New Mechanisms for Cryogenic Solid-Gas Sublimation Refrigeration

Author(s):  
Lin Chen

Sublimation is one phase change mechanism which usually happens under low-to-moderate temperatures and at the same time large amounts of latent heat is absorbed or released. Low temperature sublimation has been proposed in a lot of applications as one useful fast cooling/refrigeration mechanisms, such as medical cooling, food engineering, chemical synthesis, domestic cooling and many industrial sectors. In this brief chapter, the basic mechanisms of static sublimation process and sublimation two-phase flows are clarified and analyzed first, which covers the theoretical and physical problems of sublimation phase-change. Then the previous studies are classified into numerical modeling and experimental verifications. Representative refrigeration systems are also introduced and compared in this chapter, which may give useful indications for future innovations in this field. Future research focuses are also summarized and proposed in this chapter.

Author(s):  
P.P.K. Smith

Grains of pigeonite, a calcium-poor silicate mineral of the pyroxene group, from the Whin Sill dolerite have been ion-thinned and examined by TEM. The pigeonite is strongly zoned chemically from the composition Wo8En64FS28 in the core to Wo13En34FS53 at the rim. Two phase transformations have occurred during the cooling of this pigeonite:- exsolution of augite, a more calcic pyroxene, and inversion of the pigeonite from the high- temperature C face-centred form to the low-temperature primitive form, with the formation of antiphase boundaries (APB's). Different sequences of these exsolution and inversion reactions, together with different nucleation mechanisms of the augite, have created three distinct microstructures depending on the position in the grain.In the core of the grains small platelets of augite about 0.02μm thick have farmed parallel to the (001) plane (Fig. 1). These are thought to have exsolved by homogeneous nucleation. Subsequently the inversion of the pigeonite has led to the creation of APB's.


Author(s):  
M.G. Burke ◽  
M.K. Miller

Interpretation of fine-scale microstructures containing high volume fractions of second phase is complex. In particular, microstructures developed through decomposition within low temperature miscibility gaps may be extremely fine. This paper compares the morphological interpretations of such complex microstructures by the high-resolution techniques of TEM and atom probe field-ion microscopy (APFIM).The Fe-25 at% Be alloy selected for this study was aged within the low temperature miscibility gap to form a <100> aligned two-phase microstructure. This triaxially modulated microstructure is composed of an Fe-rich ferrite phase and a B2-ordered Be-enriched phase. The microstructural characterization through conventional bright-field TEM is inadequate because of the many contributions to image contrast. The ordering reaction which accompanies spinodal decomposition in this alloy permits simplification of the image by the use of the centered dark field technique to image just one phase. A CDF image formed with a B2 superlattice reflection is shown in fig. 1. In this CDF micrograph, the the B2-ordered Be-enriched phase appears as bright regions in the darkly-imaging ferrite. By examining the specimen in a [001] orientation, the <100> nature of the modulations is evident.


2016 ◽  
Vol 11 (1) ◽  
pp. 60-65 ◽  
Author(s):  
R.Kh. Bolotnova ◽  
E.F. Gainullina

The spherical explosion propagation process in aqueous foam with the initial water volume content α10=0.0083 corresponding to the experimental conditions is analyzed numerically. The solution method is based on the one-dimensional two-temperature spherically symmetric model for two-phase gas-liquid mixture. The numerical simulation is built by the shock capturing method and movable Lagrangian grids. The amplitude and the width of the initial pressure pulse are found from the amount of experimental explosive energy. The numerical modeling results are compared to the real experiment. It’s shown, that the foam compression in the shock wave leads to the significant decrease in velocity and in amplitude of the shock wave.


2006 ◽  
Vol 4 ◽  
pp. 224-236
Author(s):  
A.S. Topolnikov

The paper is devoted to numerical modeling of Navier–Stokes equations for incompressible media in the case, when there exist gas and liquid inside the rectangular calculation region, which are separated by interphase boundary. The set of equations for incompressible liquid accounting for viscous, gravitational and surface (capillary) forces is solved by finite-difference scheme on the spaced grid, for description of interphase boundary the ideology of Level Set Method is used. By developed numerical code the set of hydrodynamic problems is solved, which describe the motion of two-phase incompressible media with interphase boundary. As a result of numerical simulation the solutions are obtained, which are in good agreement with existing analytical and experimental solutions.


Energies ◽  
2021 ◽  
Vol 14 (12) ◽  
pp. 3634
Author(s):  
Grzegorz Czerwiński ◽  
Jerzy Wołoszyn

With the increasing trend toward the miniaturization of electronic devices, the issue of heat dissipation becomes essential. The use of phase changes in a two-phase closed thermosyphon (TPCT) enables a significant reduction in the heat generated even at high temperatures. In this paper, we propose a modification of the evaporation–condensation model implemented in ANSYS Fluent. The modification was to manipulate the value of the mass transfer time relaxation parameter for evaporation and condensation. The developed model in the form of a UDF script allowed the introduction of additional source equations, and the obtained solution is compared with the results available in the literature. The variable value of the mass transfer time relaxation parameter during condensation rc depending on the density of the liquid and vapour phase was taken into account in the calculations. However, compared to previous numerical studies, more accurate modelling of the phase change phenomenon of the medium in the thermosyphon was possible by adopting a mass transfer time relaxation parameter during evaporation re = 1. The assumption of ten-fold higher values resulted in overestimated temperature values in all sections of the thermosyphon. Hence, the coefficient re should be selected individually depending on the case under study. A too large value may cause difficulties in obtaining the convergence of solutions, which, in the case of numerical grids with many elements (especially three-dimensional), significantly increases the computation time.


Rare Metals ◽  
2021 ◽  
Author(s):  
Jia-Xing Song ◽  
Xin-Xing Yin ◽  
Zai-Fang Li ◽  
Yao-Wen Li

Abstract As a promising photovoltaic technology, perovskite solar cells (pero-SCs) have developed rapidly over the past few years and the highest power conversion efficiency is beyond 25%. Nowadays, the planar structure is universally popular in pero-SCs due to the simple processing technology and low-temperature preparation. Electron transport layer (ETL) is verified to play a vital role in the device performance of planar pero-SCs. Particularly, the metal oxide (MO) ETL with low-cost, superb versatility, and excellent optoelectronic properties has been widely studied. This review mainly focuses on recent developments in the use of low-temperature-processed MO ETLs for planar pero-SCs. The optical and electronic properties of widely used MO materials of TiO2, ZnO, and SnO2, as well as the optimizations of these MO ETLs are briefly introduced. The commonly used methods for depositing MO ETLs are also discussed. Then, the applications of different MO ETLs on pero-SCs are reviewed. Finally, the challenge and future research of MO-based ETLs toward practical application of efficient planar pero-SCs are proposed. Graphical abstract


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