Photophysical Properties of Carbazole Derivative DPSPC Doped Composite Glass

2011 ◽  
Vol 239-242 ◽  
pp. 1006-1009
Author(s):  
Yun Long Deng ◽  
Yun Hui Sun ◽  
Du Xia Cao ◽  
Ying Chen ◽  
Zhi Qiang Liu
Keyword(s):  
Fluorescence Quenching ◽  
Methyl Methacrylate ◽  
Photophysical Properties ◽  
Sol Gel ◽  
Organic Dye ◽  
Fluorescence Properties ◽  
Donor Group ◽  
Carbazole Derivative ◽  
Composite Glass ◽  
Gel Glasses

A D-π-D type of organic dye 2,7-di[4-(N,N-diphenylamino)styryl]-9-n-pentyl-9H- carbazole (DPSPC) with diphenylamine as donor group and styrene-carbazole-styrene as conjugation bridge has been synthesized. The photophysical properties of the dye in different solvents and poly methyl methacrylate/organic modified sol-gel glasses are researched. The results indicate that the fluorescence properties of the organic dye in composite glass increase relative to that in solvents and there are no fluorescence quenching in high doped concentration in composite glass matrixes. The dye has higher stability in the composite glass than that in solution.

Photochemistry Channels of Merocyanine Encapsulated in Sol-Gel Glasses

1994 ◽  
Vol 346 ◽  
Author(s):  
A. M. Mahloudji ◽  
L. B. Meuret ◽  
C. T. Lin
Keyword(s):  
Molecular Form ◽  
Photophysical Properties ◽  
Sol Gel ◽  
Emission Spectra ◽  
Transfer Characteristic ◽  
Optically Transparent ◽  
Quinoid Form ◽  
Gel Glasses ◽  
Processing Techniques ◽  
First Time

ABSTRACTPhotophysical properties of l-Docosyl-4-(4-hydroxystyryl)pyridiniurn bromide (SB), a merocyanine dye in solution and encapsulated in sol-gel derived glass are investigated at 298 and 77 K. In solution, the absorption spectra of SB display an equilibrium between the quinolinium and benzoid forms. The equilibrium can be shifted to either quinolinium or benzoid form under an acidic or basic condition, respectively. The emission spectra of SB, on the other hand, give not only the quinolinium and benzoid forms but also the quinoid form which emits at 500 nm. The existence of excited state quinoid form of SB is also evident in the excitation spectrum while the emission at 500 nm is monitored. Both in solution and in xerogel, the quinoid form of SB is shown to be photochemically unstable as compared to the benzoid form. It is proposed that the photoexcited quinolinium form of SB is a proton dissociative species which transforms readily to become the quinoid form. The results indicate that photochemistry channels of SB are originated from the quinoid form. Moreover, the benzoid form of SB (photochemically stable) exhibits large hyperpolarizability due to its charge-transfer characteristic, and is a desired molecular form for nonlinear optical (NLO) applications. The material processing techniques for stabilizing the benzoid form of SB in optically transparent sol-gel glasses are illustrated for the first time.

scholarly journals Spectral Behavior and Photophysical Parameters of Dihydrophenanthro[9,10-e][1,2,4]Triazine Derivative Dyes in Sol–gel and Methyl Methacrylate Polymer Matrices

2021 ◽  
Author(s):  
Mahmoud Sakr ◽  
Maram T. H. Abou Kana ◽  
Ahmed H.M. Elwahy ◽  
Samy A. El-Daly A. El-Daly ◽  
El-Zeiny M. Ebeid
Keyword(s):  
Methyl Methacrylate ◽  
Cross Sections ◽  
Electronic Transition ◽  
Photophysical Properties ◽  
Sol Gel ◽  
Emission Spectra ◽  
Molar Absorptivity ◽  
Excited State Lifetime ◽  
Photophysical Parameters ◽  
Photo Stability

