Thermo-Oxidative Behavior of Carbon Black Composites for Self-Regulating Heaters

2019 ◽  
Vol 34 ◽  
pp. 66-80
Author(s):  
Radu Setnescu ◽  
Marius Lungulescu ◽  
Adela Bara ◽  
Alina Caramitu ◽  
Sorina Mitrea ◽  
...  
Keyword(s):  
Carbon Black ◽  
Polymer Matrix ◽  
Elevated Temperatures ◽  
Conductive Filler ◽  
Limiting Factor ◽  
Conductive Composites ◽  
Major Interest ◽  
Materials Used ◽  
Crystallinity Changes ◽  
Physical Changes

The composite materials for self-regulating heaters are conductive composites based on a polymer matrix and a dispersed conductive filler consisting in either carbon black or another carbon material, such as graphite or nanotubes. Similar materials are suitable for sensors and current limitations. As these materials used in heating applications work usually at elevated temperatures in presence of air, the ageing processes would be an important limiting factor of their lifetime. Therefore, thermal oxidation processes and crystallinity changes during the service of these products are of major interest in durability studies. The potential interference of carbon-based materials with the oxidation and ageing of polymer matrix shall be known in order to correctly estimate the durability of such materials. The effect of radiation exposure is studied taking into account the potential use of such materials in radiation environments. In this work, the activation energies of some initial, unaged and aged products at elevated temperatures are compared in order to characterize the effect of thermo-oxidative ageing and hence to evaluate their durability. The effect of some antioxidants is also discussed. The crystallinity, calculated from DSC was used for evaluation of the physical changes induced within the aged materials, following the procedures described in previous work. FTIR-ATR technique was used for characterization of chemical changes induced by ageing.

Ionic Crosslinking of Carboxylated SBR

1983 ◽  
Vol 56 (5) ◽  
pp. 942-958 ◽  
Author(s):  
Kyosaku Sato
Keyword(s):  
Zinc Oxide ◽  
Carbon Black ◽  
Elevated Temperatures ◽  
Ion Clusters ◽  
Ionic Crosslinking ◽  
Reinforcing Fillers ◽  
Ionic Bonds ◽  
Tan Δ ◽  
And Shifts ◽  
Ionic Crosslinks

Abstract 1. Ionic bonding of carboxylated SBR with zinc oxide is detectable by means of measurements of the temperature dependence of tan δ. There is an α peak in the region of 60°C at 3.5 Hz. The position and shape of the α peak are strongly dependent on the state of cure of the vulcanizates. Without permanent crosslinking, the α peak is a plateau; as the crosslink density increases, the α peak becomes sharper and shifts to lower temperatures. The presence of carbon black causes the α peak to shift to higher temperatures, regardless of the presence of permanent crosslinks. 2. Ionic bonds in carboxylated SBR reacted with zinc oxide are in the form of ion clusters which function as crosslinks at room temperature. The ionic crosslinks provide carboxylated SBR with high tensile strength in the absence of reinforcing fillers. The presence of carbon black causes the 300% modulus to increase. The ionic crosslinks are labile, and the strength is lost at moderately elevated temperatures. A mixed cure system consisting of both sulfur and zinc oxide provides higher heat resistance than either of the single cure systems.

A Study on Carbon Electro-Conductive Filler for the Epoxy Conductive Coating

2011 ◽  
Vol 291-294 ◽  
pp. 41-46
Author(s):  
Bing Li ◽  
Yan Hong Li ◽  
Wen Xing Chen
Keyword(s):  
Carbon Black ◽  
Titanium Oxide ◽  
Epoxy Resins ◽  
Conductive Filler ◽  
Resistance Rate ◽  
Conductive Coating ◽  
Different Types ◽  
Optimal Mix ◽  
Oil Tank ◽  
Experiment Analysis

