Distribution of some Heavy Metals in Leachates from a Municipal Waste Dumpsite

2007 ◽  
Vol 18-19 ◽  
pp. 495-500 ◽  
Author(s):  
K.O. Obahiagbon ◽  
G.B. Olowojoba

The distribution of heavy metals in leachates from a waste dumpsite was investigated. Soil samples were taken from a major dumpsite in Edo State located at Oluku near the National Institute for Oil Palm Research (NIFOR) and analyzed. The heavy metals considered were Iron, Lead, Zinc, Mercury, Chromium, Cadmium, Arsenic, Nickel, and Copper. The concentrations, in mg/l, of these heavy metals in the leachates from the soil samples over a distance of 80 meters were determined using the Atomic Absorption Spectrophotometer (AAS). The following results were obtained, the concentration of Iron ranged between 1.25-1.85 mg/l, Chromium: 0.01-0.07 mg/l, Zinc: 0.45-3.45 mg/l, Copper: 0.01-0.03 mg/l, Lead, Mercury, Cadmium, Arsenic, and Nickel had negligible values, i.e. less than 0.01 mg/l. From the results the concentrations of iron and zinc fell within Federal Environmental Protection Agency (FEPA) limits.

2021 ◽  
Vol 2 (3) ◽  
pp. 242-257
Author(s):  
Abdul Rafeeq ◽  
Syed Azhar Ali ◽  
Asad Khan Tanoli ◽  
Naseem Akhter ◽  
Ghulam Raza

The concentrations of Cd, Cr, Cu, Fe, Ni, Pb, & Zn were determined in the samples of soil, dismantling dust and rubber collected from the electronic waste dumping site of Shershah market and rubber from the Local market of Karachi city Pakistan. The city e-waste dumping and dismantling sites toxicity were not conducted before using modern techniques. The subsequent data of the heavy metals concentration were obtained using Atomic Absorption Spectrometry (AAS), Scanning Electron Microscopy (SEM), and Wavelength Dispersive- X-Ray Fluorescence Spectrometry (WD-XRF). Cu, Pb, and Zn were found as 133.17, 104.53 & 113.26 in soil, whereas in dismantling dust Pb & Zn were remained 10.56 and 12.65 mg/kg similarly. The China toy particle analysis by SEM was resulting metallic trend as Fe > Zn > Pb > Cd > Ni > Cr. The estimated data were compared with the levels allowed by the Pakistan Environmental Protection Agency (Pak-EPA) and the United States Environmental Protection Agency (USEPA). The maximum allowable limit for Cd is 3; Cr, Cd, and Pb are 100 for Ni is 50 and 300 mg/kg for Zn. The presence of these heavy metals from e-waste dumping would become soon a significant reason to cause serious health problems for the nearby residents and as well as city too. It has been concluded that the dumping of e-waste is the major source of contamination of heavy metals in the studied media. It is recommended that the e-waste must be recycled formally to prevent the soil from being polluted. .


Author(s):  
Prince M. Gyekye ◽  
Adams Sadick ◽  
Felix O. Ababio ◽  
Mohammed Musah ◽  
Calys Tagoe Edward

A study was conducted to determine the extent of site contamination by Lead (Pb) present in the soil on the premises of Air Liquide Ghana Limited, and give the appropriate recommendation for decontamination, where necessary. Eighteen (18) soil samples were collected from the study area using an augur. The geographical coordinates and elevations of the samples were recorded with the GPS. The samples were analyzed in the laboratory using Atomic Absorption Spectrophotometer. In the absence of present standards from the Ghana Environmental Protection Agency (EPA), both the Dutch List and the International List standard were used to evaluate the concentration levels of Pb in the soil. Results from the analysis revealed that the concentration of lead (Pb) initially exceeded the international threshold of the Dutch intervention value of 530 mg/kg in some sample areas. Nine locations of the sample areas where diesel was being stored, S2-Diese Tank and Smoking Area S5-Smoking Area recorded values of 636.4 mg/kg and 602 respectively which is above the recommended threshold. The control recorded below the threshold value of 530 mg/kg. The study also showed that Lead compounds attached to soil particles took a shorter time to break down to reduce the levels of concentration over time.


