Water vapor infiltration into multi-layer ceramic capacitors under highly accelerated temperature and humidity stress tests

Author(s):  
Yoshito Saito ◽  
Toshimi Oguni ◽  
Tomoyuki Nakamura ◽  
Kenichi Nada ◽  
Harunobu Sano ◽  
...  
Author(s):  
Jaesu Han ◽  
Dongjin Yu ◽  
Sangseok Yu

Abstract Proton Exchange Membrane Fuel Cell (PEMFC) has advantages that other energy sources don’t have, and recently, it has been spotlighted in many industries such as transportation and power generation. However, although much research has been conducted on PEMFC, studies on operating conditions of bipolar plates in cells have been insufficient. Most of the studies that have been conducted so far are obtained by setting a few points on the edge or the latter line of the bipolar plate when acquiring data such as the operating temperature or relative humidity of the cell, so the research is extremely limited. In order to maximize the performance of PEMFC and preserve its durability, it is very important to control operating temperature and humidity optimally. Typically, water contents inside membrane electrolyte is determined by externally delivered water vapor and electrically reacted water vapor. Since water vapor is delivered and exhausted through bipolar plate, the vapor concentration in the bipolar plate is a clue to understand operating characteristics of PEMFC. Even though vapor concentration is a key to improve the performance, it is very difficult to measure direct distribution on the membrane electrode assembly. Therefore, this study attempted to observe the behavior of vapor flow inside the bipolar plate. By mounting several sensors in the flow path of the bipolar plate, it is possible to measure the temperature and humidity field data in the flow path, so that it is possible to observe the actual operating environment in the stack under various operating conditions and to establish a control strategy. Especially, this approach not only makes it possible to analyze the static water content in a steady state where no change in load occurs, but also enables dynamic observation of transient characteristics in the flow path when the current density changes. Several temperature and humidity sensors were installed on the bipolar plates of the cathode and anode respectively, and reliability and performance evaluations were performed through experiments. Reliability was evaluated by setting up a relatively accurate comparison sensor among the existing sensors that were not used in this study, and analyzed the effects of flow disturbance in the flow path by comparing with the polarization curve in the general cell. After the sensor calibration, an experiment was performed to obtain temperature and humidity data as the current density changed. As a result, it was possible to quantitatively analyze the water content delivered from the outside or generated inside the stack.


2011 ◽  
Vol 11 (19) ◽  
pp. 10127-10148 ◽  
Author(s):  
A. Solomon ◽  
M. D. Shupe ◽  
P. O. G. Persson ◽  
H. Morrison

Abstract. Observations suggest that processes maintaining subtropical and Arctic stratocumulus differ, due to the different environments in which they occur. For example, specific humidity inversions (specific humidity increasing with height) are frequently observed to occur near cloud top coincident with temperature inversions in the Arctic, while they do not occur in the subtropics. In this study we use nested LES simulations of decoupled Arctic Mixed-Phase Stratocumulus (AMPS) clouds observed during the DOE Atmospheric Radiation Measurement Program's Indirect and SemiDirect Aerosol Campaign (ISDAC) to analyze budgets of water components, potential temperature, and turbulent kinetic energy. These analyses quantify the processes that maintain decoupled AMPS, including the role of humidity inversions. Key structural features include a shallow upper entrainment zone at cloud top that is located within the temperature and humidity inversions, a mixed layer driven by cloud-top cooling that extends from the base of the upper entrainment zone to below cloud base, and a lower entrainment zone at the base of the mixed layer. The surface layer below the lower entrainment zone is decoupled from the cloud mixed-layer system. Budget results show that cloud liquid water is maintained in the upper entrainment zone near cloud top (within a temperature and humidity inversion) due to a down gradient transport of water vapor by turbulent fluxes into the cloud layer from above and direct condensation forced by radiative cooling. Liquid water is generated in the updraft portions of the mixed-layer eddies below cloud top by buoyant destabilization. These processes cause at least 20% of the cloud liquid water to extend into the inversion. The redistribution of water vapor from the top of the humidity inversion to its base maintains the cloud layer, while the mixed layer-entrainment zone system is continually losing total water. In this decoupled system, the humidity inversion is the only source of water vapor for the cloud system, since water vapor from the surface layer is not efficiently transported into the mixed layer. Sedimentation of ice is the dominant sink of moisture from the mixed layer.


