A Study on Carbon Electro-Conductive Filler for the Epoxy Conductive Coating

2011 ◽  
Vol 291-294 ◽  
pp. 41-46
Author(s):  
Bing Li ◽  
Yan Hong Li ◽  
Wen Xing Chen

To ensure the use of oil tank safely, it is necessary that the conductive coating was used in inner oil tank. This paper concentrates on a study of the electrical properties (surface resistance rate) of epoxy resins filled with different types of carbon pigments, such as colloid graphite, carbon black and mixture of colloid graphite/carbon black, as well as on the investigation of some mechanical properties, appearance and morphology .To produce a light grey and conductive coating, titanium oxide and carbon electro-conductive pigments were investigated in this article. The objective of the experiment therefore was to choose the optimal electro-conductive filler and determine the optimal mix ratio of colloid graphite/ carbon black and titanium oxide /colloid graphite and titanium oxide /mixable electro-conductive filler. From the experiment analysis, it was found that the optimized colloid graphite and carbon black mix ratio is 3:1; the optimized titanium oxide and colloid graphite mix ratio is 1:1; the optimized titanium oxide and mixable electro-conductive filler mix ratio is 8:1. In terms of resistance rate and color, we may arrive at the conclusion that 15μm colloid graphite as the optimized electro- conductive pigments and the optimal mix ratio of titanium oxide /colloid graphite is 1:1.

2013 ◽  
Vol 753-755 ◽  
pp. 2379-2382
Author(s):  
Shi Meng Xu ◽  
Run Bo Ma ◽  
Jian Hua Du ◽  
Jun Hong Liu ◽  
Qi Jin

Filled the N330 carbon black, silica T80 carbon black and Al powder and Fe2O3 magnetic nanoparticles, the rubber composites on multi-component electromagnetic fillers were prepared according to orthogonal experiment analysis, and the preliminary experiment conclusions of the filler prescription designs were given; Based on the experiment design, the mechanical properties and thermal conductivity of the rubber composite were tested, and the testing results were analyzed by using variance analysis. Thus, the paper shows that the effects of N330 on rubber mechanical properties are significant, and the effects of Al powder on the rubber thermal conductivity are significant. Moreover, it is highly emphasized in this paper that the orthogonal experiment design must be carefully explored before the tests are executed.


2017 ◽  
Vol 266 ◽  
pp. 172-176
Author(s):  
Pattarawadee Maijan ◽  
Nitinart Saetung ◽  
Wisut Kaewsakul

Mixing behaviors of the compounds filled with different reinforcing fillers were studied in correlation with compound and vulcanizate properties. Four filler systems were used including: 1) silica plus small amount of silane coupling agent; 2) carbon black; 3) pre-modified silica; and 4) silica+silane-carbon black mixed one. The results have shown that silica provides longer optimum cure time and shorter cure rate than carbon black due to accelerator adsorption on silica surface. In addition, owing to highly polar nature on silica surface the silica-based compounds show rather high viscosity, attributed to stronger filler-filler interaction as can be confirmed by Payne effect and reinforcement index. However, the commercial surface treatment or pre-modified form of silica shows superior properties than in-situ modification of silica by silane during mixing, while it gives comparable properties to carbon black-based compound. Tensile properties of vulcanizates show a good correlation with the basic properties of their compounds.


Author(s):  
Ahmed A Al-Ghamdi ◽  
Omar A Al-Hartomy ◽  
Falleh R Al-Solamy ◽  
Nikolay Dishovsky ◽  
Petrunka Malinova ◽  
...  

The paper presents the investigations on obtaining dual phase fillers with preset silica content running a successful impregnation of two completely different types of conventional carbon black with silicasol. The hybrid fillers studied were characterized by atomic absorption spectroscopy and inductively coupled plasma–optical emission spectroscopy. The total pore volume, the average pore diameter, the specific surface area, the oil absorption number, and iodine adsorption of the fillers were also investigated. The distribution of both phases within the hybrid filler obtained and their interpenetration were investigated with scanning transmission electron microscopy-energy dispersive X-ray spectroscopy. The hybrid products obtained were investigated as reinforcing fillers of natural rubber-based composites. The results obtained show that the suggested impregnation with silicasol of conventional carbon black is a perspective method for preparation of carbon-silica dual phase fillers. The method provides an easy control over the quantitative ratio between the two phases. The fillers thus prepared do not change significantly the curing and mechanical characteristics of the vulcanizates, but improve their thermal aging resistance. The isolation of the carbon black aggregates by the silica phase, and the interpenetration of the two phases is a prerequisite to obtain elastomer composites of good mechanical and microwave properties suitable for producing of microwave shielding devices.


