scholarly journals Electrochemically Reduced Graphene Oxide-Based Screen-Printed Electrodes for Total Tetracycline Determination by Adsorptive Transfer Stripping Differential Pulse Voltammetry

Sensors ◽  
2019 ◽  
Vol 20 (1) ◽  
pp. 76 ◽  
Author(s):  
Anabela S. Lorenzetti ◽  
Tania Sierra ◽  
Claudia E. Domini ◽  
Adriana G. Lista ◽  
Agustin G. Crevillen ◽  
...  
Keyword(s):  
Graphene Oxide ◽  
Differential Pulse Voltammetry ◽  
Reduced Graphene Oxide ◽  
Selective Adsorption ◽  
Differential Pulse ◽  
Screen Printed Electrodes ◽  
Reduced Graphene ◽  
Electrochemically Reduced Graphene Oxide ◽  
Pulse Voltammetry ◽  
Screen Printed

Disposable electrochemically reduced graphene oxide-based (ERGO) screen-printed electrodes (SPE) were developed for the determination of total tetracyclines as a sample screening approach. To this end, a selective adsorption-detection approach relied on adsorptive transfer stripping differential pulse voltammetry (AdTDPV) was devised, where the high adsorption capacity and the electrochemical properties of ERGO were simultaneously exploited. The approach was very simple, fast (6 min.), highly selective by combining the adsorptive and the electrochemical features of tetracyclines, and it used just 10 μL of the sample. The electrochemical sensor applicability was demonstrated in the analysis of environmental and food samples. The not-fully explored AdTDPV analytical possibilities on disposable nanostructured transducers become a new tool in food and environmental fields; drawing new horizons for “in-situ” analysis.

Potentiometric Taste Sensing Using Reduced Graphene Oxide Screen Printed Electrodes

2020 ◽  
Vol 18 (12) ◽  
pp. 881-888
Author(s):  
Anil B. Patil ◽  
Umesh. J. Tupe ◽  
Vikas V. Deshmane ◽  
Arun V. Patil
Keyword(s):  
Graphene Oxide ◽  
Reduced Graphene Oxide ◽  
Principal Component ◽  
Experimental Results ◽  
Statistical Tool ◽  
Sensing Applications ◽  
Screen Printed Electrodes ◽  
Reduced Graphene ◽  
Pharmaceutical Industries ◽  
Screen Printed

This paper reports the development of simple and economical reduced graphene oxide (rGO) based screen-printed electrodes (SPE) for five basic taste sensing applications. Twenty different test solutions for the five tastes of salty, sour, sweet, umami, and bitter at 1 ppm, 10 ppm, 100 ppm, 1000 ppm concentration levels were tested with the fabricated SPEs. From experimental results, electrical signals generated between the electrode and test solution interface were measured using the potentiometric method. Satisfactory potentiometric responses of SPEs to different ppm concentrations for each sample were used to analyze the sample data. Histogram using the statistical tool was used to analyze the changes in the conductivity response. A multivariate Principal Component Analysis (PCA) statistical tool correlated using loading plots between variables and factors of all the five basic tastes. The plot showed the interrelation between variables and test samples. The obtained experimental results from these rGO based SPEs make them suitable for their use in taste sensing applications such as for any taste disorder disability, food-producing industry, pharmaceutical industries, etc.

scholarly journals A label-free biosensor based on graphene and reduced graphene oxide dual-layer for electrochemical determination of beta-amyloid biomarkers

2020 ◽  
Vol 187 (5) ◽  
Author(s):  
Jagriti Sethi ◽  
Michiel Van Bulck ◽  
Ahmed Suhail ◽  
Mina Safarzadeh ◽  
Ana Perez-Castillo ◽  
...  
Keyword(s):  
Graphene Oxide ◽  
Reduced Graphene Oxide ◽  
Limit Of Detection ◽  
Electrochemical Techniques ◽  
Differential Pulse ◽  
Electrochemical Determination ◽  
Label Free ◽  
Reduced Graphene ◽  
Electrochemically Reduced Graphene Oxide

AbstractA label-free biosensor is developed for the determination of plasma-based Aβ1–42 biomarker in Alzheimer’s disease (AD). The platform is based on highly conductive dual-layer of graphene and electrochemically reduced graphene oxide (rGO). The modification of dual-layer with 1-pyrenebutyric acid N-hydroxysuccinimide ester (Pyr-NHS) is achieved to facilitate immobilization of H31L21 antibody. The effect of these modifications were studied with morphological, spectral and electrochemical techniques. The response of the biosensor was evaluated using differential pulse voltammetry (DPV). The data was acquired at a working potential of ~ 180 mV and a scan rate of 50 mV s−1. A low limit of detection (LOD) of 2.398 pM is achieved over a wide linear range from 11 pM to 55 nM. The biosensor exhibits excellent specificity over Aβ1–40 and ApoE ε4 interfering species. Thus, it provides a viable tool for electrochemical determination of Aβ1–42. Spiked human and mice plasmas were used for the successful validation of the sensing platform in bio-fluidic samples. The results obtained from mice plasma analysis concurred with the immunohistochemistry (IHC) and magnetic resonance imaging (MRI) data obtained from brain analysis.

