Serpentinization at the Rainbow and Saldanha sites, Mid-Atlantic Ridge: Mineralogical, geochemical, and isotopic features

Abstract The Rainbow hydrothermal field (36°14′N) and the Saldanha seamount (36°34′N), in the Mid-Atlantic Ridge (MAR), are tectonic exposures of serpentinized upper mantle peridotites, both associated with significant hydrothermal activity. On the basis of detailed mineralogical and geochemical characterization of serpentinites from both sites, several serpentinization-related issues are discussed in the present work. As expected in oceanic environments, most of the sampled rocks are lizardite-chrysotile serpentinites exhibiting a variety of pseudomorphic through non-pseudomorphic textures, such textural evolution probably being related to changing water/rock ratios during this retrograde process. Oxygen isotope temperatures indicate that the serpentinization took place at 300–200 °C; on the other hand, isotopic data suggest that replacement of early pseudomorphic lizardite by lizardite ± chrysotile non-pseudomorphic textures requires that temperatures and/or water/rock ratios are high enough to promote the necessary dissolution–recrystallization processes. Mass-balance calculations for olivine-serpentine and orthopyroxene-serpentine pairs provided a basis for establishing serpentinization reactions likely to have produced the present rocks. Moreover, these calculations also showed that, notwithstanding some noticeable loss of MgO from olivine and of SiO2 from orthopyroxene, serpentinization of both minerals implies volume increases on the order of 26–27%, therefore potentially promoting the overall expansion of the rock. The geochemical and isotopic features of the studied rocks indicate that unmodified seawater was responsible for the serpentinization of the MAR peridotites. However, the mineralogy and REE patterns of some of these serpentinites indicate occasional subsequent interaction of the serpentinized rocks with seawater at much lower temperatures (seafloor alteration, characterized by carbonate deposition and negative Ce anomalies), or with high-temperature ore-forming hydrothermal fluids (ore-forming alteration, characterized by sulfide precipitation and steep positive Eu anomalies).

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Petrological and geochemical characterization of the arc-related Suru–Thasgam ophiolitic slice along the Indus Suture Zone, Ladakh Himalaya

Geological Magazine ◽

10.1017/s0016756821000042 ◽

2021 ◽

pp. 1-20

Author(s):

I.M. Bhat ◽

T. Ahmad ◽

D.V. Subba Rao ◽

N.V. Chalapathi Rao

Keyword(s):

Suture Zone ◽

Secondary Mineral ◽

High Field Strength ◽

Geochemical Characterization ◽

Rock Types ◽

Ladakh Himalaya ◽

Magnesian Olivine ◽

Textural Relationship ◽

Ree Patterns

Abstract The Ladakh Himalayan ophiolites preserve remnants of the eastern part of the Neo-Tethyan Ocean, in the form of Dras, Suru Valley, Shergol, Spongtang and Nidar ophiolitic sequences. In Kohistan region of Pakistan, Muslim Bagh, Zhob and Bela ophiolites are considered to be equivalents of Ladakh ophiolites. In western Ladakh, the Suru–Thasgam ophiolitic slice is highly dismembered and consists of peridotites, pyroxenites and gabbros, emplaced as imbricate blocks thrust over the Mesozoic Dras arc complex along the Indus Suture Zone. The Thasgam peridotites are partially serpentinized with relict olivine, orthopyroxene and minor clinopyroxene, as well as serpentine and iron oxide as secondary mineral assemblage. The pyroxenites are dominated by clinopyroxene followed by orthopyroxene with subordinate olivine and spinel. Gabbros are composed of plagioclase and pyroxene (mostly replaced by amphiboles), describing an ophitic to sub-ophitic textural relationship. Geochemically, the studied rock types show sub-alkaline tholeiitic characteristics. The peridotites display nearly flat chondrite-normalized rare earth element (REE) patterns ((La/Yb)N = 0.6–1.5), while fractionated patterns were observed for pyroxenites and gabbros. Multi-element spidergrams for peridotites, pyroxenites and gabbros display subduction-related geochemical characteristics such as enriched large-ion lithophile element (LILE) and depleted high-field-strength element (HFSE) concentrations. In peridotites and pyroxenites, highly magnesian olivine (Fo88.5-89.3 and Fo87.8-89.9, respectively) and clinopyroxene (Mg no. of 93–98 and 90–97, respectively) indicate supra-subduction zone (SSZ) tectonic affinity. Our study suggests that the peridotites epitomize the refractory nature of their protoliths and were later evolved in a subduction environment. Pyroxenites and gabbros appear to be related to the base of the modern intra-oceanic island-arc tholeiitic sequence.