1997 ◽  
Vol 70 (2) ◽  
pp. 222-230 ◽  
Author(s):  
Emma Thorn-Csányi ◽  
Hans-Detlef Luginsland

Abstract Intermolecular metathetic polymer degradation opens up an analytic method to identify the quality and quantity of the components in blends of different types of rubber even if they are crosslinked and filled with carbon black, mineral oil, etc.. Furthermore the amount of soluble and insoluble additives can be determined. Moreover, metathetic degradation allows for determination of detailed information about the chemical microstructure (e.g. sequence length distribution of 1,2-butadiene and styrene units) of the rubbers used. This method is suitable for analysis of rubber components in tires.


2018 ◽  
Vol 2018 (1) ◽  
pp. 000344-000348
Author(s):  
Eric Ouyang ◽  
Billy Ahn ◽  
SeonMo Gu ◽  
Jim Hsu ◽  
Yonghyuk Jeong ◽  
...  

Abstract In this paper, the impact of two different types of warpage, strip warpage and system-in-packages (SiP) module warpage, are considered and studied, both experimentally and numerically. An advanced material characterization method is also conducted to study the curing reaction and Pressure-Volume-Temperature-Cure (PVTC) kinetics of the packages. The curing reaction of epoxy resins, as a function of temperature and activation energies, is experimentally determined. During the curing process, the viscosity of epoxy resins change with temperature and conversion rate. The Castro-Macosko model is adopted to describe the rheological properties of epoxy resins. Experimentally, we have prepared substrate strip samples with different component density and molding compound materials. Each substrate strip contains eighteen system-in-packages. The warpages of all substrate strips and all the system-in-package modules were measured, compared, and correlated.


2018 ◽  
Vol 776 ◽  
pp. 98-103
Author(s):  
Tomáš Žlebek ◽  
Jakub Hodul ◽  
Rostislav Drochytka

The paper deals with the possibility of using two different types of fly ash contaminated by flue gas denitrification (Selective Non-Catalytic Reduction (SNCR)) as a filler into the polymer anchor based on epoxy resin. Due to the problematic use of contaminated fly ash in silicate materials, the use of such fly ash in polymer materials seems to be effective because by mixing with polymers such as polyester and epoxy resins, toxic gas ammonia (NH3) does not release. Determination of optimal percentage of filling by the fly ash was performed in order to achieve the best possible physical and mechanical properties of the epoxy anchor material. It was found out that the 45% addition of both used of contaminated fly ashes seems to be the most appropriate, when the polymer anchor material exhibited better tensile properties than reference anchors containing quartz sand Dorsilit. Furthermore, it was found that the optimal addition of contaminated fly ash also positively influenced the maximum anchoring force found in the tug test. Detailed connection of anchor material with anchored bar and concrete was observed on tomography images.


Author(s):  
Hsin Her Yu ◽  
Min-Hsun Cheng ◽  
Rong-Yuan Jou ◽  
Kuang-Chyi Lee ◽  
Chien-Chang Lin

With increasing global urbanization and industrialization, many more pipelines for gas, potable water, sewer, oil, and power cables have been installed underground, underwater, in buildings and in factories. Maintenance of such pipelines is crucial. However, it is often difficult and has become a growing problem these days. The PALTEM-HL (Trade mark and stands for Pipeline Automatic Lining SysTEM, Hose Lining Method), a pipeline relining system, was developed as an effective and inexpensive solution for this problem. In this project, we try to develop a new resins and the adhesives system to replace the raw materials used in the PALTEM-HL system. Anionic harder combined two different types of epoxy resins were investigated in this study. After curing, the mechanical properties and glass transition temperature of the mixture were examined and the optimum sample preparation prescription was also found. FTIR (Fourier Transform Infrared Spectroscopy) and DSC (Differential Scanning Calorimeter) were employed to monitor the curing process of the mixtures. The mechanical properties of the mixture were also measured by Instron and micro Vickers.


1995 ◽  
Vol 48 (2) ◽  
pp. 237-241 ◽  
Author(s):  
G.M. Nasr ◽  
M.M. Badawy ◽  
S.E. Gwaily ◽  
N.M. Shash ◽  
H.H. Hassan

1961 ◽  
Vol 34 (3) ◽  
pp. 709-728 ◽  
Author(s):  
C. W. Sweitzer ◽  
K. A. Burgess ◽  
F. Lyon

Abstract 1. The removal of chemisorbed oxygen from channel black and furnace black, without alteration of the underlying carbon surface, results in only minor effects in reinforcement potential regardless of the curative system employed, whether polar or free radical. 2. When the underlying carbon surface is changed by heat treatment to a state of lower energy, a significant decrease in the reinforcing ability of the carbon black results. 3. Different types of oxygen functional groups added to the carbon surface produce similar effects upon rubber properties. 4. These effects are limited to retardation of cure rate in sulfur curing systems. Only small effects of any kind are produced in the natural rubber-peroxide system. 5. The net conclusion to be drawn is that combined oxygen on the carbon surface plays a relatively minor role in the chemical effect of carbon black upon reinforcement; the nature of the carbon surface itself is of primary importance.


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