scholarly journals Sol Gel Synthesized Nanosilica as Photoanode Material for Dye Sensitized Solar Cells (DSSCs) System

2014 ◽  
Vol 625 ◽  
pp. 110-113
Author(s):  
Stephanie Lau Chai Tying ◽  
Coswald Stephen Sipaut ◽  
Jedol Dayou ◽  
Rachel Fran Mansa

Dye-sensitized solar cells (DSSCs) have been extensively studied due to their promising potential for high efficiency, low production cost and eco-friendly production. The photoanode of DSSCs is traditionally composed of randomly packed TiO2 nanoparticles which have large specific surface area and suitable band gap (3.2 eV) for the effective injection of electrons from the dye molecules to the semiconductor. However, its high surface charge recombination rate accounts for its low efficiency. Alternatively, silica which is chemically inert, thermally stable, high surface area, and inexpensive can be used to substitute TiO2 as photoanode material. However, bulk silica has a wide band gap of 8.9 eV and its band gap need to be narrowed in order to use it as photoanode materials. Thus, in this study, the effect of nanosilica photoanode and its particle size on the performance of dye sensitized solar cell are investigated and characterized. The result is then compared with the fumed silica and conventional TiO2 DSSCs. Although the results shows that photon-electron conversion is inferior compared to TiO2 photoanode, it has a great potential as the fabrication cost is low and more environmental friendly.Keywords : Dye Sensitized Solar Cell, Photoanode material, Nanosilica, Sol gel synthesis

Author(s):  
M. Szindler ◽  
M.M. Szindler ◽  
P. Boryło

Purpose: The article presents the results of research on ZnO nanopowder prepared using sol-gel method that is the easy process enabling us to control shape and size of particles The purpose of this article is to synthesized ZnO nanostructures by sol-gel method and characterized them for use in dye sensitized solar cells. Design/methodology/approach: Zinc oxide nanopowder was synthesized by using zinc acetate dehydrate as a precursor. The prepared nanopowder has been subjected to structural analysis using a transmission electron microscope (TEM). Scanning Electron Microscopic (SEM) images were taken with a Zeiss Supra 35. Qualitative studies of chemical composition were also performed using the Energy Dispersive Spectrometer (EDS). The structure of zinc oxide was investigated by X-ray crystallography The absorbance of zinc oxide layers with and without dye were measured by Thermo Scientific Evolution 220 spectrophotometer equipped with a xenon lamp in the wavelength range from 190 nm to 1100 nm. Findings: Sol-gel method allows the formation of uniform nanoparticles of zinc oxide. The nanoparticles have been successfully used in photoelectrode of dye sensitized solar cell. The light harvesting efficiency of the electrode it remains in a wide spectral range above 85%, which gives better results than in the case of titanium dioxide. Research limitations/implications: The next step in the research will be to investigate the ZnO/NiO composite on the properties of the photoelectrode of dye sensitized solar cell. Practical implications: he unique properties of produced ZnO nanostructural materials have caused their interest in such fields as medicine, transparent electronics and photovoltaics. Originality/value: The ZnO nanoparticles were prepared using sol-gel method and then effectively used in the photoanode of dye sensitized solar cell.


2018 ◽  
Vol 6 (42) ◽  
pp. 11444-11456 ◽  
Author(s):  
Jonnadula Venkata Suman Krishna ◽  
Narra Vamsi Krishna ◽  
Towhid H. Chowdhury ◽  
Suryaprakash Singh ◽  
Idriss Bedja ◽  
...  

We have designed and synthesised four novel porphyrin sensitizers for dye-sensitized solar cell applications and shown power conversion efficiency of 10.5%.


2018 ◽  
Vol 47 (34) ◽  
pp. 11942-11952 ◽  
Author(s):  
Kitty Y. Chen ◽  
Phil A. Schauer ◽  
Brian O. Patrick ◽  
Curtis P. Berlinguette

Two sets of structurally analogous Co(iii/ii)-based redox mediators were incorporated in the dye-sensitized solar cells and a linear correlation was demonstrated between redox potential and photovoltage.


2015 ◽  
Vol 3 (12) ◽  
pp. 6383-6391 ◽  
Author(s):  
Jia-De Peng ◽  
Chuan-Pei Lee ◽  
D. Velayutham ◽  
V. Suryanarayanan ◽  
Kuo-Chuan Ho

A quasi-solid state dye-sensitized solar cell with the photoanode film of mesoporous TiO2spheres exhibited an efficiency of 6.18% and unfailing stability for 1200 h at 50 °C.


2017 ◽  
Vol 41 (13) ◽  
pp. 5605-5612 ◽  
Author(s):  
Radhakrishnan Sivakumar ◽  
Rodrigo Recabarren ◽  
Sekar Ramkumar ◽  
Arumugam Manivel ◽  
Jans Alzate-Morales ◽  
...  

A new type of ruthenium sensitizers, S3 and S4, consisting of carbazole–diazafluorene based bipolar ancillary ligands have been synthesized and characterized for dye sensitized solar cells.


2017 ◽  
Vol 1 (6) ◽  
pp. 1059-1072 ◽  
Author(s):  
N. Prachumrak ◽  
T. Sudyoadsuk ◽  
A. Thangthong ◽  
P. Nalaoh ◽  
S. Jungsuttiwong ◽  
...  

Three new D–π–A dyes containing different numbers of triphenylamine donor substitutions on a π-linker were synthesized for dye-sensitized solar cells.


2015 ◽  
Vol 44 (33) ◽  
pp. 14697-14706 ◽  
Author(s):  
Tejaswi Jella ◽  
Malladi Srikanth ◽  
Rambabu Bolligarla ◽  
Yarasi Soujanya ◽  
Surya Prakash Singh ◽  
...  

Three new heteroleptic Ru(ii) polypyridyl complexes have been designed with a pyridine-benzimidazole functionalized ligand for dye-sensitized solar cells.


RSC Advances ◽  
2015 ◽  
Vol 5 (40) ◽  
pp. 31404-31409 ◽  
Author(s):  
S. Veerapandian ◽  
S. Amudha ◽  
S. Austin Suthanthiraraj ◽  
M. Abdul Rahman ◽  
A. Sultan Nasar

The photovoltaic parameters of dye sensitized solar cells (DSSCs) fabricated with and without fourth generation polyurethane dendrimers have been discussed.


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