The High-Performance of Cerium Doped Sodium Bismuth Titanate Aurivillirs Phase Material

2011 ◽  
Vol 284-286 ◽  
pp. 1389-1392
Author(s):  
Yuan Yuan Feng ◽  
Yong Zhang ◽  
Zhi Gang Gai ◽  
Ping Hu ◽  
Yu Fan Zhou ◽  
...  

The effect of Ce substitution at the A-site on the properties of Na0.5Bi4.5Ti4O15 (NBT)–based ceramics was systematically investigated. The substitution at A-site caused distortion of lattice and improved piezoelectric activity correspondingly. The piezoelectric coefficient d33 of the Na0.5Bi4.5-xCexTi4O15 (x=0.03) ceramic was found to be as high as 26 pC/N, together with high mechanical quality factor Q ( 2769 ), and stable piezoelectric properties, demonstrating that the Ce-modified NBT-based materials are promising candidates for high-temperature applications.

2011 ◽  
Vol 239-242 ◽  
pp. 3240-3243 ◽  
Author(s):  
Chun Huy Wang

Extending the investigations on (Bi0.5Na0.5)TiO3-based solid solution for lead-free piezoelectric ceramics, this paper consider the complex solid-solution system (Bi0.5Na0.5)TiO3–(Bi0.5K0.5)TiO3[BNT-BKT]. (Bi0.5Na0.5)TiO3with 7~ 30 mol% (Bi0.5K0.5)TiO3ceramics have been prepared following the conventional mixed oxide process. A morphotropic phase boundary (MPB) between rhombohedral (R) and tetragonal (T) was found at the composition 0.82BNT-0.18BKT with correspondingly enhanced piezoelectric properties. The electromechanical planar coupling factor is higher for compositions near the MPB. The mechanical quality factor (Qm), planar coupling coefficient (kp) and thickness coupling coefficient (kt) of 0.82BNT-0.18BKT ceramics were 125, 28.8% and 47.4%, respectively.


2012 ◽  
Vol 05 (02) ◽  
pp. 1260013
Author(s):  
TAKESHI KIMURA ◽  
SHU YIN ◽  
TAKATOSHI HASHIMOTO ◽  
ATUSHI SASAKI ◽  
YUICHI TOKANO ◽  
...  

High purity ( Ba 1-x Ca x)( Ti 1-y Zr y) O 3((x,y)=(0.00,0.00)–(0.50,0.50)) were synthesized by a composite-hydroxide-mediated approach at 200°C using a sealed tube with a rolling system. The powders with an average size of 50 nm in diameter and narrow size distribution were produced. The highest electromechanical coupling factor k r was 36.1% ((x,y) = (0.05,0.03)) and highest mechanical quality factor Q m was 256 ((x,y) = (0.11,0.13)).


2012 ◽  
Vol 487 ◽  
pp. 770-774
Author(s):  
Wei Ye Chen ◽  
Lan Zhu ◽  
Peng Yi Liu ◽  
Cai Ping Lin ◽  
Hao Jian Tu

The effects of NiO-doping on the microstructure and piezoelectric properties of PMSZT ceramics were investigated. The experimental results indicate that pure perovskite structure was obtained in the doping range. With the increasing of doping amounts, phases shift from tetragonal phase to rhombohedral phase. The mechanical quality factor (Qm) , Dielectric constant (εr) , electromechanical coupling factor (Kp) and piezoelectric constant (d33) increase with the increasing of doping amounts and then decrease, whereas, dielectric loss (tanδ) decrease and then increase. The ceramics with doping amount of 0.1wt.% sintered at 980 °C have the optim properties of Qm=1345, εr=1853, Kp=0.62, d33=375 and tanδ=0.21%。


2010 ◽  
Vol 146-147 ◽  
pp. 89-92
Author(s):  
Zhi Gang Gai ◽  
Yuan Yuan Feng ◽  
Jin Feng Wang ◽  
Hong Wu

Na0.5Bi4.5Ti4O15-based materials with A-site vacancy were synthesized using conventional solid state processing. The (Li,Ce) modification of Na0.5Bi4.5Ti4O15-based materials resulted in the obvious improvement of the piezoelectric activity and dielectric permittivity. The dielectric and piezoelectric properties of Na0.5Bi4.5Ti4O15-based ceramics exhibiting a very stable temperature behavior, together with its high TC ~641oC, excellent piezoelectric coefficient ~28pC/N and very low temperature coefficient of resonant frequency, making the (Li,Ce) modified Na0.5Bi4.5Ti4O15-based ceramics a promising candidate for high temperature applications.


2011 ◽  
Vol 239-242 ◽  
pp. 486-489
Author(s):  
Ling Fang Xu ◽  
Wen Chen ◽  
Jing Zhou ◽  
Chang Ping Yang

Niobium doped Pb(Zr,Ti)O3fiber/epoxy resin 1-3 composites with different ceramic volume fraction of 10-85% were fabricated by filling-casting method. Effects of ceramic volume fraction on electric properties were investigated. For a typical 30% ceramic content composite, the thickness coupling coefficientkt, mechanical quality factorQm, acoustic impedanceZmand anisotropic propertykt/kpwere 0.67, 0.55, 11.03 MRayl and 2.23, respectively.


