Accurate empirical equation of ionic mobility from electrolytic conductance

2016 ◽  
Vol 34 (6) ◽  
pp. 625 ◽  
Author(s):  
Yuchen HE ◽  
Xuejing WU ◽  
Fanzhi KONG ◽  
Chengxi CAO ◽  
Liuyin FAN ◽  
...  
Keyword(s):  
Empirical Equation ◽  
Ionic Mobility ◽  
Electrolytic Conductance

Surface confinement induces the formation of solid-like insulating ionic liquid nanostructures

2017 ◽  
Author(s):  
Massimiliano Galluzzi ◽  
Simone Bovio ◽  
Paolo Milani ◽  
Alessandro Podestà
Keyword(s):  
Ionic Liquid ◽  
Electrical Properties ◽  
Electric Fields ◽  
Relative Dielectric Constant ◽  
Ionic Mobility ◽  
Electric Properties ◽  
Bulk Liquid ◽  
Structural Reorganization ◽  
Surface Confinement ◽  
Insulator Layers

We report on the modification of the electric properties of the imidazolium-based [BMIM][NTf2] ionic liquid upon surface confinement in the sub-monolayer regime. Solid-like insulating nanostructures of [BMIM][NTf2] spontaneously form on a variety of insulating substrates, at odd with the liquid and conductive nature of the same substances in the bulk phase. A systematic spatially resolved investigation by atomic force microscopy of the morphological, mechanical and electrical properties of [BMIM][NTf2] nanostructures showed that this liquid substance rearranges into lamellar nanostructures with a high degree of vertical order and enhanced resistance to mechanical compressive stresses and very intense electric fields, denoting a solid-like character. The morphological and structural reorganization has a profound impact on the electric properties of supported [BMIM][NTf2] islands, which behave like insulator layers with a relative dielectric constant between 3 and 5, comparable to those of conventional ionic solids, and significantly smaller than those measured in the bulk ionic liquid. These results suggest that in the solid-like ordered domains confined either at surfaces or inside the pores of the nanoporous electrodes of photo-electrochemical devices, the ionic mobility and the overall electrical properties can be significantly perturbed with respect to the bulk liquid phase, which would likely influence the<br>performance of the devices.<br>

Prediction of Palm Based Biodiesel Properties Through the Preparation of Empirical Equation

2019 ◽  
Vol 2 (1) ◽  
pp. 12-23
Author(s):  
Joelianingsih Joelianingsih ◽  
◽  
Marcelinus Christwardana ◽  
Is Sulistyati Purwaningsih ◽  
◽  
...  
Keyword(s):  
Empirical Equation ◽  
Biodiesel Properties

Laboratory Prediction of Phosphorus Release from Deciduous Leaves to Urban Runoff

1995 ◽  
Vol 30 (2) ◽  
pp. 243-246 ◽  
Author(s):  
Heather Culbert ◽  
Robert France
Keyword(s):  
Total Phosphorus ◽  
Empirical Equation ◽  
Urban Runoff ◽  
Phosphorus Release ◽  
Total Export ◽  
Forested Watershed ◽  
Distilled Water ◽  
Trembling Aspen ◽  
Urban Catchments

Abstract In urban centres, leaves are customarily gathered and temporarily stored in large roadside piles prior to their transport to disposal sites. To simulate the release of total phosphorus to urban runoff, birch and trembling aspen leaves were leached with distilled water in laboratory flasks. There was no difference in rate of total phosphorus release between oven-dried and non-dried leaves. An empirical equation developed from these data and knowledge of the litterfall rates for southern Canada indicated that leaves yielded from 11 to 45 mg TP m−2 of forested watershed. This amount represents up to 5% of the total export of total phosphorus from urban catchments and has the potential to exacerbate eutrophication of municipal waters if leaf pickup is not promptly enforced.