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Electromagnetic experiments for the detection and characterization of seafloor massive sulfides: two case studies from the Mediterranean and Northern Mid-Atlantic Ridge

10.5194/egusphere-egu2020-19308 ◽

2020 ◽

Author(s):

Hölz Sebastian ◽

Haroon Amir ◽

Konstantin Reeck ◽

Jegen Marion

Keyword(s):

Sedimentary Cover ◽

Hydrothermal Activity ◽

Tyrrhenian Sea ◽

Massive Sulfides ◽

Ocean Ridges ◽

Transient Electromagnetic ◽

Global Demand ◽

Mid Atlantic Ridge ◽

The Mediterranean

Seafloor massive sulfides (SMS) are regarded as a potential future resource to satisfy the growing global demand of strategic metals. Aside from mining and retrieving profitable amounts of massive sulfides from the seafloor, the present challenge is to detect and delineate significant SMS accumulations, which are generally located near mid-ocean ridges and along submarine volcanic arc and backarc spreading centers.In the past years we have used the marine transient electromagnetic induction system MARTEMIS, a coincident-loop TEM system developed at GEOMAR (Kiel, Germany), in various marine geological settings for the detection and characterization of SMS in the shallow seafloor down to a depth of ~30m. The system was also used in combination with remote EM receivers (Coil2Dipole experiment) to allow for investigations of conductive structures, which are covered by up to ~100m of sediments.We present experiments from two locations, one at an inactive site in the Mediterranean (Palinuro, Tyrrhenian Sea) where the occurrence of SMS had previously been confirmed by drilling, and one active site on the Northern Mid-Atlantic Ridge (Grimsey Hydrothermal Field, offshore Northern Iceland) where no SMS have been found in gravity cores up to now. The results demonstrate the suitability of the system to detect, delineate and characterize SMS even in scenarios, where the mineralizations are no longer connected to any hydrothermal activity or are buried under a sedimentary cover.

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I. Ultramafic rocks - Peridotite—gabbro—basalt complex from the equatorial Mid-Atlantic Ridge

Philosophical Transactions of the Royal Society of London. Series A, Mathematical and Physical Sciences ◽

10.1098/rsta.1971.0002 ◽

1971 ◽

Vol 268 (1192) ◽

pp. 385-402 ◽

Cited By ~ 99

Keyword(s):

Upper Mantle ◽

Early Stage ◽

Ultramafic Rocks ◽

Metamorphic Rocks ◽

Fracture Zones ◽

Equatorial Atlantic ◽

Isotopic Data ◽

The World ◽

Mid Atlantic Ridge ◽

Liquid Fractionation

Rocks were dredged where the Mid-Atlantic Ridge is intersected by the Chain, Romanche, St Paul and Vema Fracture Zones, and from unfractured portions of the Ridge between 6 and 8° N. Peridotites are common at the fracture zones, but were found also in unfractured sections of the Ridge; harzburgites prevail, but lherzolites, dunites and plagioclase peridotites are also present. A variety of gabbros was recovered, generally above the peridotites, including norites, troctolites, quartz gabbros and theralites. The chemistry of these gabbros indicates a marked crystal-liquid fractionation, following both a ‘tholeiitic’ and an ‘alkali’ trend. The basalts show also both trends, but less markedly. Metamorphic rocks ranging from ‘greenschist’ to ‘amphibolite’ facies are found throughout the sections. Strontium isotopic data suggest that the peridotites (excluding St Peter-Paul rocks) are not related genetically to the associated gabbro-basalt, in a situation similar to that of alpine complexes on the continents. The peridotites are probably residual and were depleted of lithophile elements at some early stage of their history, before the opening of the Atlantic rift. It is postulated that in the upper mantle below the equatorial Atlantic a zone exists of residual, alpine-type peridotite, while the lower crust consists of a mixture of ultramafics and intrusive gabbros. The data indicate strong similarities between the Mid-Atlantic Ridge and alpine complexes from various parts of the world.

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