The Catalyzed Synthesis of Prenyl Alcohol

2014 ◽  
Vol 577 ◽  
pp. 7-10
Author(s):  
Fu Xian Ruan ◽  
Zhi Peng He ◽  
Hong Lang Song ◽  
Ke Lin Huang ◽  
Jing Hu ◽  
...  
Keyword(s):  
Reaction Time ◽  
Water Consumption ◽  
Dichloroacetic Acid ◽  
Raw Material ◽  
Distilled Water ◽  
Reaction Conditions ◽  
Acid Ratio ◽  
Optimum Reaction ◽  
Ft Ir

In this paper, the prenyl alcohol was catalyzed synthesized by using isoprene and dichloroacetic acid as raw material and sodium dichloroacetate as catalyst. The obtained product was mainly characterized by FT-IR and GC. Furthermore, the olefine acid ratio, reaction time, amount of catalyst, saponification time, NaOH concentration and distilled water consumption were systematically investigated during the work. The optimum reaction conditions were as follows: the olefine acid ratio was 1:2, reaction time was 2h, amount of catalyst was 1.5g, saponification time was 2h, NaOH concentration was 4mol/L and amount of distilled water was 0.2mL, the yield of prenyl alcohol was 26%

The Catalyzed Synthesis of Prenyl Alcohol in Anhydrous System

2014 ◽  
Vol 881-883 ◽  
pp. 241-244
Author(s):  
Fu Xian Ruan ◽  
Zhi Peng He ◽  
Hong Lang Song ◽  
Ke Lin Huang ◽  
Jing Hu ◽  
...  
Keyword(s):  
Reaction Time ◽  
Dichloroacetic Acid ◽  
Raw Material ◽  
Reaction Conditions ◽  
Acid Ratio ◽  
Optimum Reaction ◽  
Ft Ir

In this paper, the prenyl alcohol was catalyzed synthesized in anhydrous system by using isoprene and dichloroacetic acid as raw material and sodium dichloroacetate as catalyst. The obtained product was mainly characterized by FT-IR and GC. Furthermore, the olefine acid ratio, reaction time, amount of catalyst, saponification time and NaOH concentration were systematically investigated during the work. The optimum reaction conditions are as follows: the olefine acid ratio was 1:2, reaction time was 2h, amount of catalyst was 1.8g, saponification time was 2h and NaOH concentration was 4mol/L, the yield of prenyl alcohol was 45%.

The Preparation of Sugarcane Bagasse Microcrystaline Cellulose in Subcritical Water/CO2

2011 ◽  
Vol 396-398 ◽  
pp. 1769-1772
Author(s):  
Ke Lin Huang ◽  
Ben Wang ◽  
Xiao Yu Peng ◽  
Ze Fen Wang ◽  
Ke Xian Li ◽  
...  
Keyword(s):  
Reaction Time ◽  
Sugarcane Bagasse ◽  
Reaction Temperature ◽  
Subcritical Water ◽  
Reaction Conditions ◽  
Reaction Pressure ◽  
Good Thermal Stability ◽  
Solid Ratio ◽  
Optimum Reaction ◽  
Ft Ir

Sugarcane bagasse microcrystalline cellulose (SBMC) was first prepared under subcritical Water/CO2 by degradation of sugarcane bagasse cellulose (SBC). The obtained products were characterized by FT-IR, XRD and TGA and the results showed that the amorphous parts of SBC was easily decomposed, and yet the crystal parts kept a good form all along during the degradation, which demonstrated SBMC had good thermal stability. Furthermore, the reaction temperature, reaction time, reaction pressure and liquid-solid ratio were systematically investigated during the work. The optimum reaction conditions are as follows: the reaction temperature was 200°C; the reaction time was 60 min; the reaction pressure was 2 MPa and the liquid-solid ratio was 40:1.