An equation for the empirical design of anoxic zones used to eliminate rising sludges at nitrifying activated sludge plants

1996 ◽  
Vol 33 (3) ◽  
pp. 185-194 ◽  
Author(s):  
M. Sarioglu ◽  
N. Horan
Keyword(s):  
Activated Sludge ◽  
Empirical Equation ◽  
Nitrate Nitrogen ◽  
Critical Concentration ◽  
Settling Tank ◽  
Limited Information ◽  
Batch Experiments ◽  
Anoxic Zone ◽  
Secondary Settling ◽  
Anoxic Zones

Anoxic zones are designed for the removal of nitrogen in nitrifying activated sludge plants. This can be carried out either to achieve a nitrogen discharge consent or to eliminate the problem of rising sludges. The rising sludge problem is mostly encountered in medium and small size plants in warm conditions and there is limited information as to the appropriate design of anoxic zones to protect against rising sludges in the secondary sedimentation tanks. Therefore a series of batch experiments were undertaken in order to establish the critical concentration of nitrate-nitrogen which causes rising sludge in the secondary settling tank and the effect of environmental factors such as temperature (15°C to 30°C) and residual carbon source (100 to 600 mg/1 COD) were examined. Based on the results of these experiments an empirical equation was presented which can be used to size an anoxic zone to eliminate rising sludges. The application of this equation at full-scale plants is discussed.

Equation of state of a Lennard-Jones 12-6 pairwise additive fluid

1980 ◽  
Vol 45 (4) ◽  
pp. 977-983 ◽  
Author(s):  
Jan Sýs ◽  
Anatol Malijevský
Keyword(s):  
Equation Of State ◽  
Empirical Equation ◽  
The State ◽  
Critical Properties ◽  
Lennard Jones ◽  
State Behaviour ◽  
Compressibility Factors

An empirical equation of state was proposed, which is based on pseudoexperimental data on the state behaviour. The equation can be used at reduced temperatures from the range 0.7-100.0 and reduced densities up to 2. Calculated compressibility factors and critical properties agree well with available literature data.

Mass Transfer in Liquid in an Apparatus with Mobile Packing. Application of a Dispersion Model

1993 ◽  
Vol 58 (5) ◽  
pp. 1078-1086
Author(s):  
Zdeněk Palatý
Keyword(s):  
Experimental Data ◽  
Mass Transfer ◽  
Empirical Equation ◽  
Dispersion Model ◽  
Transfer Coefficients ◽  
Mass Transfer Coefficients

The paper deals with the mass transfer in a liquid on a plate with mobile packing. A procedure has been suggested which enables estimation of the mass transfer coefficients from experimental data considering the dispersion flow of the liquid. The results obtained from the desorption of CO2 from water are presented graphically and in the form of empirical equation.

scholarly journals Structural, Electrical and Electrochemical Properties of Glycerolized Biopolymers Based on Chitosan (CS): Methylcellulose (MC) for Energy Storage Application

Polymers ◽  
2021 ◽  
Vol 13 (8) ◽  
pp. 1183
Author(s):  
Shujahadeen B. Aziz ◽  
Ahmad S. F. M. Asnawi ◽  
Mohd Fakhrul Zamani Kadir ◽  
Saad M. Alshehri ◽  
Tansir Ahamad ◽  
...  
Keyword(s):  
Energy Storage ◽  
Ion Transport ◽  
Ammonium Thiocyanate ◽  
Transference Number ◽  
Ionic Mobility ◽  
Transport Parameters ◽  
Ionic Transference Number ◽  
Energy Storage Application ◽  
Electrochemical Double Layer ◽  
Ion Conducting

In this work, a pair of biopolymer materials has been used to prepare high ion-conducting electrolytes for energy storage application (ESA). The chitosan:methylcellulose (CS:MC) blend was selected as a host for the ammonium thiocyanate NH4SCN dopant salt. Three different concentrations of glycerol was successfully incorporated as a plasticizer into the CS–MC–NH4SCN electrolyte system. The structural, electrical, and ion transport properties were investigated. The highest conductivity of 2.29 × 10−4 S cm−1 is recorded for the electrolyte incorporated 42 wt.% of plasticizer. The complexation and interaction of polymer electrolyte components are studied using the FTIR spectra. The deconvolution (DVN) of FTIR peaks as a sensitive method was used to calculate ion transport parameters. The percentage of free ions is found to influence the transport parameters of number density (n), ionic mobility (µ), and diffusion coefficient (D). All electrolytes in this work obey the non-Debye behavior. The highest conductivity electrolyte exhibits the dominancy of ions, where the ionic transference number, tion value of (0.976) is near to infinity with a voltage of breakdown of 2.11 V. The fabricated electrochemical double-layer capacitor (EDLC) achieves the highest specific capacitance, Cs of 98.08 F/g at 10 mV/s by using the cyclic voltammetry (CV) technique.

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