To ensure the use of oil tank safely, it is necessary that the conductive coating was used in inner oil tank. This paper concentrates on a study of the electrical properties (surface resistance rate) of epoxy resins filled with different types of carbon pigments, such as colloid graphite, carbon black and mixture of colloid graphite/carbon black, as well as on the investigation of some mechanical properties, appearance and morphology .To produce a light grey and conductive coating, titanium oxide and carbon electro-conductive pigments were investigated in this article. The objective of the experiment therefore was to choose the optimal electro-conductive filler and determine the optimal mix ratio of colloid graphite/ carbon black and titanium oxide /colloid graphite and titanium oxide /mixable electro-conductive filler. From the experiment analysis, it was found that the optimized colloid graphite and carbon black mix ratio is 3:1; the optimized titanium oxide and colloid graphite mix ratio is 1:1; the optimized titanium oxide and mixable electro-conductive filler mix ratio is 8:1. In terms of resistance rate and color, we may arrive at the conclusion that 15μm colloid graphite as the optimized electro- conductive pigments and the optimal mix ratio of titanium oxide /colloid graphite is 1:1.

In situ iodoalkane-reduction of graphene oxide in a polymer matrix: an easy and effective approach for the fabrication of conductive composites

2015 ◽  
Vol 3 (43) ◽  
pp. 11531-11539 ◽  
Author(s):  
Haiquan Guo ◽  
Fangfang Liu ◽  
Jianying Zhao ◽  
Haibo Yao ◽  
Rizhe Jin ◽  
...  
Keyword(s):  
Graphene Oxide ◽  
Polymer Matrix ◽  
Conductive Composites ◽  
Polyimide Composites

Graphene/polyimide composites with the conductivity of 2.22 S m−1 were fabricated via in situ reduction of graphene oxide by 1,2-diiodoethane.

scholarly journals PENGARUH PENYAMAKAN ZIRKONIUM TERHADAP UJI KEKUATAN TARIK, UJI KEKUATAN SOBEK, UJI KEMULURAN DAN UJI SUHU KERUT PADA BERBAGAI JENIS KULIT IKAN (The Effect of Zirconium Tanning Against Tensile Strength Test, Strength Test of Tear, Glide Test, and Wrinkle Temperature Test on Different Fish Types)

2018 ◽  
Vol 13 (2) ◽  
pp. 105
Author(s):  
Rokhmah Hergiyani ◽  
Y. S. Darmanto ◽  
Lukita Purnamayati
Keyword(s):  
Tensile Strength ◽  
Negative Impact ◽  
Strength Test ◽  
Collagen Fibers ◽  
Raw Material ◽  
Tear Strength ◽  
Complex Processes ◽  
Materials Used ◽  
The One ◽  
Physical Changes