scholarly journals Reduced Graphene Oxide Carbon Yarn Electrodes for Drug Sensing

2021 ◽  
Vol 2 ◽  
Author(s):  
Sutthima Sriprasertsuk ◽  
Shuai Zhang ◽  
Gordon Wallace ◽  
Jun Chen ◽  
John R. Varcoe ◽  
...  
Keyword(s):  
Graphene Oxide ◽  
Detection Limit ◽  
Carbon Fibre ◽  
Reduced Graphene Oxide ◽  
Simultaneous Detection ◽  
Differential Pulse ◽  
Reduced Graphene ◽  
Electrochemically Deposited ◽  
Pulse Voltammetry

A modified carbon fibre yarn sensor was developed for the voltammetric determination of paracetamol and its interferents (dopamine and ascorbic acid). Reduced graphene oxide (rGO) was electrochemically deposited onto a carbon fibre yarn. Further modification was achieved using polypyrrole (PPy) coated onto the rGO carbon fibre yarn via electropolymerisation of pyrrole with cyclic voltammetry (CV). The surface of the rGO and PPy-rGO carbon fibre electrodes were characterised using Raman spectroscopy and scanning electron microscopy. The rGO and PPy-rGO carbon fibres had a 3.5-fold and 7-fold larger electrochemical surface area compared to bare carbon fibre (calculated using the Randles-Sevcik equation). Two clearly distinguished oxidation peaks at 0.49 and 0.25 V (vs. Ag/AgCl) were observed at the rGO fibre electrode during the simultaneous detection of paracetamol and dopamine, respectively, by CV. The detection limit (3σ S/N) of the rGO carbon fibre electrode for differential pulse voltammetry (DPV) determination of paracetamol was at 21.1 and 6.0 µM for dopamine. In comparison, the simultaneous determination of paracetamol and dopamine by CV at the PPy-rGO fibre electrode gave oxidation peaks of paracetamol and dopamine at 0.55 and 0.25 V (vs. Ag/AgCl), respectively. The detection limit (3σ S/N) for paracetamol was notably improved to 3.7 µM and maintained at 6.0 µM for dopamine at the PPy-rGO carbon fibre electrode during DPV.

scholarly journals Applications of Graphene-Based Materials in Sensors

Sensors ◽  
2020 ◽  
Vol 20 (11) ◽  
pp. 3196
Author(s):  
Miguel Hernaez
Keyword(s):  
Quantum Dots ◽  
Graphene Oxide ◽  
Reduced Graphene Oxide ◽  
Gas Sensors ◽  
Graphene Quantum Dots ◽  
Special Issue ◽  
Mass Sensors ◽  
Screen Printed Electrodes ◽  
Reduced Graphene ◽  
Screen Printed

This Special Issue compiles a set of innovative developments on the use of graphene-based materials in the fabrication of sensors. In particular, these contributions report original studies on a wide variety of sensors, such as gas sensors for NO2 or NH3 detection, antibody biosensors or mass sensors. All these devices have one point in common: they have been built using graphene-based materials like graphene, graphene oxide, reduced graphene oxide, inkject printing graphene, graphene-based composite sponges, graphene screen-printed electrodes or graphene quantum dots.

scholarly journals Amperometric L-Lactate Biosensor Based upon a Gold Nanoparticles/Reduced Graphene Oxide/Polyallylamine Hydrochloride Modified Screen-Printed Graphite Electrode

Chemosensors ◽  
2021 ◽  
Vol 9 (4) ◽  
pp. 74
Author(s):  
Oana-Maria Istrate ◽  
Lucian Rotariu ◽  
Camelia Bala
Keyword(s):  
Gold Nanoparticles ◽  
Graphene Oxide ◽  
Lactic Acid ◽  
Reduced Graphene Oxide ◽  
Long Term Stability ◽  
Reduced Graphene ◽  
Electrochemically Reduced Graphene Oxide ◽  
Dehydrogenase Enzyme ◽  
Polyallylamine Hydrochloride ◽  
Screen Printed

This work describes a novel L-lactate biosensor based on the immobilization of L-lactate dehydrogenase enzyme on the screen-printed electrode modified with a ternary composite based on gold nanoparticles, electrochemically-reduced graphene oxide, and poly (allylamine hydrochloride). The enzyme was stabilized by crosslinking with glutaraldehyde. Applied working potential, pH and NAD+ concentration were optimized. The biosensor reports a specific sensitivity of 1.08 µA/mM·cm2 in a range up to 3 mM L-lactic acid with a detection limit of 1 µM. The operational and long-term stability as well as good selectivity allowed the L-lactic acid measurement in dairy products and wine samples.

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