2013 ◽  
Vol 2013 ◽  
pp. 1-11 ◽  
Author(s):  
Jean Batina ◽  
René Peyrous

Our aim is to determine the more significant parameters acting on the water vapor condensation in a partly closed structure, submitted to external constraints (temperature and humidity) which induce convective movements and thermal variations inside. These constraints locally lead to condensation of the water vapor, initially contained in the air of the volume and/or on the walls. The inside bottom wall is remained dry. Condensed water quantities depend on: (1) dimensions of the structure, (2) the air renewing and its hygrometry, and (3) the phase between thermal and hydrometric conditions. Peculiar conditions are needed to obtain a maximum of condensation.


2005 ◽  
Vol 3 (1) ◽  
pp. 1-7 ◽  
Author(s):  
Saptarshi Basu ◽  
Hang Xu ◽  
Michael W. Renfro ◽  
Baki M. Cetegen

A fiber optic coupled diode laser sensor has been constructed for in situ measurements of water vapor partial pressure in active proton-exchange membrane (PEM) fuel cell systems. The bipolar plate of a prototypical PEM fuel cell was modified to allow for transmission of a near infrared laser beam through the flow channels on either the fuel or oxidizer side of its membrane-electrode assembly. The laser wavelength was scanned over several water rotational and vibrational transitions and the light absorption was detected by measuring the transmitted laser power through the device. The intensity and line shape of the measured transition was used to extract path-averaged values for the water vapor partial pressure. Measurements were initially taken in a non-operating cell with known temperature and humidity input gas streams to calibrate and test the optical device. A technique for rapid determination of the water partial pressure was developed. The optical technique is applicable over a significant temperature and humidity operating range of a PEM fuel cell. The measurement technique was applied to an operating PEM fuel cell system to examine the effects of incoming gas humidity and load on the water vapor partial pressure variation in one of the flow channels.


2017 ◽  
Vol 13 (1) ◽  
pp. 75-83
Author(s):  
Deveerappa Jagadheesha Kamsali Nagaraja

This paper discusses some improvements to a technique for retrieving temperature and humidity from neutral atmospheric refractivities. A technique previously developed used auxiliary information in the form of surface temperature and pressure along with neutral atmospheric refractivity profiles in the troposphere to retrieve temperature and humidity profiles. The height at which water vapor is presumed to be negligible was based on criteria that most of the times it was around ~ 10 km altitude. A new set of criteria are developed wherein it is shown that it is possible to bring this height further down whenever troposphere is dry at altitudes below 


Atmosphere ◽  
2021 ◽  
Vol 12 (4) ◽  
pp. 435
Author(s):  
Qing Li ◽  
Ming Wei ◽  
Zhenhui Wang ◽  
Yanli Chu

To assess the quality of the retrieved products from ground-based microwave radiometers, the “clear-sky” Level-2 data (LV2) products (profiles of atmospheric temperature and humidity) filtered through a radiometer in Beijing during the 24 months from January 2010 to December 2011 were compared with radiosonde data. Evident differences were revealed. Therefore, this paper investigated an approach to calibrate the observed brightness temperatures by using the model-simulated brightness temperatures as a reference under clear-sky conditions. The simulation was completed with a radiative transfer model and National Centers for Environmental Prediction final analysis (NCEP FNL) data that are independent of the radiometer system. Then, the least-squares method was used to invert the calibrated brightness temperatures to the atmospheric temperature and humidity profiles. A comparison between the retrievals and radiosonde data showed that the calibration of the brightness temperature observations is necessary, and can improve the inversion of temperature and humidity profiles compared with the original LV2 products. Specifically, the consistency with radiosonde was clearly improved: the correlation coefficients are increased, especially, the correlation coefficient for water vapor density increased from 0.2 to 0.9 around the 3 km height; the bias decreased to nearly zero at each height; the RMSE (root of mean squared error) for temperature profile was decreased by more than 1 degree at most heights; the RMSE for water vapor density was decreased from greater than 4 g/m3 to less than 1.5 g/m3 at 1 km height; and the decrease at all other heights were also noticeable. In this paper, the evolution of a temperature inversion process is given as an example, using the high-temporal-resolution brightness temperature after quality control to obtain a temperature and humidity profile every two minutes. Therefore, the characteristics of temperature inversion that cannot be seen by conventional radiosonde data (twice daily) were obtained by radiometer. This greatly compensates for the limited temporal coverage of radiosonde data. The approach presented by this paper is a valuable reference for the reprocessing of the historical observations, which have been accumulated for years by less-calibrated radiometers.


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