Kulit ikan merupakan limbah perikanan yang dapat memberikan dampak negatif pada lingkungan. Salah satu cara untuk menanggulangi limbah tersebut adalah dengan proses penyamakan kulit. Penyamakan kulit adalah rangkaian proses yang sangat kompleks terjadi banyak perubahan fisik dan kimia di satu sisi, bagian yang tidak berguna dihilangkan dari kulit mentah untuk mendapatkan serat kolagen murni dan membuka struktur serat kolagen. Proses penyamakan yang tidak baik mengakibatkan kulit menjadi rusak, lemas, dan kebusukan, sehingga penanganannya dapat dengan cara menambah bahan penyamak untuk menguatkan dan menghindari kebusukan. Bahan penyamak yang digunakan yaitu zirconium. Tujuan penelitian ini adalah untuk mengetahui pengaruh penyamakan zirkonium terhadap uji kekuatan tarik, uji kekuatan sobek, uji kemuluran dan uji suhu kerut pada berbagai jenis ikan. Bahan baku yang digunakan adalah kulit ikan nila, kakap dan bandeng. Metode penelitian yang digunakan adalah experimental laboratories menggunakan Rancangan Acak Lengkap (RAL) dengan tiga kali ulangan dan  menggunakan analisa ragam ANOVA. Hasil uji menunjukan penggunaan zirkonium 7,5% terhadap kulit ikan nila, kakap, dan bandeng berpengaruh nyata (p<0,05) pada kekuatan tarik, kekuatan sobek, kemuluran dan suhu kerut pada karakteristik penyamakan. Penggunaan bahan penyamak zirkonium 7,5% terbaik dihasilkan oleh kulit ikan kakap pada uji kekuatan tarik 1675,84 N/cm2, kekuatan sobek 163,92 N/cm2 dan uji suhu kerut 103,45˚C sedangkan kemuluran untuk hasil terbaik pada kulit bandeng sebesar 28,74%, jadi setiap ikan mempunyai ciri kulit tersendiri pada setiap parameter uji. The skin of the fish waste is a fishery that can give a negative impact on the environment. One way of tackling the waste is by the process of tanning leather. Tanning is a very complex processes occur many chemical and physical changes on the one hand, the useless removed from rawhide to get pure collagen fibers and the open structure of the collagen fibers. The process of tanning is not a good result in the skin becomes broken, buckled, and corruption, so that responses can be with how to add ingredients to strengthen Tanner and avoid corruption. On the research of materials used i.e. Tanners used are zirconium.. The purpose of this research is to know the influence of zirconium tanning against test tensile strength, tear strength test, test and test temperature wrinkle elongation on various types of fish. The raw material used is leather fish tilapia, milkfish and snapper. Research methods used are experimental laboratories using Complete Random Design (RAL) with three-time repeats and a range of analysis using ANOVA. Test results showed the use of zirconium 7.5% against the skin of the fish, snapper, tilapia and milkfish influential real (p < 0.05) on the tensile strength, tear strength, elongation and wrinkle on temperature characteristics of tanning. The use of zirconium Tanner 7.5% best produced by skin test on a snapper 1675.84 tensile strength N/cm2, the strength of RIP 163.92 N/cm2 and test the temperature of the wrinkle 103,45 ˚ C while elongation for the best results on the skin of the banding of 28.74%, so each fish has its own skin characteristics on each test parameter.

Effect of Technical Carbon the Deformation-Strength Properties of Low Pressure Polyethylene

2020 ◽  
Vol 869 ◽  
pp. 229-233
Author(s):  
Timur A. Borukaev ◽  
Abubekir Kh. Shaov ◽  
Raisa D. Archakova ◽  
Zakhirat Kh. Sultigova
Keyword(s):  
Carbon Black ◽  
Polymer Matrix ◽  
High Density Polyethylene ◽  
Entire Range ◽  
Filler Content ◽  
Strength Properties ◽  
Optimal Combination ◽  
High Density ◽  
Strength And Ductility ◽  
Properties Of Composites

The influence of carbon black on the deformation-strength properties of high density polyethylene is considered. It was found that the deformation-strength properties of the polymer matrix change over the entire range of the filler content. The amount of carbon black that can be introduced into high-density polyethylene and obtained a composite material with the optimal combination of stiffness, strength and ductility is established. It was shown that the change in the deformation-strength properties of composites is due to the behavior and influence of carbon black particles on the structure of the polymer matrix.

scholarly journals Effect of Ti3C2Tx MXenes etched at elevated temperatures using concentrated acid on binder-free supercapacitors

RSC Advances ◽  
2020 ◽  
Vol 10 (68) ◽  
pp. 41837-41845
Author(s):  
Sunil Kumar ◽  
Dongwoon Kang ◽  
Hyeryeon Hong ◽  
Malik Abdul Rehman ◽  
Yeon-jae Lee ◽  
...  
Keyword(s):  
Carbon Black ◽  
Elevated Temperatures ◽  
Different Temperatures ◽  
Binder Free ◽  
C 50

The effect of Ti3C2Tx MXene etched at different temperatures (25 °C, 50 °C, and 80 °C) on the capacitance of supercapacitors without the use of conducting carbon-black or a binder was studied.

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