2017 ◽  
Vol 7 (16) ◽  
pp. 38-48 ◽  
Author(s):  
Olayinka Adunni Ubani-Rex ◽  
Joseph Kayode Saliu ◽  
Taiwo Hassan Bello

Background. The presence of heavy metals in the aquatic environment is a concern because of potential toxicity and threats to plant and animal life. Objective. The present study evaluated the joint action toxicity and biochemical effects of sublethal concentrations of copper (Cu), lead (Pb) and cadmium (Cd) against Clarias gariepinus over a period of 28 days. Methods. We procured fingerlings (weight: 5–8 g; length: 4.5–6.0 cm) and juveniles (weight: 20–25 g; length: 14.5–17.5 cm) from a commercial fish farm in Bariga, Lagos state, Nigeria. Test toxicants were selected from the analyzed heavy metals in the field based on their deviation from World Health Organization, Federal Environmental Protection Agency and United States Environmental Protection Agency standards. Fish were randomly loaded into a 4-L glass aquaria for the bioassay per toxicant concentration of two replicates and untreated control (dechlorinated tap water). Results. The derived 96 hour lethal concentration 50 (LC50) value of Cu (2.11 mg/L) was the most toxic followed by Cd (24.18 mg/L) and Pb (34.48 mg/L), which was the least toxic of the singly tested pollutants. The analysis of dose-response data of the joint action toxicity of Cu and Cd, and Cu and Pb determined 96 hour LC50 values of 1.804 mg/L and 2.15 mg/L, respectively. The interactions between the mixture of Cu:Cd conformed with the model of synergism (synergistic ratio (SR)>1 and relative toxic units (RTU)>1), while the interaction between Cu:Pb was found to be antagonistic (SR<1), with an SR value of 0.98. The biochemical effects study revealed that malondialdehyde (MDA) levels decreased significantly (P<0.05) in the exposed fish, reduced glutathione was not significant at (P<0.05), and levels of superoxide dismutase (SOD), catalase, glucose and cholesterol were significantly different (P<0.05). Discussion. The observed increased in the glutathione level in the Cu:Cd mixture and a corresponding decrease in MDA concentration in the liver of test animals revealed the ability of fish to overcome the effects of lipid peroxidation in this group because the Cu ion is displaced by Cd, and the fish were able to catalyze the breakdown of hydrogen peroxide via the Fenton reaction. Conclusions. Further studies on the joint action toxicity of heavy metals are needed in order to further determine their concentration in the local environment. Ethics Approval. Study protocols were approved by the Health Research Ethics Committee of the University of Lagos. Competing Interests. The authors declare no financial competing interests


1989 ◽  
Vol 21 (6-7) ◽  
pp. 685-698
Author(s):  
J. J. Convery ◽  
J. F. Kreissl ◽  
A. D. Venosa ◽  
J. H. Bender ◽  
D. J. Lussier

Technology transfer is an important activity within the ll.S. Environmental Protection Agency. Specific technology transfer programs such as the activities of the Center for Environmental Research Information, the Innovative and Alternative Technology Program, as well as the Small Community Outreach Program are used to encourage the utilization of cost-effective municipal pollution control technology. Case studies of three technologies including a plant operations diagnostic/remediation methodology, alternative sewer technologies and ultraviolet disinfection are presented. These case studies are presented retrospectively in the context of a generalized concept of how technology flows from science to utilization which was developed in a study by Allen (1977). Additional insights from this study are presented on the information gathering characteristics of engineers and scientists which may be useful in designing technology transfer programs. The recognition of the need for a technology or a deficiency in current practice are important stimuli other than technology transfer for accelerating the utilization of new technology.


1987 ◽  
Vol 19 (10) ◽  
pp. 41-49 ◽  
Author(s):  
Ray Dinges ◽  
Jim Doersam

The Hornsby Bend Hyacinth Facility, the first such system built under the U. S. Environmental Protection Agency “Construction Grants Program”, represents the culmination of over a decade of experience at the City of Austin with hyacinth treatment. The facility consists of three culture basins 265 m in length with an area of 1.6 ha. To permit year-round hyacinth culture, basins are covered with a 2.06 ha unitary greenhouse structure. Fenced exclusion areas at intervals along sides of basins serve as natural aerators and enhance fish production. The system, operated in an aerobic mode, was designed to daily treat about three million liters of sludge lagoon supernatant. Exclusion of large vertebrate predators and stocking of basins with selected animal species will provide a unique ecosystem. Basins were planted with hyacinth in late October, 1985 and discharge commenced on February 3, 1986. Functional characteristics and ecological considerations of the facility are discussed and operational performance data are presented. Maintenance harvesting of hyacinth and disposition of plant material are described. Application of greenhoused hyacinth treatment systems are addressed.


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