Vol 19 (14) ◽  
pp. 9181-9208 ◽  
Author(s):  
Kristina Pistone ◽  
Jens Redemann ◽  
Sarah Doherty ◽  
Paquita Zuidema ◽  
Sharon Burton ◽  
...  
Keyword(s):  
Optical Properties ◽  
Case Studies ◽  
Biomass Burning ◽  
Radiative Forcing ◽  
Measurement Techniques ◽  
Single Scattering ◽  
Single Scattering Albedo ◽  
Aerosol Optical Properties ◽  
Biomass Burning Aerosol

Abstract. The total effect of aerosols, both directly and on cloud properties, remains the biggest source of uncertainty in anthropogenic radiative forcing on the climate. Correct characterization of intensive aerosol optical properties, particularly in conditions where absorbing aerosol is present, is a crucial factor in quantifying these effects. The southeast Atlantic Ocean (SEA), with seasonal biomass burning smoke plumes overlying and mixing with a persistent stratocumulus cloud deck, offers an excellent natural laboratory to make the observations necessary to understand the complexities of aerosol–cloud–radiation interactions. The first field deployment of the NASA ORACLES (ObseRvations of Aerosols above CLouds and their intEractionS) campaign was conducted in September of 2016 out of Walvis Bay, Namibia. Data collected during ORACLES-2016 are used to derive aerosol properties from an unprecedented number of simultaneous measurement techniques over this region. Here, we present results from six of the eight independent instruments or instrument combinations, all applied to measure or retrieve aerosol absorption and single-scattering albedo. Most but not all of the biomass burning aerosol was located in the free troposphere, in relative humidities typically ranging up to 60 %. We present the single-scattering albedo (SSA), absorbing and total aerosol optical depth (AAOD and AOD), and absorption, scattering, and extinction Ångström exponents (AAE, SAE, and EAE, respectively) for specific case studies looking at near-coincident and near-colocated measurements from multiple instruments, and SSAs for the broader campaign average over the month-long deployment. For the case studies, we find that SSA agrees within the measurement uncertainties between multiple instruments, though, over all cases, there is no strong correlation between values reported by one instrument and another. We also find that agreement between the instruments is more robust at higher aerosol loading (AOD400>0.4). The campaign-wide average and range shows differences in the values measured by each instrument. We find the ORACLES-2016 campaign-average SSA at 500 nm (SSA500) to be between 0.85 and 0.88, depending on the instrument considered (4STAR, AirMSPI, or in situ measurements), with the interquartile ranges for all instruments between 0.83 and 0.89. This is consistent with previous September values reported over the region (between 0.84 and 0.90 for SSA at 550nm). The results suggest that the differences observed in the campaign-average values may be dominated by instrument-specific spatial sampling differences and the natural physical variability in aerosol conditions over the SEA, rather than fundamental methodological differences.

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