Composition of outer sphere cations and the charge transfer kinetics of the Ti (IV)/Ti (III) redox couple in the KCl—KF melt.

The charge transfer kinetics for the redox couple Ti(IV)/Ti(III) in the KCl —KF (10 wt. %) —K2TiF6was studied by cyclic voltammetry method. The influence of strongly polarizing Mg2+, Ca2+, Sr2+and Ba2+cations on the kinetics of charge transfer for the Ti(IV)/Ti(III) redox couple upon their introduction into the initial melt, was studied. The activation energies of the charge transfer process for the initial melt and for the melt with the addition of alkaline earth metal cations were calculated.

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Influence of the Alkaline Earth Metal Cations on the Standard Rate Constants of Charge Transfer for the Redox Couple Ti(IV)/Ti(III) in Chloride-Fluoride Melts

ECS Meeting Abstracts ◽

10.1149/ma2016-02/47/3493 ◽

2016 ◽

Keyword(s):

Charge Transfer ◽

Rate Constants ◽

Alkaline Earth ◽

Earth Metal ◽

Metal Cations ◽

Redox Couple ◽

Alkaline Earth Metal ◽

Fluoride Melts ◽

Standard Rate

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Influence of alkaline earth metal cations on the charge transfer kinetics for the redox couple Ti(IV)/Ti(III) in a chloride–fluoride melt

Russian Metallurgy (Metally) ◽

10.1134/s0036029517020148 ◽

2017 ◽

Vol 2017 (2) ◽

pp. 100-105 ◽

Cited By ~ 1

Author(s):

D. A. Vetrova ◽

S. A. Kuznetsov

Keyword(s):

Charge Transfer ◽

Alkaline Earth ◽

Earth Metal ◽

Metal Cations ◽

Redox Couple ◽

Alkaline Earth Metal

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Influence of the Alkaline Earth Metal Cations on the Standard Rate Constants of Charge Transfer for the Redox Couple Ti(IV)/Ti(III) in Chloride-Fluoride Melts

ECS Transactions ◽

10.1149/07515.0363ecst ◽

2016 ◽

Vol 75 (15) ◽

pp. 363-371

Author(s):

D. A. Vetrova ◽

S. A. Kuznetsov

Keyword(s):

Charge Transfer ◽

Rate Constants ◽

Alkaline Earth ◽

Earth Metal ◽

Metal Cations ◽

Redox Couple ◽

Alkaline Earth Metal ◽

Fluoride Melts ◽

Standard Rate

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Kinetic study of wood pyrolysis in presence of metal halides

Open Chemistry ◽

10.2478/s11532-014-0577-4 ◽

2014 ◽

Vol 12 (12) ◽

pp. 1294-1303 ◽

Cited By ~ 6

Author(s):

Vladimir Beliy ◽

Elena Udoratina

Keyword(s):

Activation Energy ◽

Lewis Acids ◽

Alkaline Earth ◽

Reaction Order ◽

Earth Metal ◽

Inorganic Salts ◽

Alkaline Earth Metal ◽

Metal Halides ◽

Wood Pyrolysis ◽

Kinetics Of

AbstractThe purpose of this work was to study the kinetics of wood pyrolysis in the presence of inorganic salts, representatives of classes of alkali and alkaline earth metal halides (NaCl, KCl, KBr, CaCl2, BaCl2·2H2O) and Lewis acids (AlCl3·6H2O, FeCl3·6H2O, CuCl2, CuBr2, ZnCl2·1.5H2O, NiCl2·6H2O, SnCl2·2H2O) using TG-DSC. The activity of these catalysts was estimated by the temperature of the beginning of pyrolysis, charcoal yield and kinetic parameters, such as energy of activation and reaction order. Using the Lewis acids as catalysts for pyrolysis leads to a decrease in the temperature of the process beginning and the activation energy. In the presence of other catalysts activation energy does not significantly change. The increase of a seeming reaction order in the presence of Lewis acids possibly is a consequence of complication of the thermodestruction mechanism, with the appearance of new parallel competing stages.

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Decomposition Reactions and Kinetics of Alkaline-Earth Metal Levulinate and Formate Salts

ACS Sustainable Chemistry & Engineering ◽

10.1021/acssuschemeng.6b02704 ◽

2017 ◽

Vol 5 (4) ◽

pp. 3039-3045 ◽

Cited By ~ 3

Author(s):

Scott J. Eaton ◽

M. Clayton Wheeler

Keyword(s):

Alkaline Earth ◽

Earth Metal ◽

Alkaline Earth Metal ◽

Decomposition Reactions ◽

Kinetics Of

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Standard rate constants of charge transfer for the redox couple Ti(IV)/Ti(III) in chloride-fluoride melts with the different cationic composition

Transaction Kola Science Cetnre ◽

10.37614/2307-5252.2021.2.5.012 ◽

2021 ◽

Vol 12 (2-2021) ◽

pp. 60-65

Author(s):

D. A. Vetrova ◽

◽

S. A. Kuznetsov ◽

Keyword(s):

Charge Transfer ◽

Rate Constants ◽

Diffusion Coefficients ◽

Redox Couple ◽

Cationic Composition ◽

Fluoride Melts ◽

Alkali Metal Halides ◽

Cyclic Voltammetry Method ◽

Standard Rate ◽

Kinetics Of

The influence of the second coordination sphere of titanium complexes on the charge transfer kinetics of the Ti (IV)/Ti (III) redox couple in melts of alkali metal halides was studied by cyclic voltammetry method. Diffusion coefficients in the CsC-CsF (10 wt. %) melt were calculated. The standard rate constants of charge transfer have been determined by the Nicholson method. The activation energies of the charge transfer process in (NaCl- KCl)equimol-NaF (10 wt. %) — K2TiF6, KCl-KF (10 wt. %) — K2TiF6 and CsCl-CsF (10 wt. %) — K2TiF6 melts were calculated.

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Visible Intramolecular Charge Transfer Absorption of Bipyridinium-Crown Ether Conjugates in Response to the Alkali and Alkaline Earth Metal Ions

Journal of Ion Exchange ◽

10.5182/jaie.25.141 ◽

2014 ◽

Vol 25 (4) ◽

pp. 141-145 ◽

Cited By ~ 2

Author(s):

Tetsuo KUWABARA ◽

Haocheng GUO ◽

Hideki KUROKAWA

Keyword(s):

Charge Transfer ◽

Crown Ether ◽

Metal Ions ◽

Alkaline Earth ◽

Intramolecular Charge Transfer ◽

Earth Metal ◽

Alkaline Earth Metal ◽

Alkaline Earth Metal Ions

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Static second hyperpolarizability of inverse sandwich compounds (M1–C5H5–M2) of alkali (M1 = Li, Na, K) and alkaline earth metals (M2 = Be, Mg, Ca)

Physical Chemistry Chemical Physics ◽

10.1039/c8cp01210e ◽

2018 ◽

Vol 20 (19) ◽

pp. 13331-13339 ◽

Cited By ~ 1

Author(s):

Kaushik Hatua ◽

Avijit Mondal ◽

Prasanta K. Nandi

Keyword(s):

Charge Transfer ◽

Alkali Metal ◽

Alkaline Earth ◽

Earth Metal ◽

Alkaline Earth Metals ◽

Alkaline Earth Metal ◽

Sandwich Complexes ◽

Second Hyperpolarizability ◽

Sandwich Compounds

In the investigated inverse sandwich complexes, charge transfer from alkali metal (M1) led to aromatically stabilized Cp ring, which prevented further charge transfer from the alkaline earth metal (M2).

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