Measurement report: Long-term changes in black carbon and aerosol optical properties from 2012 to 2020 in Beijing, China

Atmospheric aerosols play an important role in the radiation balance of the earth–atmosphere system. However, our knowledge of the long-term changes in equivalent black carbon (eBC) and aerosol optical properties in China is very limited. Here we analyze the 9-year measurements of eBC and aerosol optical properties from 2012 to 2020 in Beijing, China. Our results showed large reductions in eBC by 71 % from 6.25 ± 5.73 µg m−3 in 2012 to 1.80 ± 1.54 µg m−3 in 2020 and 47 % decreases in the light extinction coefficient (bext, λ = 630 nm) of fine particles due to the Clean Air Action Plan that was implemented in 2013. The seasonal and diurnal variations of eBC illustrated the most significant reductions in the fall and at nighttime, respectively. ΔeBC / ΔCO also showed an annual decrease from ∼ 7 to 4 ng m−3 ppbv−1 and presented strong seasonal variations with high values in spring and fall, indicating that primary emissions in Beijing have changed significantly. As a response to the Clean Air Action Plan, single-scattering albedo (SSA) showed a considerable increase from 0.79 ± 0.11 to 0.88 ± 0.06, and mass extinction efficiency (MEE) increased from 3.2 to 3.8 m2 g−1. These results highlight the increasing importance of scattering aerosols in radiative forcing and a future challenge in visibility improvement due to enhanced MEE. Brown carbon (BrC) showed similar changes and seasonal variations to eBC during 2018–2020. However, we found a large increase of secondary BrC in the total BrC in most seasons, particularly in summer with the contribution up to 50 %, demonstrating an enhanced role of secondary formation in BrC in recent years. The long-term changes in eBC and BrC have also affected the radiative forcing effect. The direct radiative forcing (ΔFR) of BC decreased by 67 % from +3.36 W m−2 in 2012 to +1.09 W m−2 in 2020, and that of BrC decreased from +0.30 to +0.17 W m−2 during 2018–2020. Such changes might have important implications for affecting aerosol–boundary layer interactions and the improvement of future air quality.

Long-term Variation of Absorption and Total Aerosol Optical Properties over Typical Provinces of China from Satellite Observations

Increase of atmospheric aerosols has a profound impact on the Earth’s climate. It’s also one of the crucial factors that cuasesd more fequent air pollution events in China. Monthly average Aerosol Optical Depth (AOD) from MODIS and UltraViolet Absorbing aerosol Index (UVAI) from OMI during 2011 to 2019 are used to analyse the trend of absorption and total aerosol optical properties over three typical provinces of China, namely Shandong, Gansu and Guangdong provinces. The results show the average annual AOD of the three provinces are all decreasing while UVAI rises during this period. In addition, the monthly variation of AOD and UVAI are also obviously different over these provinces. In particular, the peak value of AOD appeared in July and the trough appeared in December over Shandong Province. And the peak appeared in April over Gansu Province, but AOD decrease slower then over Shandong Province. And there were two peaks in April and August over Guangdong Province. For UVAI, the peaks over Shandong and Gansu provinces both occur in January, while that over Guangdong Province appears in March. Above mentioned differences in the long-term trend and monthly variation of AOD and UVAI might be closely related to the meteorological conditions and aerosol emission of these three provinces.

Mobile on-Road Measurements of Aerosol Optical Properties during MOABAI Campaign in the North China Plain

We present the mapping at fine spatial scale of aerosol optical properties using a mobile laboratory equipped with LIDAR (Light Detection And Ranging), sun photometer and in situ instruments for performing on-road measurements. The mobile campaign was conducted from 9 May to 19 May 2017 and had the main objective of mapping the distribution of pollutants in the Beijing and North China Plain (NCP) region. The highest AOD (Aerosol Optical Depth) at 440 nm of 1.34 and 1.9 were recorded during two heavy pollution episodes on 18 May and 19 May 2017, respectively. The lowest Planetary Boundary Layer (PBL) heights (0.5–1.5 km) were recorded during the heavy pollution events, correlating with the highest AOD and southern winds. The transport of desert dust from the Gobi Desert was captured during the mobile measurements, impacting Beijing during 9–13 May 2017. Exploring the NCP outside Beijing provided datasets for regions with scarce ground measurements and allowed the mapping of high aerosol concentrations when passing polluted cities in the NCP (Baoding, Tianjin and Tangshan) and along the Binhai New Area. For the first time, we provide mass concentration profiles from the synergy of LIDAR, sun photometer and in situ measurements. The case study along the Binhai New Area revealed mean extinction coefficients of 0.14 ± 0.10 km−1 at 532 nm and a mass concentration of 80 ± 62 μg/m3 in the PBL (<2 km). The highest extinction (0.56 km−1) and mass concentrations (404 μg/m3) were found in the industrial Binhai New Area. The PM10 and PM2.5 fractions of the total mass concentration profiles were separated using the columnar size distribution, derived from the sun photometer measurements. This study offers unique mobile datasets of the aerosol optical properties in the NCP for future applications, such as satellite validation and air quality studies.