The Preparation of Micro-Molecular Dextran in Sub-Critical Water/CO2

2013 ◽  
Vol 712-715 ◽  
pp. 502-505
Author(s):  
Shu Qiong Liao ◽  
Xiao Yu Peng ◽  
Xue Wang Zhang ◽  
Ke Lin Huang ◽  
Ben Wang ◽  
...  
Keyword(s):  
Reaction Time ◽  
Reaction Temperature ◽  
Temperature Reaction ◽  
Liquid Ratio ◽  
Reaction Conditions ◽  
Reaction Pressure ◽  
Optimum Reaction ◽  
Ft Ir ◽  
Solid Liquid ◽  
Hydrolysis Of

Micro-molecular dextran was prepared in sub-critical water/CO2 by hydrolysis of dextran20. The obtained products were mainly characterized by FT-IR and GPC. Furthermore, the reaction temperature, reaction time, reaction pressure, solid-liquid radio and stirring speed were systematically investigated during the work. The optimum reaction conditions are as follows: the reaction temperature was 160°C; the reaction time was 60 min; the reaction pressure was 2.5MPa; the solid-liquid ratio was 0.6 and the stirring speed was 300r/min.

Study on the Influence of Different Catalysts on the Preparation of Ethyl Levulinate from Biomass Liquefaction

2020 ◽  
Vol 14 (3) ◽  
pp. 396-400
Author(s):  
Shuhua Yang ◽  
Qian Guan ◽  
Zijie Li ◽  
Haiyan Xu ◽  
Zhiwei Wang ◽  
...  
Keyword(s):  
Sulfuric Acid ◽  
Reaction Time ◽  
Reaction Temperature ◽  
Raw Materials ◽  
Raw Material ◽  
Reaction Conditions ◽  
Ethyl Levulinate ◽  
Catalyst Type ◽  
Optimum Reaction ◽  
Catalyst Dosage

The liquefaction experiments of straw biomass under heating and pressure were carried out with sulfuric acid and three ionic liquids as catalysts, 1-Butyl-3-methylimidazolium chloride ([BMIM] [Cl]), 1-Butyl-3-methylimidazolium hydrogen sulfate ([BMIM] [HSO4]), 1-methyl-3-(4-sulfobutyl) imidazole bisulphate ([HSO3-BMIM] [HSO4]), and anhydrous ethanol as solvent. The effects of catalyst type and dosage, reaction time and reaction temperature on liquefaction were investigated and optimized. The results showed that under the catalysis of sulfuric acid, the yield of ethyl levulinate was the highest; [HSO3-BMIM] [HSO4], the conversion of raw materials was the highest; when sulfuric acid was used as catalyst, the optimum reaction conditions were catalyst dosage 10%, reaction temperature 190 °C, reaction time 60 min, the yield of ethyl levulinate (EL) was 18.11%, and the conversion of raw materials was 75%. When [HSO3-BMIM] [HSO4] was used as catalyst, the optimum reaction conditions were as follows: catalyst dosage 26%, reaction temperature 200 °C, reaction time 60 min, the yield of EL was 10.2%, conversion of raw material 85.31%.

scholarly journals Clinoptilolite as a natural, active zeolite catalyst for the chemical transformations of geraniol

2021 ◽  
Author(s):  
Anna Fajdek-Bieda ◽  
Agnieszka Wróblewska ◽  
Piotr Miądlicki ◽  
Jadwiga Tołpa ◽  
Beata Michalkiewicz
Keyword(s):  
Reaction Time ◽  
Nitrogen Adsorption ◽  
Carbon Chain ◽  
Raw Material ◽  
Chemical Transformations ◽  
Renewable Biomass ◽  
Ft Ir ◽  
Catalyst Content ◽  
Favorable Conditions ◽  
Instrumental Methods

