Structure and Performance of Ti/TiN/PbO2 Electrodes with Plasma-Sprayed TiN Interlayer

2013 ◽  
Vol 325-326 ◽  
pp. 40-42
Author(s):  
Amin Huang ◽  
Jian Xin Zhang ◽  
Xiao Wen Wu ◽  
Yang Wang

TiN coating as an interlayer in Ti/TiN/PbO2 electrode and PbO2 catalytic layer were fabricated by reactive plasma spray and electro-deposition, respectively. It is shown that because of good effect of the TiN interlayer, the Ti/TiN/PbO2 electrode exhibits a higher oxygen evolution potential and much improved accelerated life compared with the Ti/PbO2 electrode.

2012 ◽  
Vol 602-604 ◽  
pp. 1613-1616 ◽  
Author(s):  
Xiao Wen Wu ◽  
Jian Xin Zhang ◽  
Yang Wang ◽  
Amin Huang

In this paper, TiN coating as an interlayer was fabricated on Ti substrate by reactive plasma spray. Ti/TiN/Sb-SnO2 electrodes were prepared by SOL-GEL method and the influence of the TiN interlayer on the structure, oxygen evolution potential and service life of the electrodes was studied. It was shown that the surface of the Ti/TiN/Sb-SnO2 electrodes is more homogeneous and the oxygen evolution potential and accelerated life are both higher than those of the Ti/Sb-SnO2 electrodes.


2011 ◽  
Vol 130-134 ◽  
pp. 950-954
Author(s):  
Li Hua Gao ◽  
Jian Xin Zhang ◽  
Yan Chun Dong ◽  
Yong Yang ◽  
Dian Ran Yan

In this paper TiN coating as an interlayer was fabricated on Q235 steel substrate by reactive plasma spray method and its microstructure and influences on the performance of the Fe/TiN/PO2 electrode were investigated. It is shown that the TiN coating has a rough surface and layered cross-section structure. The coating consists of main TiN phase and a small quantity of Ti oxides. After heat-treated below 550°C the TiN coating is greatly densified due to the increase of Ti oxides, and however the electric resistance of the Fe/TiN samples is still lower than that of the Ti substrate. For the Fe/TiN/PbO2 electrode a rougher surface and more micropores were observed in the active PbO2 coating than on the surface of the Ti/PbO2 electrode. Due to the presence of the TiN interlayer the Fe/TiN/PbO2 electrode shows an accelerated life of 180h under the test condition, which is much longer than 28min of the Ti/PbO2 electrode.


2005 ◽  
Vol 54 (5) ◽  
pp. 2399
Author(s):  
Feng Wen-Ran ◽  
Yan Dian-Ran ◽  
He Ji-Ning ◽  
Chen Guang-Liang ◽  
Gu Wei-Chao ◽  
...  

2007 ◽  
Vol 14 (5) ◽  
pp. 71-75 ◽  
Author(s):  
Dong-li Zou ◽  
Dian-ran Yan ◽  
Ji-ning He ◽  
Xiang-zhi Li ◽  
Yan-chun Dong ◽  
...  

Shinku ◽  
2005 ◽  
Vol 48 (3) ◽  
pp. 241-243 ◽  
Author(s):  
Motohiro YAMADA ◽  
Tatsuya INAMOTO ◽  
Masahiro FUKUMOTO ◽  
Toshiaki YASUI

2000 ◽  
Vol 16 (4) ◽  
pp. 339-343 ◽  
Author(s):  
T. Valente ◽  
F. Carassiti ◽  
M. Suzuki ◽  
M. Tului

Shinku ◽  
2003 ◽  
Vol 46 (7) ◽  
pp. 563-566 ◽  
Author(s):  
Motohiro YAMADA ◽  
Masahiro FUKUMOTO ◽  
Toshiaki YASUI

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