Impact of particle size, refractive index, and shape on the determination of the particle scattering coefficient – an optical closure study evaluating different nephelometer angular truncation and illumination corrections

Aerosol particles in the atmosphere interact with solar radiation through scattering and absorption. Accurate aerosol optical properties are needed to reduce the uncertainties of climate predictions. The aerosol optical properties can be obtained via optical modeling based on the measured particle size distribution. This approach requires knowledge or assumptions on the particle refractive index and shape. Meanwhile, integrating nephelometry provides information on the aerosol scattering properties directly. However, their measurements are affected by angular non-idealities, and their data need to be corrected for angular truncation and illumination to provide the particle scattering coefficient. We performed an extensive closure study, including a laboratory and a simulated experiment, aiming to compare different nephelometer angular truncation and illumination corrections (further referred to as "angular corrections"). We focused on coarse mode irregularly shaped aerosols, such as mineral dust, a worldwide abundant aerosol component. The angular correction of irregular particles is found to be only ~2 % higher than the angular correction of volume equivalent spheres. If the angular correction is calculated with Mie theory, the particle size distribution is needed. Our calculations show that if the particle size distribution is retrieved from optical particle spectrometer measurements and the irregular shape effect is not considered, the angular correction can be overestimated by about 5 % and up to 22 %. For mineral dust, the traditional angular correction based on the wavelength dependency of the scattering coefficient seems more accurate. We propose a guideline to establish the most appropriate angular correction depending on the aerosol type and the investigated size range.

Comparative assessment of aerosol optical properties over a mega city and an adjacent urban area in India

The present work revolves around the comparative analysis of aerosol optical properties in a mega city, Delhi and in a nearby urban area, Rohtak. It is pertinent to note that despite of the close proximity and similar meteorological conditions, the two study locations show significant differences in aerosol characteristics. The study is conducted using ground based Sky-radiometer measurements for a period of one year. The mean annual Aerosol Optical Depth (AOD) at 500 nm over Delhi and Rohtak is observed to be 1.01 and 0.73 respectively, with correlation coefficient of 0.67 and mean absolute difference of 0.51. The magnitude of AOD in Delhi is higher than in Rohtak throughout the year, except in post-monsoon season. The difference in Angstrom exponent (alpha) between the stations is minimal. However, lower magnitude of alpha is observed in Rohtak, indicating presence of more concentration of coarse-mode particles. Single Scattering Albedo (SSA) also shows seasonal variation with significantly lower values in Delhi throughout the year, indicating contribution of absorbing type of aerosols (like black carbon). The volume concentration in fine-size is found to be higher in Delhi than in Rohtak, indicating combined effect of dust, vehicular, biomass burning and industrial emissions. The aerosol classification via relationship between AOD and alpha shows that urban/biomass burning (U/B) aerosols are dominant in Delhi and mixed type (MT) aerosols in Rohtak during winter and pre-monsoon.

A Decade of Poland-AOD Aerosol Research Network Observations

The Poland-AOD aerosol research network was established in 2011 to improve aerosol–climate interaction knowledge and provide a real-time and historical, comprehensive, and quantitative database for the aerosol optical properties distribution over Poland. The network consists of research institutions and private owners operating 10 measurement stations and an organization responsible for aerosol model transport simulations. Poland-AOD collaboration provides observations of spectral aerosol optical depth (AOD), Ångstrom Exponent (AE), incoming shortwave (SW) and longwave (LW) radiation fluxes, vertical profiles of aerosol optical properties and surface aerosol scattering and absorption coefficient, as well as microphysical particle properties. Based on the radiative transfer model (RTM), the aerosol radiative forcing (ARF) and the heating rate are simulated. In addition, results from GEM-AQ and WRF-Chem models (e.g., aerosol mass mixing ratio and optical properties for several particle chemical components), and HYSPLIT back-trajectories are used to interpret the results of observation and to describe the 3D aerosol optical properties distribution. Results of Poland-AOD research indicate progressive improvement of air quality and atmospheric turbidity during the last decade. The AOD was reduced by about 0.02/10 yr (at 550 nm), which corresponds to positive trends in ARF. The estimated clear-sky ARF trend is 0.34 W/m2/10yr and 0.68 W/m2/10yr, respectively, at TOA and at Earth’s surface. Therefore, reduction in aerosol load observed in Poland can significantly contribute to climate warming.