1993 ◽  
Vol 8 (12) ◽  
pp. 3184-3191 ◽  
Author(s):  
Jong H. Moon ◽  
Hyun M. Jang ◽  
Beoung D. You

The roles of additives (MnO2, SiO2, and CdO) in controlling microstructural development and piezoelectric properties of Pb(Ni1/3Nb2/3)O3– PbTiO3–PbZrO3(PNN–PT–PZ) ceramics were systematically examined. The addition of SiO2 (<1 wt. %) to the pseudoternary PNN–PT-PZ system enhances densification, but suppresses grain growth significantly. On the other hand, the presence of MnO2 expedites the rate of grain growth without increasing the rate of densification appreciably. The observed difference in the grain-growth behavior was discussed in terms of the viscosity of liquid phase formed during sintering and the diffusion-controlled process for the solute-atoms transport. The rapid increase in the mechanical quality factor (Qm) and the decrease in the relative dielectric permittivity (∊r) and d33 for the MnO2-doped specimens indicate the formation of oxygen vacancies by the dissolution of Mn-atoms into the B-sites of perovskite structure. On the contrary, the presence of CdO (2 mol %) remarkably increases ∊r and d33 of PNN–PT–PZ ceramics.


2015 ◽  
Vol 3 (2) ◽  
pp. 329-338 ◽  
Author(s):  
Fapeng Yu ◽  
Qingming Lu ◽  
Shujun Zhang ◽  
Hewei Wang ◽  
Xiufeng Cheng ◽  
...  

BiB3O6 crystals possess large piezoelectric coefficients and high-temperature stability of their piezoelectric properties, which is promising for piezoelectric sensor applications.


2007 ◽  
Vol 280-283 ◽  
pp. 175-180
Author(s):  
Chun Huy Wang

The new piezoelectric ceramic of PbTiO3-PbZrO3-Pb(Mg1/3Nb2/3)O3 -Pb(Zn1/3Nb2/3)O3 with composition close to the morphotropic phase boundary was studied. The dielectric and piezoelectric properties of Pb0.96Sr0.04[(Zr1-yTiy)0.74(Mg1/3Nb2/3)0.20(Zn1/3Nb2/3)0.06]O3 were investigated, the composition range examined are 0.47 £ y £ 0.57. From the results of XRD and piezoelectric measurement, it is supposed that the composition with y = 0.51 corresponds to M.P.B. between tetragonal and pseudocubic perovskite. Some developed phenomena or models are introduced and take it to interpret well. After optimal choice of these conditions, the planar coupling factor close to 0.65, mechanical quality factor Qm close to 75, the longitude wave velocity close to 4100 m/s and the poled dielectric constant close to 2600 can be approached in this study.


2014 ◽  
Vol 608 ◽  
pp. 187-192
Author(s):  
Arjin Boonruang ◽  
Piyalak Ngernchuklin ◽  
Saengdoen Daungdaw ◽  
Nestchanok Yongpraderm ◽  
Chutima Eamchotchawalit

The effect of manganese doping on microstructure, piezoelectric and electromechanical properties of Pb0.94Sr0.06(Zr0.52Ti0.48)O3 (PSZT) ceramics has studied. The PSZT ceramics doped MnCO3 concentration in the region of 0-1.0 mol% were prepared by a solid-state reaction and conventional sintering process. Phase identification showed the formation of single phase perovskite structure in all compositions. Microstructure and fracture behavior were observed by scanning electron microscopy (SEM). The fracture behavior demonstrated the change of fracture type from trangranular to mix of trans-and inter-granular type with increasing the amount of MnCO3. Dielectric constant (K), d33 and kp were increased when higher amount of MnCO3 was doped. In addition, the mechanical quality factor (Qm) was highest at 0.1 mol% MnCO3 doping in PSZT ceramics.


2015 ◽  
Vol 659 ◽  
pp. 132-137
Author(s):  
Arjin Boonruang ◽  
Piyalak Ngernchuklin ◽  
Saengdoen Daungdaw ◽  
Nestchanok Yongpraderm ◽  
Chalermchai Jeerapan

The PSZTM ceramics from Pb0.94Sr0.06(Zr0.52Ti0.48)O3doped with 0.1 mol% Mn were prepared by a solid state reaction and. Two different methods were used to calculate the amount of Mn-dopant into PSZT powder. One was calculated rely on B-site precursor represented byBmethod. The other was computed based on the amount of calcined PSZT calledCmethod. This study was to investigate the effect of the two different calculating formulations of Mn doped PSZT ceramics by B and C methods on phase formation, microstructure, physical and electrical properties. The results were observed that phase identification showed the formation of perovskite structure in both cases. Besides, the mechanical quality factor (Qm) of the PSZTM ceramics derived fromBmethod was two times higher than those fromCmethod. Nevertheless, the dielectric constant (K), piezoelectric coefficient (d33) and planar coupling coefficient (kp) of the PSZTM ceramics fromBmethod were slightly lower than those of derived fromCmethod. This could be drawn the conclusion that PSZTM with 0.1 mol% Mn prepared byBmethod can be used as hard-type piezoelectric material.


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