Abstract This paper deals the optical and photophysical properties of dihydrophenanthro [9,10-e] [1,2,4] triazine fluorescent derivative dyes doped in Silicate based sol–gel, homo-poly methyl methacrylate (PMMA). Solid hosts effect on the optical and photophysical parameters such as molar absorptivity, cross sections of singlet–singlet electronic absorption and emission spectra, excited state lifetime, quantum yield of fluorescence. Also the dipole moment of electronic transition, the length of attenuation and Oscillator strength of electronic transition from So →S1 have been detected. The dyes with different pumping power were pumped by 3rd harmonic Nd:YAG pulsed laser 8ns pulse duration, with a repetition rate at (10Hz). Good Photo stability of compound 1 and 2 were obtained that was decreased to 49%, 54% and 46%, 40% of the initial ASE of dyes in sol gel and PMMA respectively, after 55000 pumping pulses at (10 mJ/pulse). The dyes in sol-gel show improved Photo stability compared with those in organic polymeric matrices.

Fluorescence properties of Er3+-doped sol—gel glasses

1996 ◽  
Vol 197 (2-3) ◽  
pp. 136-144 ◽  
Author(s):  
Brandon T. Stone ◽  
Kevin L. Bray
Keyword(s):  
Sol Gel ◽  
Fluorescence Properties ◽  
Gel Glasses

TEM visualization of surface replicated acid and base catalyzed sol-gel glasses

1986 ◽  
Vol 44 ◽  
pp. 448-449
Author(s):  
George C. Ruben ◽  
Merrill W. Shafer
Keyword(s):  
Elevated Temperatures ◽  
Sol Gel ◽  
Basic Medium ◽  
Glass Transition Point ◽  
Structural Space ◽  
Acid And Base ◽  
Organometallic Precursors ◽  
New Processing ◽  
Gel Glasses ◽  
Physical Phenomena

Traditionally ceramics have been shaped from powders and densified at temperatures close to their liquid point. New processing methods using various types of sols, gels, and organometallic precursors at low temperature which enable densificatlon at elevated temperatures well below their liquidus, hold the promise of producing ceramics and glasses of controlled and reproducible properties that are highly reliable for electronic, structural, space or medical applications. Ultrastructure processing of silicon alkoxides in acid medium and mixtures of Ludox HS-40 (120Å spheres from DuPont) and Kasil (38% K2O &62% SiO2) in basic medium have been aimed at producing materials with a range of well defined pore sizes (∼20-400Å) to study physical phenomena and materials behavior in well characterized confined geometries. We have studied Pt/C surface replicas of some of these porous sol-gels prepared at temperatures below their glass transition point.

Photopatterning of hybrid sol–gel glasses: generation of volume phase gratings under visible light

2004 ◽  
Vol 398 (1-3) ◽  
pp. 151-156 ◽  
Author(s):  
M. Feuillade ◽  
C. Croutxé-Barghorn ◽  
L. Mager ◽  
C. Carré ◽  
A. Fort
Keyword(s):  
Visible Light ◽  
Sol Gel ◽  
Volume Phase ◽  
Gel Glasses

Bioencapsulation in Sol-Gel Glasses

1998 ◽  
Vol 519 ◽  
Author(s):  
L. Bergogne ◽  
S. Fennouh ◽  
J. Livage ◽  
C. Roux
Keyword(s):  
Sol Gel ◽  
Porous Silica ◽  
Silica Matrix ◽  
Whole Cells ◽  
The Past ◽  
Wide Range ◽  
Activity Of Enzymes ◽  
Gel Glasses ◽  
Micro Organisms

AbstractBioencapsulation in sol-gel materials has been widely studied during the past decade. Trapped species appear to retain their bioactivity in the porous silica matrix. Small analytes can diffuse through the pores allowing bioreactions to be performed in-situ, inside the sol-gel glass. A wide range of biomolecules and micro-organisms have been encapsulated. The catalytic activity of enzymes is used for the realization of biosensors or bioreactors. Antibody-antigen recognition has been shown to be feasible within sol-gel matrices. Trapped antibodies bind specifically the corresponding haptens and can be used for the detection of traces of chemicals. Even whole cells are now encapsulated without any alteration of their cellular organization. They can be used for the production of chemicals or as antigens for immunoassays.

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