AbstractThis work presented the studies with the natural zeolite—clinoptilolite as the catalyst for the isomerization of geraniol. During the research, it turned out that the studied process is much more complicated, and not only isomerization takes place in it, but also dehydration, oxidation, dimerization, cyclization and fragmentation of the carbon chain. Geraniol is an organic raw material which can be obtained not only by a chemical synthesis but also from plants (renewable biomass) by distillation or extraction method, for example a source of geraniol can be a plant—geranium. Before catalytic tests clinoptilolite was characterized by the instrumental methods, such as: XRD, porosity studies—nitrogen adsorption at 77 K, SEM, EDXRF, and FT-IR. Gas chromatography analyses showed that the main products of geraniol isomerization process were 6,11-dimethyl-2,6,10-dodecatrien-1-ol and thumbergol. The selectivity of 6,11-dimethyl-2,6,10-dodecatrien-1-ol and thumbergol depended on the temperature, catalyst content and reaction time. These parameters were changed in the following ranges: 80–150 °C (temperature), 5–15 wt% (catalyst content) and 15–1440 min. (reaction time). The most favorable conditions for 6,11-dimethyl-2,6,10-dodecatrien-1-ol and thumbergol obtaining were: temperature 140 ºC, catalyst content 12.5 wt% and reaction time 180 min. At these conditions, the conversion of geraniol amounted to 98 mol%, and the selectivities of 6,11-dimethyl-2,6,10-dodecatrien-1-ol and thumbergol amounted to 14 and 47 mol%, respectively.

Study on the Synthesis of Isoamyl Acetate Catalyzed by Strong Acidic Cation Exchange Resin

2011 ◽  
Vol 396-398 ◽  
pp. 2411-2415 ◽  
Author(s):  
Ping Lan ◽  
Li Hong Lan ◽  
Tao Xie ◽  
An Ping Liao
Keyword(s):  
Acetic Acid ◽  
Reaction Time ◽  
Cation Exchanger ◽  
Cation Exchange Resin ◽  
Isoamyl Acetate ◽  
Molar Ratio ◽  
Esterification Reaction ◽  
Reaction Conditions ◽  
Optimum Reaction

Isoamyl acetate was synthesized from isoamylol and glacial acetic acid with strong acidic cation exchanger as catalyst. The effects of reaction conditions such as acid-alcohol ratio, reaction time, catalyst dosage to esterification reaction have been investigated and the optimum reaction conditions can be concluded as: the molar ratio of acetic acid to isoamylol 0.8:1, reaction time 2h, 25 % of catalyst (quality of acetic acid as benchmark). The conversion rate can reach up to 75.46%. The catalytic ability didn’t reduce significantly after reusing 10 times and the results showed that the catalyst exhibited preferably catalytic activity and reusability.

Catalytic Application of H4SiW12O40/SiO2 in Synthesis of Acetals and Ketals

2011 ◽  
Vol 284-286 ◽  
pp. 2374-2379 ◽  
Author(s):  
Shui Jin Yang ◽  
Yong Kui Huang ◽  
Li Yu
Keyword(s):  
Reaction Time ◽  
High Activity ◽  
Sol Gel ◽  
Reaction Parameters ◽  
Reaction Conditions ◽  
Catalytic Application ◽  
Ft Ir ◽  
Gel Technique ◽  
Catalyst Dosage ◽  
Novel Catalyst

A novel catalyst, H4SiW12O40/SiO2was synthesized by a sol-gel technique, and characterized by FT-IR and XRD. Catalytic application of H4SiW12O40/SiO2for synthesis of acetals and ketals were tested. The variation of different reaction parameters, such as mole ratio of aldehyde/ketone to alcohols, catalyst dosage and reaction time on the yield of acetals and ketals were also studied. The results reveal that the H4SiW12O40/SiO2catalysis generally results in good yields of acetals and ketals under mild reaction conditions and the high activity and stability of the catalyst is well retained on recycling.

Synthesis of Diamine Containing Chalcone Structure by Nitroammoniation and Aldol Condensation

2019 ◽  
Vol 801 ◽  
pp. 145-150
Author(s):  
Yan Kai Huang ◽  
Qi Lin Mei ◽  
Zhi Xiong Huang ◽  
Yan Qin ◽  
Di Zhu
Keyword(s):  
Reaction Temperature ◽  
Elemental Analysis ◽  
Aldol Condensation ◽  
Raw Material ◽  
Anhydrous Ethanol ◽  
Infrared Analysis ◽  
Reaction Conditions ◽  
Optimum Reaction ◽  
Ethanol Dosage

In this paper, the structure of the photosensitive diamines was designed and the method of synthesizing such diamines was investigated. The 1-(3-aminophenyl)-3-(4-aminophenyl)-2-propen-1-one analyzed by elemental analysis and infrared analysis was synthesized through two-step experiments with Aldol condensation and Nitroammoniation process. Through the experiment the optimum reaction conditions are raw material ratio of 1:1, anhydrous ethanol dosage of 60 ml, 10 % NaOH dosage of 10 ml and reaction temperature of 25°C for 4h. The yield was about 55.4 %.

Preparation and Properties of MgAl2O4-CaAl12O19 High Temperature Composite

2012 ◽  
Vol 512-515 ◽  
pp. 617-620
Author(s):  
Yong Hong Wang ◽  
Yan Gai Liu ◽  
Tao Yang ◽  
Zhao Hui Huang ◽  
Ming Hao Fang
Keyword(s):  
Phase Composition ◽  
High Temperature ◽  
Reaction Temperature ◽  
Bending Strength ◽  
Raw Materials ◽  
Weight Ratio ◽  
Raw Material ◽  
Reaction Conditions ◽  
Optimum Reaction ◽  
Industrial Alumina

The utilization of lightweight refractories plays an important role in reducing the energy consumption of industrial furnaces. In this paper, MgAl2O4-CaA112O19 high temperature composite was synthesized via solid state reaction using magnesite, dolomite and industrial alumina as raw materials. The influences of raw materials and reaction temperature on phase compositions and microstructure of the composite were investigated by XRD and SEM，respectively. The parameters to prepare MgAl2O4-CaA112O19 high temperature composite were optimized. The results show that the optimum reaction conditions for synthesizing MgAl2O4-CaA112O19 composite is the CA6/MA weight ratio of 2:3, and the reaction temperature of 1500°C for 4h. The CaA112O19 crystals showed laminated or plate-like structure, and the MgAl2O4 showed spherical morphology. The reaction temperature had little effect on the phase compositions of MA-CA6 composite in this experiment. The content of Al2O3 in the raw material affected the phase composition of MA-CA6 composite.With the increase of the CaA112O19 amount, the bending strength of the composite decreased.

Synthesise of (4-Ethynyl-Phenyl)-(4-trifluoromethyl-phenyl)-Diazene, a Novel Intermediate of Azobenzene Liquid Crystal with High Birefrigence

2014 ◽  
Vol 584-586 ◽  
pp. 1705-1708
Author(s):  
Xiao Ping Huo ◽  
Qi Pei Xu ◽  
Zong Cheng Miao
Keyword(s):  
Liquid Crystal ◽  
Raw Materials ◽  
Coupling Reaction ◽  
Sonogashira Coupling ◽  
Target Compound ◽  
Reaction Conditions ◽  
Silyl Group ◽  
Sonogashira Coupling Reaction ◽  
Optimum Reaction ◽  
Ft Ir

In order to obtain an important azobenzene liquid crystal intermediate with phenylacetylene group, Sonogashira coupling reaction was used to preparation the compound. In this paper, the intermediate was synthesized by (4-Iodo-phenyl)-(4-trifluoromethyl-phenyl)-diazene and trimethyl silyl acetylene (TMSA) as raw materials, and then the trimethyl silyl group was removaled under the action of K2CO3. During the synthesis, the optimum reaction conditions were obtained, that the mol ratio of (4-Iodo-phenyl)-(4-trifluoromethyl-phenyl)-diazene and trimethyl silyl acetylene was 1:2, the reaction temperature was 80 oC. Fourier transform infrared spectroscopy (FT-IR) was used to measure the molecular structure of the target compound.

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